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This article provides a review of recent work in the field of helium nanodroplet spectroscopy with emphasis on the dynamical aspects of the interactions between molecules in helium as well as their interaction with this unique quantum…

Chemical Physics · Physics 2009-11-11 Frank Stienkemeier , Kevin K Lehmann

The dynamics of vibrational wave packets excited in Na2 dimers in the triplet ground and excited states is investigated by means of helium nanodroplet isolation (HENDI) combined with femtosecond pump-probe spectroscopy. Different pathways…

Atomic and Molecular Clusters · Physics 2016-09-28 Patrick Claas , Georg Droppelmann , Claus-Peter Schulz , Marcel Mudrich , Frank Stienkemeier

Helium nanodroplets, commonly regarded as the "nearly ideal spectroscopic matrix", are being actively studied for more than two decades now. While they mostly serve as cold, weakly perturbing and transparent medium for high-resolution…

Atomic and Molecular Clusters · Physics 2015-03-03 M. Mudrich , F. Stienkemeier

Rotationally resolved infrared spectra are reported for halogen atom - HF free radical complexes formed in helium nanodroplets. An effusive pyrolysis source is used to dope helium droplets with Cl, Br and I atoms, formed by thermal…

Atomic and Molecular Clusters · Physics 2016-04-13 Jeremy M. Merritt , Jochen Küpper , Roger E. Miller

Much of our knowledge about dynamics and functionality of molecular systems has been achieved with femtosecond time-resolved spectroscopy. Despite extensive technical developments over the past decades, some classes of systems have eluded…

Chemical Physics · Physics 2020-03-25 Bernhard Thaler , Miriam Meyer , Pascal Heim , Markus Koch

Coherent diffractive imaging of individual free nanoparticles has opened novel routes for the in-situ analysis of their transient structural, optical, and electronic properties. So far, single-shot single-particle diffraction was assumed to…

Helium nanodroplets ("HNDs") are widely used for forming tailor-made clusters and molecular complexes in a cold, transparent, and weakly-interacting matrix. Characterization of embedded species by mass spectrometry is often complicated by…

Atomic and Molecular Clusters · Physics 2024-01-15 S. De , A. R. Abid , J. D. Asmussen , L. Ben Ltaief , K. Sishodia , A. Ulmer , H. B. Pedersen , S. R. Krishnan , M. Mudrich

The spectroscopy of free radicals and radical containing entrance-channel complexes embedded in superfluid helium nano-droplets is reviewed. The collection of dopants inside individual droplets in the beam represents a micro-canonical…

Atomic and Molecular Clusters · Physics 2007-08-02 Jochen Küpper , Jeremy M. Merritt

Helium tagging in action spectroscopy is an efficient method for measuring the absorption spectrum of complex molecular ions with minimal perturbations to the gas phase spectrum. We have used superfluid helium nanodroplets doped with…

Atomic and Molecular Clusters · Physics 2019-12-19 Michael Gatchell , Paul Martini , Felix Laimer , Marcelo Goulart , Florent Calvo , Paul Scheier

This review has two principal aims. The first of these is to provide a comprehensive overview of the applications of HNDs in the study of collections of atoms and molecules, i.e. clusters and complexes. These clusters and complexes must…

Atomic and Molecular Clusters · Physics 2018-05-10 A. Mauracher , O. Echt , A. M. Ellis , S. Yang , D. K. Bohme , J. Postler , A. Kaiser , S. Denifl , P. Scheier

Helium nanodroplets doped with polar molecules are studied by electrostatic deflection. This broadly applicable method allows even polyatomic molecules to attain sub-Kelvin temperatures and nearly full orientation in the field. The…

Atomic and Molecular Clusters · Physics 2019-07-26 John W. Niman , Benjamin S. Kamerin , Daniel J. Merthe , Lorenz Kranabetter , Vitaly V. Kresin

Besides the use as cold matrix for spectroscopic studies, superfluid helium droplets have served as a cold environment for the synthesis of molecules and clusters. Since vibrational frequencies of molecules in helium droplets exhibit almost…

Atomic and Molecular Clusters · Physics 2022-10-03 Florian Lackner , Wolfgang E. Ernst

Isolated electrons resting above a helium surface are predicted to have a bound spectrum corresponding to a one-dimensional hydrogen atom. But in fact, the observed spectrum is closer to that of a quantum-defect atom. Such a model is…

Quantum Physics · Physics 2009-10-31 Michael Martin Nieto

Imaging the structure and observing the dynamics of isolated proteins using single-particle X-ray diffractive imaging (SPI) is one of the potential applications of X-ray free-electron lasers (XFELs). Currently, SPI experiments on isolated…

Rotationally resolved infrared spectra are reported for the X-HCN (X = Cl, Br, I) binary complexes solvated in helium nanodroplets. These results are directly compared with that obtained previously for the corresponding X-HF complexes [J.…

Atomic and Molecular Clusters · Physics 2016-07-06 Jeremy M. Merritt , Jochen Küpper , Roger E. Miller

Helium nanodroplets are ideal model systems to unravel the complex interaction of condensed matter with ionizing radiation. Here we study the effect of purely elastic electron scattering on angular and energy distributions of photoelectrons…

We present helium atom micro-diffraction as an ideal technique for characterization of 2D materials due to its ultimate surface sensitivity combined with sub-micron spatial resolution. Thermal energy neutral helium scatters from the valence…

This paper introduces Spectral Incoherent Diffractive Imaging (SIDI) as a novel method for achieving dark-field imaging of nanostructures with heterogeneous oxidation states. With SIDI, shifts in photoemission profiles can be spatially…

Optics · Physics 2023-12-25 Tamme Wollweber , Kartik Ayyer

Helium atom scattering (HAS) is a well established technique for examining the surface structure and dynamics of materials at atomic sized resolution. The HAS technique Helium spin-echo spectroscopy opens up the possibility of compressing…

Materials Science · Physics 2015-10-05 Alex Jones , Anton Tamtögl , Irene Calvo-Almazán , Anders Hansen

Oligomers of the organic semiconductor PTCDA are studied by means of helium nanodroplet isolation (HENDI) spectroscopy. In contrast to the monomer absorption spectrum, which exhibits clearly separated, very sharp absorption lines, it is…

Other Condensed Matter · Physics 2011-02-10 Jan Roden , Alexander Eisfeld , Matthieu Dvorak , Oliver Buenermann , Frank Stienkemeier
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