Related papers: Isotope shift calculations for atoms with one vale…
Decoherence caused by nuclear field fluctuations is a fundamental obstacle to the realization of quantum information processing using single electron spins. Alternative proposals have been made to use spin qubits based on valence band holes…
We demonstrate that several metastable excited states in Hf$~$II, Hf$~$IV and W$~$VI ions may be good clock states since they are sufficiently long-living and are not sensitive to the perturbations. Cooling E1 transitions are available.…
In our work we construct a Hamiltonian, whose eigenstates approximate the solutions of the self-consistent Hartree-Fock equations for nonrelativistic atoms and ions. Its eigenvalues are given by completely algebraic expressions and the…
Optical spectroscopy in the gas phase is a key tool to elucidate the structure of atoms and molecules and of their interaction with external fields. The line resolution is usually limited by a combination of first-order Doppler broadening…
Our study is motivated by the prospect of several metastable states in the Sb$ ^{+} $, Au$ ^{+} $, and Hg$ ^{2+} $ ions being used as possible candidates for optical clocks. We calculate several atomic properties relevant to the development…
In this paper we report on internal conversion coefficients for Z = 111 to Z = 126 superheavy elements obtained from relativistic Dirac-Fock (DF) calculations. The effect of the atomic vacancy created during the conversion process has been…
The mass sensitivity of the vibration-rotation-inversion transitions of H$_3{}^{16}$O$^+$, H$_3{}^{18}$O$^+$, and D$_3{}^{16}$O$^+$ is investigated variationally using the nuclear motion program TROVE~\citep{TROVE:2007}. The calculations…
Most modern calculations of many-electron atoms use basis sets of atomic orbitals. An accurate account for the electronic correlations in heavy atoms is very difficult computational problem and optimization of the basis sets can reduce…
We present an effective field theory (EFT) for a model-independent description of deformed atomic nuclei. In leading order this approach recovers the well-known results from the collective model by Bohr and Mottelson. When higher-order…
The ac Stark shift of hyperfine levels of neutral atoms can be calculated using the third order perturbation theory(TOPT), where the third order corrections are quadratic in the atom-photon interaction and linear in the hyperfine…
We present a nucleus-dependent valence-space approach for calculating ground and excited states of nuclei, which generalizes the shell-model in-medium similarity renormalization group to an ensemble reference with fractionally filled…
We present a simple method for determination of absolute vibrational numbering of isolated near dissociation levels in diatomic molecules, usually observed in cold physics experiments. The method is based on the isotope shift and works even…
We show that the energy of a perturbed system can be fully recovered from the unperturbed system's electron density. We derive an alchemical integral transform by parametrizing space in terms of transmutations, the chain rule and…
The structure of the $N \approx Z$ nuclei $^{66}$Ge and $^{68}$Ge is studied by the shell model on a spherical basis. The calculations with an extended $P+QQ$ Hamiltonian in the configuration space ($2p_{3/2}$, $1f_{5/2}$, $2p_{1/2}$,…
Theories unifying gravity and other interactions suggest the possibility of spatial and temporal variation of physical ``constants''. Accuracy achieved for the atomic optical frequency standards (optical clocks) approaches the level when…
In the work [1], within the framework of a dipole approximation for the radiation transition operator, of the second-order nonrelativistic quantum perturbation theory and the Hartree-Fock single-configuration approximation, the first…
Here, we propose a new modified quantum mechanics and its new algorithms of atomic fine-structure,asymmetric variational method based on hydrogen-like atom orbit. In addition, as we all know, the ab initio calculation of atomic…
Isotope separation is one of the grand challenges of modern society and holds great potential for basic science, medicine, energy, and defense. We consider here a new and general approach to isotope separation. The method is based on an…
In this paper we study theoretically the process of electron capture between one-optical-electron atoms (e.g. hydrogenlike or alkali atoms) and ions at low-to-medium impact velocities (v/v_e <= 1) working on a modification of an already…
The analysis of shape transitions in Nd isotopes, based on the framework of relativistic energy density functionals and restricted to axially symmetric shapes in Ref. \cite{PRL99}, is extended to the region $Z = 60$, 62, 64 with $N \approx…