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Chemical theories involving thermodynamical equilibrium states invariably utilize statistical mechanical equilibrium density distributions. Here, a definition of heat-work transformation termed thermo mechanical coherence is first made, and…

Chemical Physics · Physics 2007-05-23 Christopher G. Jesudason

The Von Neumann entropy of reduced states is a measure of bipartite entanglement. Despite its name, the entanglement entropy cannot by itself be used as a resource for creating thermodynamic heat flows. In order to extract heat from an…

Quantum Physics · Physics 2026-05-04 Lisa Lenstra , Jasper van Wezel

The linear response to temperature changes is derived for systems with overdamped stochastic dynamics. Holding both in transient and steady state conditions, the results allow to compute nonequilibrium thermal susceptibilities from…

Statistical Mechanics · Physics 2016-04-11 Gianmaria Falasco , Marco Baiesi

We investigate holographically the entanglement entropy of a nonconformal medium whose dual geometry is described by an Einstein-Maxwell-dilaton theory. Due to an additional conserved charge corresponding to the number operator, its…

High Energy Physics - Theory · Physics 2015-06-17 Chanyong Park

The laws of thermodynamics, despite their wide range of applicability, are known to break down when systems are correlated with their environments. Here, we generalize thermodynamics to physical scenarios which allow presence of…

Quantum Physics · Physics 2018-02-06 Manabendra Nath Bera , Arnau Riera , Maciej Lewenstein , Andreas Winter

A general thermodynamic framework is presented for open quantum systems in fixed contact with a thermal reservoir. The first and second law are obtained for arbitrary system-reservoir coupling strengths, and including both factorized and…

Quantum Physics · Physics 2020-04-23 Ángel Rivas

The standard treatment of relativistic thermodynamics does not allow for a systematic treatment of mixtures. It is proposed that a formulation of thermodynamics as an action principle may be a suitable approach to adopt for a new…

General Physics · Physics 2010-06-09 Christian Fronsdal

Quantum technologies use entanglement to outperform classical technologies, and often employ strong cooling and isolation to protect entangled entities from decoherence by random interactions. Here we show that the opposite strategy -…

The dynamics of the entanglement rate are investigated in this paper for pairwise interaction and two special sets of initial states. The results show that for the given interaction and the decoherence scheme, the competitions between…

Quantum Physics · Physics 2009-11-10 X. X. Yi , H. T. Cui , X. G. Wang

The experimental calorimetric two-state criterion requires the van't Hoff enthalpy $\Delta H_{\rm vH}$ around the folding/unfolding transition midpoint to be equal or very close to the calorimetric enthalpy $\Delta H_{\rm cal}$ of the…

Statistical Mechanics · Physics 2009-09-25 Huseyin Kaya , Hue Sun Chan

Simulations are performed of a small quantum system interacting with a quantum environment. The system consists of various initial states of two harmonic oscillators coupled to give normal modes. The environment is "designed" by its level…

Statistical Mechanics · Physics 2015-06-15 George L. Barnes , Michael E. Kellman

We introduce a systematic classification method for the analogs of phase transitions in finite systems. This completely general analysis, which is applicable to any physical system and extends towards the thermodynamic limit, is based on…

Statistical Mechanics · Physics 2015-05-28 Stefan Schnabel , Daniel T. Seaton , David P. Landau , Michael Bachmann

Physical kinetic roughening processes are well known to exhibit universal scaling of observables that fluctuate in space and time. Are there analogous dynamic scaling laws that are unique to the chemical reaction mechanisms available…

Statistical Mechanics · Physics 2022-11-17 Shrabani Mondal , Jonah S. Greenberg , Jason R. Green

It is known that the equilibrium properties of open classical systems that are strongly coupled to a heat bath are described by a set of thermodynamic potentials related to the system's Hamiltonian of mean force. By adapting this framework…

Statistical Mechanics · Physics 2017-06-28 Harry J. D. Miller , Janet Anders

We derive a general quantum exchange fluctuation theorem for multipartite systems with arbitrary coupling strengths by taking into account the informational contribution of the back-action of the quantum measurements, which contributes to…

Quantum Physics · Physics 2023-07-18 Akira Sone , Diogo O. Soares-Pinto , Sebastian Deffner

Recent theoretical and experiments have explored the use of entangled photons as a spectroscopic probe of material systems. We develop here a theoretical description for entropy production in the scattering of an entangled biphoton state…

Quantum Physics · Physics 2019-05-22 Hao Li , Andrei Piryatinski , Ajay Ram Srimath Kandada , Carlos Silva , Eric R. Bittner

Entanglement, which is an essential characteristic of quantum mechanics, is the key element in potential practical quantum information and quantum communication systems. However, there are many open and fundamental questions (relating to…

Quantum Physics · Physics 2015-05-18 G. W. Ford , Yang Gao , R. F. O'Connell

The quantum thermodynamic behaviour of a charged oscillator in the presence of a magnetic field and coupled to a heat bath through different coupling schemes is obtained analytically. It is shown that finite dissipation substitutes the…

Statistical Mechanics · Physics 2008-04-03 Malay Bandyopadhyay

I show that non-decreasing entropy provides a necessary and sufficient condition to convert the state of a physical system into a different state by a reversible transformation that acts on the system of interest and a further "catalyst"…

Quantum Physics · Physics 2022-01-06 Henrik Wilming

This article presents a heuristic combination of the local and global formulations of the second law of thermodynamics that suggests the possibility of theoretical existence of thermodynamics processes with positive and negative entropy…

General Physics · Physics 2010-12-06 Jose Iraides Belandria