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Double and triple ionization of allene are investigated using electron-electron, ion-ion, electron-electron-ion and electron-electron-ion-ion (ee, ii, eei, eeii) coincidence spectroscopies at selected photon energies. The results provide…

Photoionization cross sections and rate coefficients have been calculated for all bound vibrational levels of the 1s$\sigma_{\mathrm{g}}$ state of H$_{2}^{+}$, HD$^{+}$, and D$_{2}^{+}$. The Born-Oppenheimer approximation is employed in our…

Atomic Physics · Physics 2023-11-03 Adam Singor , Liam H. Scarlett , Mark C. Zammit , Igor Bray , Dmitry V. Fursa

We outline a non-perturbative procedure for calculating the total photoionization cross-section of two-electron atomic systems. The procedure is based on the Floquet-Fourie representation of the solution of the time-dependent Schrodinger…

Atomic Physics · Physics 2007-05-23 I. A. Ivanov , A. S. Kheifets

This article is a continuation of our previous work (Phys. Rev. A 88, 032511 (2013)). The prefactors for the partial-wave expansion of the helium atom are derived. Due to series of cancellations, the partial-wave increments of the energy…

Atomic Physics · Physics 2021-07-06 Cong Wang

We calculate the hydrogen molecule ion from the two particle Schr"odinger equation. Therefore a very simple two particle basis set is chosen. We suggest this ansatz to be used to solve the "two electron one phonon" three particle…

Quantum Physics · Physics 2007-05-23 D. Schmicker

Single, double, and triple ionization of the C+ ion by a single photon have been investigated in the energy range 286 to 326 eV around the K-shell single-ionization threshold at an unprecedented level of detail. At energy resolutions as low…

New approach to highly accurate calculations of the photodetachment cross-sections of the negatively charged hydrogen ions is developed. This effective, fast and numerically stable method is based on the use of the Rayleigh's formula for…

Solar and Stellar Astrophysics · Physics 2015-09-09 Alexei M. Frolov

High-resolution photoionization experiments were carried out using beams of Be-like C$^{2+}$, N$^{3+}$, and O$^{4+}$ ions with roughly equal populations of the $^1$S ground-state and the $^3$P$^o$ manifold of metastable components. The…

Earth and Planetary Astrophysics · Physics 2012-03-30 A Müller , S Schippers , R. A. Phaneuf , A. L. D. Kilcoyne , H. Bräuning , A. S. Schlachter , M. Lu , B. M. McLaughlin

High accuracy helium wave functions based on exponentials with random coefficients are transformed into momentum space. The utility of the wave functions is demonstrated through calculation of the expectation value of various operators…

Atomic Physics · Physics 2009-11-10 J. Sapirstein

The form of the wave function at three-electron coalescence points is examined for several spin states using an alternative method to the usual Fock expansion. We find that, in two- and three-dimensional systems, the non-analytical nature…

Chemical Physics · Physics 2016-01-18 Pierre-François Loos , Nathaniel J. Bloomfield , Peter M. W. Gill

We show that it is possible to change not only s-wave but also higher partial wave atom-atom interactions in cold collision in the presence of relatively intense laser fields tuned near a photoassociative transition.

Atomic Physics · Physics 2015-05-13 Bimalendu Deb , Jisha Hazra

Relations between particle and wave properties for charge carriers in periodic potentials of crystalline metals and semiconductors are derived. The particle aspects of electrons and holes in periodic potentials are considered using…

Mesoscale and Nanoscale Physics · Physics 2020-07-15 Wlodek Zawadzki

We determine two-particle scattering phase shifts and mixing angles for quantum theories defined with lattice regularization. The method is suitable for any nonrelativistic effective theory of point particles on the lattice. In the…

Nuclear Theory · Physics 2008-11-26 Bugra Borasoy , Evgeny Epelbaum , Hermann Krebs , Dean Lee , Ulf-G. Meißner

The $m \alpha^6$ correction to energy is expressed in terms of an effective Hamiltonian $H^{(6)}$ for an arbitrary state of helium. Numerical calculations are performed for $n=2$ levels, and the previous result for the $2^3P$ centroid is…

Atomic Physics · Physics 2009-11-13 Krzysztof Pachucki

Aims. In this work we rigorously show the shortcomings of various simplifications that are used to calculate the total internal partition function. These shortcomings can lead to errors of up to 40 percent or more in the estimated partition…

Chemical Physics · Physics 2016-11-16 Andrius Popovas , Uffe G. Jørgensen

We present an analytic formulation to model the fluctuating component of the HI signal from the epoch of reionization during the phase of partial heating. During this phase, we assume self-ionized regions, whose size distribution can be…

Cosmology and Nongalactic Astrophysics · Physics 2018-06-14 Janakee Raste , Shiv Sethi

We develop a model for predicting fine- and hyperfine intensities in the direct photoionization of molecules based on the separability of electron and nuclear spin states from vibrational-electronic states. Using spherical tensor algebra,…

Chemical Physics · Physics 2016-08-24 Matthias Germann , Stefan Willitsch

Partial atomic charges are a useful and intuitive concept for understanding molecular properties and chemical reaction mechanisms, showing how changes in molecular geometry can affect the flow of electronic charge within a molecule.…

Chemical Physics · Physics 2022-01-14 Ryan J. MacDonell , Serguei Patchkovskii , Michael S. Schuurman

We present ab-initio calculations of the binding energy and radii of the two-neutron halo nucleus 6He using two-body low-momentum interactions based on chiral effective field theory potentials. Calculations are performed via a…

Nuclear Theory · Physics 2015-06-04 S. Bacca , N. Barnea , A. Schwenk

We present first-principles theoretical determination of the three-body polarizability and the third dielectric virial coefficient of helium. Coupled-cluster theory and the full configuration interaction procedure were used to perform…

Chemical Physics · Physics 2023-03-29 Jakub Lang , Michal Lesiuk , Michal Przybytek , Bogumil Jeziorski