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Related papers: Molecular Alignment and Orientation: From Laser-In…

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We study interaction of generic asymmetric molecules with a pair of strong time-delayed short laser pulses with crossed linear polarizations. We show that such an excitation not only provides unidirectional rotation of the most polarizable…

Chemical Physics · Physics 2018-02-28 E. Gershnabel , I. Sh. Averbukh

Laser cooling and trapping of atoms and atomic ions has led to numerous advances including the observation of exotic phases of matter, development of exquisite sensors and state-of-the-art atomic clocks. The same level of control in…

We demonstrate that the current laser technology used for field-free molecular alignment via a cascade of Raman rotational transitions allows for observing long-discussed non-linear quantum phenomena in the dynamics of the periodically…

Quantum Physics · Physics 2015-05-30 Johannes Floß , Ilya Sh. Averbukh

A gradient-based optimization approach combined with automatic differentiation is employed to ensure high accuracy and scalability when working with high-dimensional parameter spaces. Numerical simulations confirm the effectiveness of the…

Quantum Physics · Physics 2025-07-15 Roman Sahakyan , Romik Sargsyan , Edgar Pogosyan , Karen Arzumanyan , Emil A. Gazazyan

We present a practical roadmap to achieve optical cycling and laser cooling of asymmetric top molecules (ATMs). Our theoretical analysis describes how reduced molecular symmetry, as compared to diatomic and symmetric non-linear molecules,…

Atomic Physics · Physics 2020-08-05 Benjamin L. Augenbraun , John M. Doyle , Tanya Zelevinsky , Ivan Kozyryev

The recent progress towards production of near-ground state quantum-degenerate molecules raises the issue of how such "small" molecules behave in an optical lattice. In this Letter we show that the coupling of the molecular orientation to…

Other Condensed Matter · Physics 2007-07-09 J. R. Holt , J. M. F. Gunn

We propose a new formulation of optimal and local control algorithms which enforces the constraint of time-integrated zero-area on the control field. The fulfillment of this requirement, crucial in many physical applications, is…

Quantum Physics · Physics 2015-06-22 D. Sugny , S. Vranckx , M. Ndong , O. Atabek , M. Desouter-Lecomte

The training of molecular models of quantum mechanical properties based on statistical machine learning requires large datasets which exemplify the map from chemical structure to molecular property. Intelligent a priori selection of…

By means of optimal control techniques we model and optimize the manipulation of the external quantum state (center-of-mass motion) of atoms trapped in adjustable optical potentials. We consider in detail the cases of both non interacting…

In this work, we investigate how and to which extent a quantum system can be driven along a prescribed path in Hilbert space by a suitably shaped laser pulse. To calculate the optimal, i.e., the variationally best pulse, a properly defined…

Quantum Physics · Physics 2007-05-23 I. Serban , J. Werschnik , E. K. U. Gross

Experimental multi-objective Quantum Control is an emerging topic within the broad physics and chemistry applications domain of controlling quantum phenomena. This realm offers cutting edge ultrafast laser laboratory applications, which…

Neural and Evolutionary Computing · Computer Science 2011-12-23 Ofer M. Shir , Jonathan Roslund , Zaki Leghtas , Herschel Rabitz

We investigate the full control over the orientation of a non-symmetric molecule by using moderate and weak electric fields. Quantum Optimal Control techniques allow us to orient any axis of 6-chloropyridazine-3-carbonitrile, which is taken…

Quantum Physics · Physics 2023-11-21 Rosario González-Férez , Juan J. Omiste

Following excitation by a strong ultra-short laser pulse, molecules develop coordinated rotational motion, exhibiting transient alignment along the direction of the laser electric field, followed by periodic full and fractional revivals…

Quantum Physics · Physics 2007-05-23 Sharly Fleischer , Ilya. Sh. Averbukh , Yehiam Prior

Coherent control of chaotic molecular systems, using laser-assisted alignment of sulphur dioxide (SO$_2$) molecules in the presence of a static electric field as an example, is considered. Conditions for which the classical version of this…

Chemical Physics · Physics 2017-04-26 Johannes Floß , Paul Brumer

Genetic learning algorithms are widely used to control ultrafast optical pulse shapes for photo-induced quantum control of atoms and molecules. An unresolved issue is how to use the solutions found by these algorithms to learn about the…

Quantum Physics · Physics 2009-11-10 J. L. White , B. J. Pearson , P. H. Bucksbaum

The development of ultra-intense laser-based sources of high energy ions is an important goal, with a variety of potential applications. One of the barriers to achieving this goal is the need to maximize the conversion efficiency from laser…

Significant molecular orientation can be achieved by time-symmetric single-cycle pulses of zero area, in the THz region. We show that in spite of the existence of a combined time-space symmetry operation, not only large peak instantaneous…

Chemical Physics · Physics 2012-10-22 Juan Ortigoso

Half-cycle laser pulse is applied on an absorbed molecule to investigate its alignment and orientation behavior. Crossover from field-free to hindered rotation motion is observed by varying the angel of hindrance of potential well. At small…

Atomic Physics · Physics 2007-05-23 Y. Y. Liao , Y. N. Chen , D. S. Chuu

Starting with the basic control system model often employed in NMR pulse design, we derive more realistic control system models taking into account effects such as off-resonant excitation for systems with fixed inter-qubit coupling…

Quantum Physics · Physics 2009-10-01 Sonia Schirmer

We present a quantum dynamic study on organic lasing phenomena, which is a challenging issue in organic optoelectronics. Previously, phenomenological method has achieved success in describing experimental observation. However, it cannot…

Chemical Physics · Physics 2023-08-07 Bin Zhang , Zhigang Shuai
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