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An ultrafast mechanism belonging to the family of interatomic Coulombic decay (ICD) phenomena is proposed. When two excited species are present, an ultrafast energy transfer can take place bringing one of them to its ground state and…

An excited two-atom system can decay via different competing relaxation processes. If the excess energy is sufficiently high the system may not only relax via spontaneous emission but can also undergo interatomic Coulombic decay (ICD) or…

Quantum Physics · Physics 2022-04-27 Janine Franz , Stefan Yoshi Buhmann

Light-induced energy confinement in nanoclusters via plasmon excitations influences applications in nanophotonics, photocatalysis, and the design of controlled slow electron sources. The resonant decay of these excitations through the…

Atomic and Molecular Clusters · Physics 2023-06-21 Rasheed Shaik , Hari R. Varma , Mohamed El-Amine Madjet , Fulu Zheng , Thomas Frauenheim , Himadri S. Chakraborty

As opposed to purely molecular systems where electron dynamics proceed only through intramolecular processes, weakly bound complexes such as He droplets offer an environment where local excitations can interact with neighbouring embedded…

Atomic and Molecular Clusters · Physics 2021-04-15 A. C. LaForge , M. Shcherbinin , F. Stienkemeier , R. Richter , R. Moshammer , T. Pfeifer , M. Mudrich

Dissipation in granular media leads to interesting phenomena as there are cluster formation and crystallization in non-equilibrium dynamical states. The freely cooling system is examined concerning the energy decay and the cluster evolution…

Statistical Mechanics · Physics 2009-11-10 S. Miller , S. Luding

In interatomic Coulombic electron capture, the capture of a free electron at an atomic center is accompanied by the radiationless transfer of the excess energy to a neighboring atom of different species, leading to ionization of the latter.…

Atomic Physics · Physics 2023-04-19 S. Remme , A. B. Voitkiv , C. Müller

The emission of an Auger electron is the predominant relaxation mechanism of core-vacant states in molecules composed of light nuclei. In this non-radiative decay process, one valence electron fills the core vacancy while a second valence…

Chemical Physics · Physics 2023-01-24 Florian Matz , Thomas-C. Jagau

For the asymmetric spherical dimer of an endohedrally confined atom and a host fullerene, an innershell vacancy of either system can decay through the continuum of an outer electron hybridized between the systems. Such decays, viewed as…

Atomic and Molecular Clusters · Physics 2021-06-08 Maia Magrakvelidze , Ruma De , Mohammad H. Javani , Mohamed E. Madjet , Steven T. Manson , Himadri S. Chakraborty

We provide the experimental evidence that the single electron capture process in slow collisions between O$^{3+}$ ions and neon dimer targets leads to an unexpected production of low-energy electrons. This production results from the…

Electron-impact ionization of an atom or ion in the presence of a neighboring atom is studied. The latter is first collisionally excited by the incident electron, whose energy is assumed to be high but nonrelativistic. Afterwards, the…

Atomic Physics · Physics 2019-11-06 F. Grüll , A. B. Voitkiv , C. Müller

When a vacancy is created in an inner-valence orbital of a dimer of atoms or molecules, the resulting species can undergo interatomic/intermolecular Coulombic decay (ICD): the hole is filled through a relaxation process that leads to a…

Chemical Physics · Physics 2023-05-18 Valentina Parravicini , Thomas-C. Jagau

Atoms and molecules attached to rare gas clusters are ionized by an interatomic autoionization process traditionally termed 'Penning ionization' when the host cluster is resonantly excited. Here we analyze this process in the light of the…

We study the direct incoherent energy transfer from an immobile excited donor molecule to acceptor molecules, which are all attached to polymer chains, randomly arranged in a viscous solvent. The decay forms are found explicitly, in terms…

Condensed Matter · Physics 2008-02-03 G. Oshanin , J. De Coninck , A. Blumen , S. F. Burlatsky , M. Moreau

We report on the experimental observation of interatomic Coulombic decay (ICD) in pure $^4$He nanoclusters of mean sizes between $N \approx$ 5000 and 30000 and the subsequent scattering of energetic He$^+$ fragments inside the neutral…

Molecular mechanisms that enable collective and upconverted energy transfer from multiple photoacceptors to a non-absorbing spectator reaction center are highly desirable for efficient light-energy utilization. Here, we show that…

Chemical Physics · Physics 2026-03-05 Saroj Barik , Pratikkumar Thakkar , Siddhartha S. Payra , Yash Lenka , Y. Sajeev , G. Aravind

In a multi-electron atom, an excited electron can decay by emitting a photon. Typically, the leftover electrons are in their ground state. In a radiative Auger process, the leftover electrons are in an excited state and a redshifted photon…

In the presence of a neighboring atom, electron-ion recombination can proceed resonantly via excitation of an electron in the atom, with subsequent relaxation through radiative decay. It is shown that this two-center dielectronic process…

Atomic Physics · Physics 2015-03-13 C. Müller , A. B. Voitkiv , J. R. Crespo López-Urrutia , Z. Harman

We demonstrate that the Auger decay rate in an endohedral atom is very sensitive to the atom's location in the fullerene cage. Two additional decay channels appear in an endohedral system: (a) the channel due to the change in the electric…

Atomic and Molecular Clusters · Physics 2015-05-20 Andrey V. Korol , Andrey V. Solov'yov

Understanding the interaction between metal ions and their aqueous environment is fundamental in many areas of chemistry, biology, and environmental science. In this study, we investigate the electronic structure of hydrated calcium ions,…

The Zeeman-split spin states of a single quantum dot can be used together with its optical trion transitions to form a spin-photon interface between a stationary (the spin) and a flying (the photon) quantum bit. Besides long coherence times…

Mesoscale and Nanoscale Physics · Physics 2021-10-26 Hendrik Mannel , Jens Kerski , Pia Lochner , Marcel Zöllner , Andreas D. Wieck , Arne Ludwig , Axel Lorke , Martin Geller
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