Related papers: Off-diagonal hyperfine interaction between the 6p1…
Sub-Doppler, saturation dip, spectra of lines in the $v_1 + v_3$, $v_1 + 2v_4$ and $v_3 + 2v_4$ bands of $^{14}$NH$_3$ have been measured by frequency comb-referenced diode laser absorption spectroscopy. The observed spectral line widths…
The interaction of two excited hydrogen atoms in metastable states constitutes a theoretically interesting problem because of the quasi-degenerate 2P_{1/2} levels which are removed from the 2S states only by the Lamb shift. The total…
Hyperfine structure parameters are calculated for the 2p2(3P)3s 4P_J, 2p2(3P)3p 4Po_J and 2p2(3P)3p 4Do_J levels, using the ab initio multiconfiguration Hartree-Fock method. The theoretical hyperfine coupling constants are in complete…
Employing two state-of-the-art methods, multiconfiguration Dirac--Hartree--Fock and second-order many-body perturbation theory, highly accurate calculations are performed for the lowest 272 fine-structure levels arising from the $2s^{2}…
The theory of the long-range interaction of metastable excited atomic states with ground-state atoms is analyzed. We show that the long-range interaction is essentially modified when quasi-degenerate states are available for virtual…
The discovery of superconductivity at 203K in SH$_3$ is an important step toward higher values of $T_c$. Predictions based on state-of-the-art DFT for the electronic structure, including one preceding experimental confirmation, showed the…
The hyperfine interaction constants of the 2p4(3P)3p 2Do_{3/2,5/2}, 4Do_{1/2-7/2} and 4Po_{1/2-5/2} levels in neutral fluorine are investigated theoretically. Large-scale calculations are carried out using the multiconfiguration…
The ground-state hyperfine splitting values of high-Z boronlike ions are calculated. Calculation of the interelectronic-interaction contribution is based on a combination of the 1/Z perturbation theory and the large-scale…
We report the first direct measurement of the hyperfine transition of the ground state positronium. The hyperfine structure between ortho-positronium and para-positronium is about 203 GHz. We develop a new optical system to accumulate about…
Two anomalously weak transitions within the $2 ^3{\rm S}_1~-~3 ^3{\rm P}_J$ manifolds in $^3$He have been identified. Their transition strengths are measured to be 1,000 times weaker than that of the strongest transition in the same group.…
Optical frequency measurements of the intercombination line $(6s^{2})\,^{1}S_{0} -(6s6p)\,^{3}P_{1}$ in the isotopes of ytterbium are carried out with the use of sub-Doppler fluorescence spectroscopy on an atomic beam. A dispersive signal…
We report a precise measurement of the hyperfine interval in the ${2P}_{1/2}$ state of $^{7}$Li. The transition from the ground state ($D_1$ line) is accessed using a diode laser and the technique of saturated-absorption spectroscopy in hot…
The hyperfine structure of the ground state of erbium doped yttrium orthosilicate is analyzed with the use of electron paramagnetic resonance experiments in a tunable microwave resonator. This work was prompted by the disagreement between…
The hyperfine structure of the S1/2-D5/2 quadrupole transition at 729 nm in 43Ca+ has been investigated by laser spectroscopy using a single trapped 43Ca+ ion. We determine the hyperfine structure constants of the metastable level as…
We have studied the effect of including nearest-neighbor, electron-electron interactions, in particular the off-diagonal (non density-density) terms, on the spectra of truncated tetrahedral and icosahedral ``Hubbard molecules,'' focusing on…
This work presents accurate ab initio determination of the hyperfine splitting for the ground state and few low-lying excited states of 113Cd+; important candidates for the frequency standard in the microwave region, using coupled-cluster…
Over a two-year duration, we have compared the frequency of the 199Hg+ 5d106s 2S 1/2 (F=0)<-> 5d9 6s2 2D 5/2 (F=2) electric-quadrupole transition at 282 nm with the frequency of the ground-state hyperfine splitting in neutral 133Cs. These…
Cross-section and analyzing power data from (p,p') scattering to the 6- states at 11.58 and 14.35 MeV in 28Si, taken with energies of 80, 100, 134, and 180 MeV protons, have been analyzed using a distorted wave approximation with…
This work is an ab initio study of the 2p3 4So_3/2, and 2Do_{3/2,5/2} states of C- and 2p2 3P_{0,1,2}, 1D_2, and 1S_0 states of neutral carbon. We use the multi-configuration Hartree-Fock approach, focusing on the accuracy of the wave…
The ground state rotational spectrum of PH3 has been reanalyzed taking into account recently published very accurate data from sub-Doppler and conventional absorption spectroscopy measurements as well as previous data from the…