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The essential postulates of classical thermodynamics are formulated, from which the second law is deduced as the principle of increase of entropy in irreversible adiabatic processes that take one equilibrium state to another. The entropy…

Soft Condensed Matter · Physics 2009-10-30 Elliott H. Lieb , Jakob Yngvason

The second law of thermodynamics can be formulated as a restriction on the evolution of the entropy of any system undergoing Markovian dynamics. Here I show that this form of the second law is strengthened for multi-dimensional, complex…

Statistical Mechanics · Physics 2024-02-14 David H. Wolpert

We present a conjugate analysis of two different dark energy models investigating both their agreement with recent data and their thermodynamical properties. The successful match with the data allows to both constrain the model parameters…

Cosmology and Nongalactic Astrophysics · Physics 2017-10-11 Vincenzo F. Cardone , Ninfa Radicella , Antonio Troisi

Based on recent data about the history of the Hubble factor, it is argued that the second law of thermodynamics holds at the largest scales accessible to observation. This is consistent with previous studies of the same question.

Cosmology and Nongalactic Astrophysics · Physics 2025-12-02 Narayan Banerjee , Purba Mukherjee , Diego Pavón

In our recent letter [1] we discussed that thermodynamics is violated in quantum Brownian motion beyond the weak coupling limit. In his comment, Tasaki [2] derives an inequality for the relative entropy and claims, without making any…

Statistical Mechanics · Physics 2007-05-23 A. E. Allahverdyan , Th. M. Nieuwenhuizen

It is nearly 150 years since Maxwell challenged the validity of the second law of thermodynamics by imagining a tiny creature who could sort the molecules of a gas in such a way that would decrease entropy without exerting any work. The…

Statistical Mechanics · Physics 2016-08-24 Ian J. Ford

We obtain macroscopic isothermal thermodynamic transformations by space-time scalings of a microscopic Hamiltonian dynamics in contact with a heat bath. The microscopic dynamics is given by a chain of anharmonic oscillators subject to a…

Statistical Mechanics · Physics 2013-10-03 Stefano Olla

The second law of thermodynamics, formulated as an ultimate bound on the maximum extractable work, has been rigorously derived in multiple scenarios. However, the unavoidable limitations that emerge due to the lack of control on small…

Quantum Physics · Physics 2016-04-27 H. Wilming , R. Gallego , J. Eisert

The universal validity of the second law of thermodynamics is widely attributed to a finely tuned initial condition of the universe. This creates a problem: why is the universe atypical? We suggest that the problem is an artefact created by…

General Relativity and Quantum Cosmology · Physics 2015-07-27 Julian Barbour , Tim Koslowski , Flavio Mercati

The present work deals with irreversible Universal thermodynamics. The homogenous and isotropic flat model of the universe is chosen as open thermodynamical system and non-equilibrium thermodynamics comes into picture due to the mechanism…

General Relativity and Quantum Cosmology · Physics 2016-05-17 Subhajit Saha , Atreyee Biswas , Subenoy Chakraborty

Thermodynamics have been applied to astronomy, biology, psychology, some social systems and so on. But, various evolutions from astronomy to biology and social systems cannot be only increase of entropy. When fluctuations are magnified due…

General Physics · Physics 2009-10-06 Yi-Fang Chang

The relationships between reversible Carnot cycles, the absence of perpetual motion machines and the existence of a non-decreasing, globally unique entropy function forms the starting point of many textbook presentations of the foundations…

Statistical Mechanics · Physics 2015-05-14 O. J. E. Maroney

The equations of fluid motions are considered in the case of internal energy depending on mass density, volume entropy and their spatial derivatives. The model corresponds to domains with large density gradients in which the temperature is…

Fluid Dynamics · Physics 2017-06-27 Henri Gouin

This article is a short version of a longer article to appear in Physics Reports (cond-mat/9708200). The essential postulates of classical thermodynamics are formulated, from which the second law is deduced as the principle of increase of…

Mathematical Physics · Physics 2007-05-23 Elliott H. Lieb , Jakob Yngvason

The second law of thermodynamics implies a relationship between the net entropy export by the Earth and its internal irreversible entropy production. The application of this constraint for the purpose of understanding Earth's climate is…

Atmospheric and Oceanic Physics · Physics 2022-01-19 Martin S. Singh , Morgan E O'Neill

The Second Law of Thermodynamics states that temporal evolution of an isolated system occurs with non-diminishing entropy. In quantum realm, this holds for energy-isolated systems the evolution of which is described by the so-called unital…

The authors of Ref. [1] claim to have experimental verification of violations of the second law of thermodynamics based on the assertions: (i) "for large systems and over long times the entropy production rate is necessarily positive"; (ii)…

Quantum Physics · Physics 2007-06-20 Elias P. Gyftopoulos

The behavior of lattice models in which time reversibility is enforced at the level of trajectories (microscopic reversibility) is studied analytically. Conditions for ergodicity breaking are explored, and a few examples of systems…

Statistical Mechanics · Physics 2025-02-17 Piero Olla

An apparent violation of the second law of thermodynamics occurs when an atom coupled to a zero-temperature bath, being necessarily in an excited state, is used to extract work from the bath. Here the fallacy is that it takes work to couple…

Quantum Physics · Physics 2009-11-13 G. W. Ford , R. F. O'Connell

Recent theoretical research on the fundamentals of statistical mechanics has led to a remarkable discovery [2-4]: with a locally nonchaotic energy barrier, a macroscopic system may produce useful work in a cycle by absorbing heat from a…

Soft Condensed Matter · Physics 2025-11-10 Yu Qiao , Meng Wang