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Recent experiments demonstrated that interfacial water dissociation (H2O = H+ + OH-) could be accelerated exponentially by an electric field applied to graphene electrodes, a phenomenon related to the Wien effect. Here we report an…

Resonant Inelastic X-Ray Scattering (RIXS) spectra of hematite were measured at the Fe L3-edge for heteroepitaxial thin films which were undoped and doped with 1% Ti, Sn or Zn, in the energy loss range in excess of 1 eV to study electronic…

This article studies the photodetachment of a single electron anion near an attractive center. Both the differential and total photodetachment cross section are analysed. We obtain the electron flux crossing through a spherical detector…

Atomic Physics · Physics 2014-11-26 X. P. You , M. L. Du

Low-dimensional transition metal dichalcogenide, TMDC, materials are heralding a new era in optoelectronics and valleytronics owing to their unique properties. Photo-induced dynamics in these systems has mostly been studied from the…

Mesoscale and Nanoscale Physics · Physics 2023-03-08 Pritha Dey , Tejendra Dixit , Vikash Mishra , Anubhab Sahoo , Cheriyanath Vijayan , Sivarama Krishnan

Despite inherently poor interlayer conductivity, photodetectors made from few-layer devices of 2D transition metal dichalcogenides (TMDs) such as WSe$_2$ and MoS$_2$ can still yield a desirably fast ($\leq$90 ps) and efficient…

Applied Physics · Physics 2020-09-04 Kyle T. Vogt , Su-Fei Shi , Feng Wang , Matt W. Graham

We study dynamics of incoherent exciton formation under interband photoexcitation in Cu$_2$O using time-and angle-resolved photoemission spectroscopy at 90 K. Hot electrons injected by allowed optical transitions with 3.40-eV photons show…

Mesoscale and Nanoscale Physics · Physics 2019-10-23 H. Tanimura , K. Tanimura , P. H. M. van Loosdrecht

Anion and cation emission following water dissociation was studied for 6.6-keV $^{16}$O$^{+}$ + H$_{2}$O collisions. Absolute cross sections for the emission of all positively and negatively charged fragments, differential in both energy…

We present results of classical dynamics calculations, performed to study the photodissociation of water in crystalline and amorphous ice surfaces at a surface temperature of 10 K. Dissociation in the top six monolayers is considered.…

Astrophysics · Physics 2009-11-11 Stefan Andersson , Ayman Al-Halabi , Geert-Jan Kroes , Ewine F. van Dishoeck

We investigate the dynamical formation of excitons from photoexcited electron-hole plasma and its subsequent decay dynamics in monolayer MoS2 grown by chemical vapor deposition using ultrafast pump and terahertz probe spectroscopy.…

Materials Science · Physics 2014-10-14 Xuefeng Liu , Qingqing Ji , Zhihan Gao , Shaofeng Ge , Jun Qiu , Zhongfan Liu , Yanfeng Zhang , Dong Sun

Angle-resolved photoelectron spectroscopy of the unpaired electron in sodium-doped water, methanol, ammonia, and dimethyl ether clusters is presented. The experimental observations and the complementary calculations are consistent with…

Atomic and Molecular Clusters · Physics 2016-03-14 Adam H. C. West , Bruce L. Yoder , David Luckhaus , Clara-Magdalena Saak , Maximilian Doppelbauer , Ruth Signorell

The dynamics of polarized fluorescence in NADH at 460 nm under two-photon excitation at 720 nm by femtosecond laser pulses in water-methanol solutions has been studied experimentally and theoretically as a function of methanol…

Understanding the mechanisms of proton energy deposition in matter and subsequent damage formation is fundamental to radiation science. Here we exploit the picosecond (10^-12 s) resolution of laser-driven accelerators to track ultra-fast…

Phenomena involving electron transfer are ubiquitous in nature, photosynthesis and enzymes or protein activity being prominent examples. Their deep understanding thus represents a mandatory scientific goal. Moreover, controlling the…

Chemical Physics · Physics 2017-12-01 Carlo Andrea Rozzi , Filippo Troiani , Ivano Tavernelli

We have used molecular simulation and methods of importance sampling to study the thermodynamics and kinetics of ionic charge separation at a liquid water-metal interface. We have considered this process using canonical examples of two…

Chemical Physics · Physics 2022-06-08 John A. Kattirtzi , David T. Limmer , Adam P. Willard

We present the results of experimental studies of photon-negative ion interactions involving the dynamics of two electrons. Resonances associated with doubly excited states of Li^- and He^- have been observed using laser photodetachment…

Atomic Physics · Physics 2015-06-26 D. Hanstorp , G. Haeffler , A. E. Klinkmueller , U. Ljungblad , U. Berzinsh , I. Yu. Kiyan , D. J. Pegg

A key challenge in ultrafast science has been to directly track the coupled motions of electrons and nuclei in real-space and real-time. This study presents a significant step towards this goal by demonstrating the feasibility of…

Chemical Physics · Physics 2025-06-27 Tianyu Wang , Hui Jiang , Ming Zhang , Xiao Zou , Pengfei Zhu , Feng He , Zheng Li , Dao Xiang

We exploit inverse Raman scattering and solvated electron absorption to perform a quantitative characterization of the energy loss and ionization dynamics in water with tightly focused near-infrared femtosecond pulses. A comparison between…

A major goal of many spectroscopic techniques is to provide comprehensive information on the local chemical environment. Electron transfer mediated decay (ETMD) is a sensitive probe of the environment since it is actively involved in this…

When irradiated with violet light, hexaazatrinaphthylene (HATN) extracts a hydrogen atom from an alcohol forming a long-living hydrogenated species. The apparent kinetic isotope effect for fluorescence decay time in deuterated methanol…

Chemical Physics · Physics 2022-05-30 Olaf Morawski , Paweł Gawryś , Jarosław Sadło , Andrzej L. Sobolewski

Energy dissipation in water is very fast and more efficient than in many other liquids. This behavior is commonly attributed to the intermolecular interactions associated with hydrogen bonding. Here, we investigate the dynamic energy flow…