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For the Hirshfeld-I atom-in-molecule model, associated single-atom energies and interaction energies at the Hartree-Fock level are determined efficiently in one-electron Hilbert space. In contrast to most other approaches, the energy terms…

A fast multigrid solver is presented for high-order accurate Stokes problems discretised by local discontinuous Galerkin (LDG) methods. The multigrid algorithm consists of a simple V-cycle, using an element-wise block Gauss-Seidel smoother.…

Numerical Analysis · Mathematics 2020-11-25 Robert Saye

This paper presents a new fast iterative solver for large systems involving kernel matrices. Advantageous aspects of H2 matrix approximations and the multigrid method are hybridized to create the H2-MG algorithm. This combination provides…

Numerical Analysis · Mathematics 2025-09-12 Daria Sushnikova , George Turkiyyah , Edmond Chow , David Keyes

We present a new algorithm which allows for direct numerically exact solutions within dynamical mean-field theory (DMFT). It is based on the established Hirsch-Fye quantum Monte Carlo (HF-QMC) method. However, the DMFT impurity model is…

Strongly Correlated Electrons · Physics 2008-01-09 N. Blümer

Fourth-order differential equations play an important role in many applications in science and engineering. In this paper, we present a three-field mixed finite-element formulation for fourth-order problems, with a focus on the effective…

Numerical Analysis · Mathematics 2022-10-13 Patrick E. Farrell , Abdalaziz Hamdan , Scott P. MacLachlan

In this article, a nonlinear fractional Cable equation is solved by a two-grid algorithm combined with finite element (FE) method. A temporal second-order fully discrete two-grid FE scheme, in which the spatial direction is approximated by…

Numerical Analysis · Mathematics 2016-06-14 Yang Liu , Yanwei Du , Hong Li , Jinfeng Wang

Donor-based quantum devices in silicon are attractive platforms for universal quantum computing and analog quantum simulations. The nearly-atomic precision in dopant placement promises great control over the quantum properties of these…

Quantum Physics · Physics 2025-03-05 Maicol A. Ochoa , Keyi Liu , Piotr Różański , Michał Zieliński , Garnett W. Bryant

The implementation of efficient multigrid preconditioners for elliptic partial differential equations (PDEs) is a challenge due to the complexity of the resulting algorithms and corresponding computer code. For sophisticated finite element…

Mathematical Software · Computer Science 2016-10-07 Lawrence Mitchell , Eike Hermann Müller

The multiconfigurational time-dependent Hartree-Fock equations are discussed and solved for a one-dimensional model of the Helium atom. Results for the ground state energy and two-particle density as well as the absorption spectrum are…

Quantum Physics · Physics 2015-03-13 D. Hochstuhl , S. Bauch , M. Bonitz

In this work, we formulate and analyze a geometric multigrid method for the iterative solution of the discrete systems arising from the finite element discretization of symmetric second-order linear elliptic diffusion problems. We show that…

Numerical Analysis · Mathematics 2024-01-17 Michael Innerberger , Ani Miraçi , Dirk Praetorius , Julian Streitberger

This article presents an optimized algorithm and implementation for calculating resolution-of-the-identity Hartree-Fock (RI-HF) energies and analytic gradients using multiple Graphics Processing Units (GPUs). The algorithm is especially…

Computational Physics · Physics 2024-07-31 Ryan Stocks , Elise Palethorpe , Giuseppe M. J. Barca

The paper aims to establish a fully discrete finite element (FE) scheme and provide cost-effective solutions for one-dimensional time-space Caputo-Riesz fractional diffusion equations on a bounded domain $\Omega$. Firstly, we construct a…

Numerical Analysis · Mathematics 2017-07-27 Xiaoqiang Yue , Weiping Bu , Shi Shu , Menghuan Liu , Shuai Wang

We introduce \texttt{featom}, an open source code that implements a high-order finite element solver for the radial Schr\"odinger, Dirac, and Kohn-Sham equations. The formulation accommodates various mesh types, such as uniform or…

We resume the recent successes of the grid-based tensor numerical methods and discuss their prospects in real-space electronic structure calculations. These methods, based on the low-rank representation of the multidimensional functions and…

Numerical Analysis · Mathematics 2016-01-20 Venera Khoromskaia , Boris N. Khoromskij

The symmetry-projected Hartree--Fock ansatz for the electronic structure problem can efficiently account for static correlation in molecules, yet it is often unable to describe dynamic correlation in a balanced manner. Here, we consider a…

Strongly Correlated Electrons · Physics 2015-06-17 Carlos A. Jiménez-Hoyos , R. Rodríguez-Guzmán , Gustavo E. Scuseria

In this paper, several two-grid finite element algorithms for solving parabolic integro-differential equations (PIDEs) with nonlinear memory are presented. Analysis of these algorithms is given assuming a fully implicit time discretization.…

Numerical Analysis · Mathematics 2019-01-01 Wansheng Wang , Qingguo Hong

This contribution presents a hierarchical multigrid approach for the solution of large-scale finite cell problems on both uniform grids and multi-level hp-discretizations. The proposed scheme leverages the hierarchical nature of the basis…

Numerical Analysis · Mathematics 2021-09-08 John Jomo , Oguz Oztoprak , Frits de Prenter , Nils Zander , Stefan Kollmannsberger , Ernst Rank

A novel finite element method for the approximation of Maxwell's equations over hybrid two-dimensional grids is studied. The choice of appropriate basis functions and numerical quadrature leads to diagonal mass matrices which allow for…

Numerical Analysis · Mathematics 2022-09-22 Herbert Egger , Bogdan Radu

Within the finite-field Kohn-Sham framework, static electric response properties of diatomic molecules are presented. The electronic energy, dipole moment ({\boldmath$\mu$}), static dipole polarizability ({\boldmath$\alpha$}) and…

Chemical Physics · Physics 2019-04-26 Abhisek Ghosal , Tanmay Mandal , Amlan K. ~Roy

We present a density matrix approach for computing global solutions of Hartree-Fock theory, based on semidefinite programming (SDP), that gives upper and lower bounds on the Hartree-Fock energy of quantum systems. Equality of the upper- and…

Chemical Physics · Physics 2014-02-11 Srikant Veeraraghavan , David A. Mazziotti