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Heat capacity curves as functions of temperature for classical atomic clusters bound by pairwise Lennard-Jones potentials were calculated for aggregate sizes from 4 to 24 using Monte Carlo methods. J-walking (or jump-walking) was used to…

chem-ph · Physics 2009-10-22 Don D. Frantz

Heat capacity curves as functions of temperature were calculated using Monte Carlo methods for the series of Ar_{13-n}Kr_n clusters (0 <= n <= 13). The clusters were modeled classically using pairwise additive Lennard-Jones potentials.…

chem-ph · Physics 2009-10-28 Don D. Frantz

Detailed studies of the thermodynamic properties of selected binary Lennard-Jones clusters of the type X_{13-n}Y_n (where n=1,2,3) are presented. The total energy, heat capacity and first derivative of the heat capacity as a function of…

Statistical Mechanics · Physics 2009-11-10 Dubravko Sabo , Cristian Predescu , J. D. Doll , David L. Freeman

Single impurity effect on the melting process of magic number Lennard-Jones, rare gas, clusters of up to 309 atoms is studied on the basis of Parallel Tempering Monte Carlo simulations in the canonical ensemble. A decrease on the melting…

Atomic and Molecular Clusters · Physics 2015-05-19 Nicolás Quesada , Gloria E. Moyano

The heat capacity and isomer distributions of the 38 atom Lennard-Jones cluster have been calculated in the canonical ensemble using parallel tempering Monte Carlo methods. A distinct region of temperature is identified that corresponds to…

Chemical Physics · Physics 2009-11-06 J. P. Neirotti , F. Calvo , David L. Freeman , J. D. Doll

Heat capacity curves as functions of temperature were calculated using Monte Carlo methods for the series of Ne_(13-n)Ar_n clusters (0 <= n <= 13). The clusters were modeled classically using pairwise additive Lennard-Jones potentials. The…

Chemical Physics · Physics 2009-10-30 Don D. Frantz

We present a new theoretical framework for modelling the cluster growing process. Starting from the initial tetrahedral cluster configuration, adding new atoms to the system and absorbing its energy at each step, we find cluster growing…

Atomic and Molecular Clusters · Physics 2007-05-23 A. Koshelev , A. Shutovich , Il. A. Solov'yov , A. V. Solov'yov , W. Greiner

The thermal behaviour of the 309-atom Lennard-Jones cluster, whose structure is a complete Mackay icosahedron, has been studied by parallel tempering Monte Carlo simulations. Surprisingly for a magic number cluster, the heat capacity shows…

Other Condensed Matter · Physics 2007-05-23 Eva G. Noya , Jonathan P. K. Doye

We review the theory behind abundance of experimentally observed nanoclusters produced in beams, aiming to understand their magic number behavior. It is shown how use of statistical physics, with certain assumptions, reduces the calculation…

Statistical Mechanics · Physics 2014-04-02 Kiamars Vafayi , Keivan Esfarjani

We present a new theoretical framework for modelling the fusion process of Lennard-Jones (LJ) clusters. Starting from the initial tetrahedral cluster configuration, adding new atoms to the system and absorbing its energy at each step, we…

Atomic and Molecular Clusters · Physics 2009-09-29 Ilia A. Solovyov , Andrey V. Solovyov , Walter Greiner

The interplay between magic number stabilities and superfluidity of small para-hydrogen clusters with sizes $N = 5$ to 40 and temperatures $0.5 K \leq T \leq 4.5 $K is explored with classical and quantum Path Integral Monte Carlo…

Computational Physics · Physics 2010-09-14 S. A. Khairallah , M. B. Sevryuk , D. M. Ceperley , J. P. Toennies

The excitation energies of parahydrogen clusters have been systematically calculated by the diffusion Monte Carlo technique in steps of one molecule from 3 to 40 molecules. These clusters possess a very rich spectra, with angular momentum…

Atomic and Molecular Clusters · Physics 2009-11-13 R. Guardiola , J. Navarro

We study the 38-atom Lennard-Jones cluster with parallel tempering Monte Carlo methods in the microcanonical and molecular dynamics ensembles. A new Monte Carlo algorithm is presented that samples rigorously the molecular dynamics ensemble…

Chemical Physics · Physics 2009-11-06 F. Calvo , J. P. Neirotti , David L. Freeman , J. D. Doll

The thermodynamic and structural properties of (NH$_4$Cl)$_n$ clusters, n=3-10 are studied. Using the method of simulated annealing, the geometries of several isomers for each cluster size are examined. Jump-walking Monte Carlo simulations…

chem-ph · Physics 2009-10-28 Alexander Matro , David L. Freeman , Robert Q. Topper

A dimer of bound atoms cannot melt, only dissociate. Bulk metals show a well defined first order transition between their solid and liquid phases. The appearance of the melting transition is explored for increasing clusters sizes via the…

Atomic and Molecular Clusters · Physics 2009-11-10 Ralph Werner

Putative global minima of sodium clusters with up to 380 atoms have been located for two model interatomic potentials. Structures based upon the Mackay icosahedra predominate for both potentials, and the magic numbers for the…

Other Condensed Matter · Physics 2007-06-13 Eva G. Noya , Jonathan P. K. Doye , David J. Wales

An interesting problem in statistical physics is the condensation of classical particles in droplets or clusters when the pair-interaction is given by a stable Lennard-Jones-type potential. We study two aspects of this problem. We start by…

Probability · Mathematics 2015-03-18 Sabine Jansen , Wolfgang König , Bernd Metzger

A systematic and detailed investigation of the finite-temperature behavior of small sodium clusters, Na_n, in the size range of n= 8 to 50 are carried out. The simulations are performed using density-functional molecular-dynamics with…

Statistical Mechanics · Physics 2015-06-25 Mal-Soon Lee , S. Chacko , D. G. Kanhere

The formation, growth, structure and cluster size distribution (CSD) properties in a two-dimensional system of particles interacting with Lennard-Jones (LJ) potential under controlled cooling condition have been studied using Monte-Carlo…

Soft Condensed Matter · Physics 2018-01-18 Barnana Pal

A few experiments have already detected the presence of icosahedral superclusters in undercooled liquids, confirming a possible homogeneous nucleation of such entities as suggested by Franck. These superclusters survive in melts above the…

Materials Science · Physics 2014-07-29 Robert Felix Tournier
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