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We have investigated the ultracold interspecies scattering properties of metastable triplet He and Rb. We performed state-of-the-art ab initio calculations of the relevant interaction potential, and measured the interspecies elastic cross…

Ultracold collisions of the polyatomic species CaOH are considered, in internal states where the collisions should be dominated by long-range dipole-dipole interactions. The computed rate constants suggest that evaporative cooling can be…

Chemical Physics · Physics 2019-06-25 Lucie D. Augustovičová , John L. Bohn

Inelastic collision rates for ultracold $^{85}$Rb atoms in the F=2 m$_{f}$=-2 state have been measured as a function of magnetic field. Dramatic change in the vicinity of a Feshbach resonance at 155 G was observed. Similar to the elastic…

Atomic Physics · Physics 2009-11-06 J. L. Roberts , N. R. Claussen , S. L. Cornish , C. E. Wieman

We present quantum-theoretical studies of collisions between an open-shell S-state atom and a ^2Pi-state molecule in the presence of a magnetic field. We analyze the collisional Hamiltonian and discuss possible mechanisms for inelastic…

An intriguing phenomenon in molecular collisions is the occurrence of scattering resonances, which originate from bound and quasi-bound states supported by the interaction potential at low collision energies. The resonance effects in the…

Charge exchange collisions between ultracold fermionic 6Li atoms and 40Ca+ ions are observed in the mK temperature range. The reaction product of the charge exchange collision is identified via mass spectrometry during which the motion of…

Atomic Physics · Physics 2015-04-01 Shinsuke Haze , Ryoichi Saito , Munekazu Fujinaga , Takashi Mukaiyama

We present first steps toward understanding the ultracold scattering properties of polar molecules in strong electric field-seeking states. We have found that the elastic cross section displays a quasi-regular set of potential resonances as…

Atomic Physics · Physics 2009-11-11 Christopher Ticknor , John L. Bohn

Accurate knowledge of interaction potentials among the alkali atoms and alkaline earth ions is very useful in the studies of cold atom physics. Here we carry out theoretical studies of the long-range interactions among the Li, Na, K, and Rb…

Atomic Physics · Physics 2014-09-26 Jasmeet Kaur , D. K. Nandy , Bindiya Arora , B. K. Sahoo

Rigorous quantum scattering calculations on ultracold molecular collisions in external fields present an outstanding computational problem due to strongly anisotropic atom-molecule interactions that depend on the relative orientation of the…

Atomic Physics · Physics 2020-12-03 Masato Morita , Jacek Kłos , Timur V. Tscherbul

We observe long-range $^{85}$Rb and $^{87}$Rb (24$D$+5$S_{1/2}$) Rydberg molecules for eight different spin couplings, with binding energies up to 440~MHz and sub-percent relative uncertainty. Isotopic effects of the molecular binding…

Atomic Physics · Physics 2020-01-15 Jamie L. MacLennan , Yun-Jhih Chen , Georg Raithel

The scattering length is commonly used to characterize the strength of ultracold atomic interactions, since it is the leading parameter in the low-energy expansion of the scattering phase shift. Its value can be modified via a magnetic…

Atomic Physics · Physics 2009-11-13 Bout Marcelis , Boudewijn Verhaar , Servaas Kokkelmans

We theoretically investigate the properties of highly polar diatomic molecules containing $^2S$-state transition-metal atoms. We calculate potential energy curves, permanent electric dipole moments, spectroscopic constants, and leading…

Atomic Physics · Physics 2021-02-16 Michał Śmiałkowski , Michał Tomza

The interaction between a Rydberg electron and a neutral atom situated inside its extended orbit is described via contact interactions for each atom-electron scattering channel. In ultracold environments, these interactions lead to…

Atomic Physics · Physics 2017-05-10 Matthew T Eiles , Chris H Greene

We measure inelastic collisions between ultracold CaF molecules by combining two optical tweezers, each containing a single molecule. We observe collisions between $^2\Sigma$ CaF molecules in the absolute ground state $|X,v=0,…

We establish the existence of a fundamental limit to the efficiency of spin-exchange optical pumping of 3He nuclei by collisions with spin-polarized alkali-metal atoms. Using accurate ab initio calculations of molecular interactions and…

Atomic Physics · Physics 2012-02-06 T. V. Tscherbul , P. Zhang , H. R. Sadeghpour , A. Dalgarno

Ultracold molecules undergo "sticky collisions" that result in loss even for chemically nonreactive molecules. Sticking times can be enhanced by orders of magnitude by interactions that lead to non-conservation of nuclear spin or total…

Atomic Physics · Physics 2022-12-07 Marijn P Man , Gerrit C Groenenboom , Tijs Karman

We present a treatment of cold hydrogen-antihydrogen collisions based on the asymptotic properties of atom-antiatom interactions. We derive general formulas for the elastic and inelastic cross sections and for the scattering lengths and…

Atomic Physics · Physics 2009-11-13 A. Yu. Voronin , P. Froelich

Elastic and spin-changing inelastic collision cross sections are presented for cold and ultracold magnetically trapped NH. The cross sections are obtained from coupled-channel scattering calculations as a function of energy and magnetic…

In this paper we investigate the effective scattering length $a$ of spin-polarized Ne*. Due to its anisotropic electrostatic interaction, its scattering length is determined by five interaction potentials instead of one, even in the…

Atomic Physics · Physics 2009-11-10 V. P. Mogendorff , E. J. D. Vredenbregt , B. J. Verhaar , H. C. W. Beijerinck

We investigate the interactions between ultracold alkali metal atoms and closed-shell atoms using electronic structure calculations on the prototype system Rb+Sr. There are molecular bound states that can be tuned across atomic thresholds…

Atomic Physics · Physics 2015-05-19 Piotr S. Zuchowski , J. Aldegunde , Jeremy M. Hutson