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The change from the diffusion-limited to the reaction-limited cooperative behaviour in reaction-diffusion systems is analysed by comparing the universal long-time behaviour of the coagulation-diffusion process on a chain and on the Bethe…

Statistical Mechanics · Physics 2018-10-29 Dmytro Shapoval , Maxym Dudka , Xavier Durang , Malte Henkel

Steric or attractive interactions among reactants or between reactants and inert crowders can substantially influence the total rate of a diffusion-influenced reaction in the liquid phase. However, the role of the product species, that has…

Chemical Physics · Physics 2018-04-19 Rafael Roa , Toni Siegl , Won Kyu Kim , Joachim Dzubiella

Chemical reactions involve the movement of charges, and this work presents a mathematical model for describing chemical reactions in electrolytes. The model is developed using an energy variational method that aligns with classical…

Chemical Physics · Physics 2023-11-02 Shixin Xu , Robert Eisenberg , Zilong Song , Huaxiong Huang

Large transverse momentum distributions of identified particles observed at RHIC are analyzed by a relativistic stochastic model in the three dimensional rapidity space. Temperature for inclusive reactions is estimated.

High Energy Physics - Phenomenology · Physics 2007-05-23 Naomichi Suzuki , Minoru Biyajima

Molecular dynamics simulations are used to study the mechanism and kinetics of hydrated electron diffusion. The electron center of mass is found to exhibit Brownian-type behavior with a diffusion coefficient considerably greater than that…

Chemical Physics · Physics 2012-11-06 Kafui A. Tay , François-Xavier Coudert , Anne Boutin

A diffusion-limited annihilation process, A+B->0, with species initially separated in space is investigated. A heuristic argument suggests the form of the reaction rate in dimensions less or equal to the upper critical dimension $d_c=2$.…

Condensed Matter · Physics 2016-08-31 P. L. Krapivsky

The reaction-diffusion master equation (RDME) is commonly used to model processes where both the spatial and stochastic nature of chemical reactions need to be considered. We show that the RDME in many cases is inconsistent with a…

Quantitative Methods · Quantitative Biology 2009-05-29 Paul Sjoberg , Otto G Berg , Johan Elf

A reaction-diffusion model of receptor-toxin-antibody (RTA) interaction is studied numerically. The protective properties of an antibody against a given toxin are evaluated for a spherical cell placed into a toxin-antibody solution. The…

Cell Behavior · Quantitative Biology 2012-06-06 P. Katauskis , P. Skakauskas , A. Skvortsov

Reaction dynamics involving subdiffusive species is an interesting topic with only few known results, especially when the motion of different species is characterized by different anomalous diffusion exponents. Here we study the reaction…

Soft Condensed Matter · Physics 2009-11-11 S. B. Yuste , Katja Lindenberg

A system of a parabolic partial differential equation coupled with ordinary differential inclusions that arises from a closed-loop control problem for a thermodynamic process governed by the Allen-Cahn diffusion reaction model is studied. A…

Optimization and Control · Mathematics 2011-09-22 Grzegorz Dudziuk , Marek Niezgódka

We consider a reaction-diffusion system where some components react and diffuse on the boundary of a region, while other components diffuse in the interior and react with those on the boundary through mass transport. We establish local…

Analysis of PDEs · Mathematics 2015-11-20 Vandana Sharma , Jeff Morgan

We have developed a simulation tool to model self-limited processes such as atomic layer deposition and atomic layer etching inside reactors of arbitrary geometry. In this work, we have applied this model to two standard types of cross-flow…

Applied Physics · Physics 2024-06-19 Angel Yanguas-Gil , Joseph A. Libera , Jeffrey W. Elam

We study the blow up solutions of a semilinear reaction diffusion system coupled in both equations and boundary conditions. The main purpose is to understand how the reaction terms and the absorption terms affect the blow-up properties. We…

Analysis of PDEs · Mathematics 2016-11-26 Maan A. Rasheed , Miroslav Chlebik

We study a micro and macroscopic model for chemical reactions with feedback between reactions and temperature of the solute. The first result concerns the quasipotential as the large-deviation rate of the microscopic invariant measure. The…

Mathematical Physics · Physics 2021-11-25 D. R. Michiel Renger

We study the effect of confinement on diffusion limited bimolecular reactions within a lattice model where a small number of reactants diffuse amongst a much larger number of inert particles. When the number of inert particles is held…

Soft Condensed Matter · Physics 2013-05-29 Jeremy D. Schmit , Ercan Kamber , Jané Kondev

We develop a microscopic theory for reaction-difusion (R-D) processes based on a generalization of Einstein's master equation with a reactive term and we show how the mean field formulation leads to a generalized R-D equation with…

Statistical Mechanics · Physics 2015-05-30 Jean Pierre Boon , James F. Lutsko , Christopher Lutsko

This paper is devoted to the study of systems of reaction-cross diffusion equations arising in population dynamics. New results of existence of weak solutions are presented, allowing to treat systems of two equations in which one of the…

Analysis of PDEs · Mathematics 2014-10-28 Laurent Desvillettes , Thomas Lepoutre , Ayman Moussa , Ariane Trescases

The nucleus-nucleus potential and energy dissipation in fusion reactions are obtained from microscopic mean-field dynamics. The deduced potentials nicely reproduce the one extracted from experimental data. Energy dissipation shows a…

Nuclear Theory · Physics 2015-05-14 Kouhei Washiyama , Denis Lacroix , Sakir Ayik

We develop an efficient method to calculate probabilities of large deviations from the typical behavior (rare events) in reaction--diffusion systems. The method is based on a semiclassical treatment of underlying "quantum" Hamiltonian,…

Statistical Mechanics · Physics 2009-11-10 Vlad Elgart , Alex Kamenev

We study a model for unimolecular reaction on a supported catalyst including reactant diffusion and desorption, using analytical methods and scaling concepts. For rapid reactions, enhancing surface diffusion or increasing particle size…

Statistical Mechanics · Physics 2009-06-18 T. G. Mattos , Fabio D. A. Aarao Reis
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