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We provide a simple physical interpretation, in the context of the second law of thermodynamics, to the information inequality (a.k.a. the Gibbs' inequality, which is also equivalent to the log-sum inequality), asserting that the relative…

Information Theory · Computer Science 2009-03-29 Neri Merhav

A microscopic definition of the thermodynamic entropy in an isolated quantum system must satisfy (i) additivity, (ii) extensivity and (iii) the second law of thermodynamics. We show that the diagonal entropy, which is the Shannon entropy in…

Statistical Mechanics · Physics 2015-03-30 Tatsuhiko N. Ikeda , Naoyuki Sakumichi , Anatoli Polkovnikov , Masahito Ueda

We consider the statistical irreversibility and its compatibility with the reversible dynamics. The role played by the observation is analyzed in detail. It makes our previous proof for the second law of thermodynamics clearer. On this…

Statistical Mechanics · Physics 2012-02-24 Qi-Ren Zhang

The entropy production is commonly interpreted as measuring the distance from equilibrium. However, this explanation lacks a rigorous description due to the absence of a natural equilibrium measure. The present analysis formalizes this…

Statistical Mechanics · Physics 2025-10-23 David Andrieux

Shannon entropy was defined for probability distributions and then its using was expanded to measure the uncertainty of knowledge for systems with complete information. In this article, it is proposed to extend the using of Shannon entropy…

Information Theory · Computer Science 2017-09-15 Vasile Patrascu

All of the basic microsopic physical laws are time reversible. In contrast, the second law of thermodynamics, which is a macroscopic physical representation of the world, is able to describe irreversible processes in an isolated system…

Chemical Physics · Physics 2015-06-19 Roland Riek

We demonstrate that irreversibility arises from the principle of microscopic reversibility and the presence of memory in the time evolution of a single copy of a system driven by a protocol. We introduce microscopic reversibility by using…

Statistical Mechanics · Physics 2015-11-30 J. Ricardo Arias-Gonzalez

Upper and lower bounds are obtained for the joint entropy of a collection of random variables in terms of an arbitrary collection of subset joint entropies. These inequalities generalize Shannon's chain rule for entropy as well as…

Information Theory · Computer Science 2024-05-07 Mokshay Madiman , Prasad Tetali

We study how the Shannon entropy of sequences produced by an information source converges to the source's entropy rate. We synthesize several phenomenological approaches to applying information theoretic measures of randomness and memory to…

Statistical Mechanics · Physics 2007-05-23 James P. Crutchfield , David P. Feldman

We obtain macroscopic adiabatic thermodynamic transformations by space-time scalings of a microscopic Hamiltonian dynamics subject to random collisions with the environment. The microscopic dynamics is given by a chain of oscillators…

Statistical Mechanics · Physics 2014-12-12 Stefano Olla , Marielle Simon

Linear, irreversible thermodynamics predicts that the entropy production rate can become negative. We demonstrate this prediction for metals under AC-driving whose conductivity is well-described by the Drude-Sommerfeld model. We then show…

Statistical Mechanics · Physics 2022-01-26 Marcus V. S. Bonança , Sebastian Deffner

Statistical thermodynamics is valuable as a conceptual structure that shapes our thinking about equilibrium thermodynamic states. A cloud of unresolved questions surrounding the foundations of the theory could lead an impartial observer to…

Statistical Mechanics · Physics 2025-10-31 O. B. Ericok , J. K. Mason

Nonreciprocal interactions are commonplace in continuum-level descriptions of both biological and synthetic active matter, yet studies addressing their implications for time-reversibility have so far been limited to microscopic models.…

Statistical Mechanics · Physics 2023-04-19 Henry Alston , Luca Cocconi , Thibault Bertrand

Fisher information, Shannon information entropy and Statistical Complexity are calculated for the interface of a normal metal and a superconductor, as a function of the temperature for several materials. The order parameter $\Psi({\bf r})$…

Quantum Physics · Physics 2018-06-05 Ch. C. Moustakidis , C. P. Panos

We demonstrate that Shannon's information entropy and the thermodynamic entropy of Boltzmann and Gibbs are quantitatively equivalent for real condensed-matter systems. By interpreting atomic configurations as information sources, we compute…

Statistical Mechanics · Physics 2025-12-03 Dallin Fisher , Qi-Jun Hong

We investigate how undecidability enters into computations of classical physical systems and contributes to the increase of entropy and loss of information. In actual computation with finite bit of information capacity we accept…

Statistical Mechanics · Physics 2008-03-13 Sungyun Kim

The application of the Shannon entropy to study the relationship between information and structures has yielded insights into molecular and material systems. However, the difficulty in directly observing and manipulating atoms and molecules…

There are several inequalities in physics which limit how well we can process physical systems to achieve some intended goal, including the second law of thermodynamics, entropy bounds in quantum information theory, and the uncertainty…

Quantum Physics · Physics 2016-07-19 Francesco Buscemi , Siddhartha Das , Mark M. Wilde

We demonstrate that the Gibbs-Shannon entropy is applicable to non-equilibrium systems of any size and boundary conditions. The change in microscopic entropy can be attributed to the stochastic nature of dynamic processes and to the…

Statistical Mechanics · Physics 2020-10-13 Jianzhong Wu

A thermodynamic framework for asymptotic inference is developed in which sample size and parameter variance define a state space. Within this description, Shannon information plays the role of entropy, and an integrating factor organizes…

Information Theory · Computer Science 2026-03-26 Willy Wong