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First, Second and Combined Laws of Thermodynamics are revised in terms of entropy change, partial entropy, partial volume, and chemical potential.

Statistical Mechanics · Physics 2025-06-03 Zi-Kui Liu

The structure, thermodynamics and slow activated dynamics of the equilibrated metastable regime of glass-forming fluids remains a poorly understood problem of high theoretical and experimental interest. We apply a highly accurate…

Soft Condensed Matter · Physics 2024-08-21 Subhashish Chaki , Baicheng Mei , Kenneth S. Schweizer

We present an educational proposal which aims to illustrate the elegant, refined and coherent physics contained in Thermodynamics, through a path which assigns to the microscopic description of the physical systems a constantly privileged…

Physics Education · Physics 2023-11-01 Alessandro Ercoli , Vittorio Lubicz

Equilibrium statistical mechanics is intended to link the microscopic dynamics of particles to the thermodynamic laws for macroscopic quantities. However, the modern statistical theory is faced with significant difficulties, as applied to…

Statistical Mechanics · Physics 2016-03-15 A. G. Godizov , A. A. Godizov

The equation of state for dense fluids has been derived within the framework of the Sutherland and Katz potential models. The equation quantitatively agrees with experimental data on the isothermal compression of water under extrapolation…

Chemical Physics · Physics 2012-03-15 V. Yu. Bardik , D. Nerukh , E. V. Pavlov , I. V. Zhyganiuk

In the causal theory of relativistic dissipative fluid dynamics, there are conditions on the equation of state and other thermodynamic properties such as the second-order coefficients of a fluid that need to be satisfied to guarantee that…

Nuclear Theory · Physics 2008-11-26 Azwinndini Muronga

Thermodynamics allows the application of Statistical Mechanics to finite and even small systems. As surface effects cannot be scaled away, one has to be careful with the standard arguments of splitting a system into two or bringing two…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

Fundamental physical constants play a profound role in physics. For example, they govern nuclear reactions, formation of stars, nuclear synthesis and stability of biologically vital elements. These are high-energy processes discussed in…

Statistical Mechanics · Physics 2023-04-24 K. Trachenko

Multiscale thermodynamics is a theory of relations among levels of investigation of complex systems. It includes the classical equilibrium thermodynamics as a special case but it is applicable to both static and time evolving processes in…

Statistical Mechanics · Physics 2021-02-24 Miroslav Grmela

A thermodynamically consistent particle-based model for fluid dynamics with continuous velocities and a non-ideal equation of state is presented. Excluded volume interactions are modeled by means of biased stochastic multiparticle…

Soft Condensed Matter · Physics 2009-11-11 Thomas Ihle , Erkan Tuzel , Daniel M. Kroll

Non-linear equations of radial motion of a gas bubble in a compressible viscous liquid have been modified considering effects of viscosity and compressibility more complete than all previous works. A new set of equations has been derived…

Fluid Dynamics · Physics 2007-05-23 Ahmad Moshaii , Rasool Sadighi-Bonabi , Mohammd Taeibi-Rahni

The viscosity and self-diffusion constant of particle-based mesoscale hydrodynamic methods, multi-particle collision dynamics (MPC) and dissipative particle dynamics (DPD), are investigated, both with and without angular-momentum…

Soft Condensed Matter · Physics 2009-11-13 Hiroshi Noguchi , Gerhard Gompper

Microcanonical Thermodynamics allows the application of Statistical Mechanics on one hand to closed finite and even small systems and on the other to the largest,self-gravitating ones. However, one has to reconsider the fundamental…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

Thermodynamic properties of matter are conveniently expressed as functional relations between variables known as equations of state. Here we experimentally determine the compressibility, density and pressure equations of state for an…

Quantum Gases · Physics 2016-02-12 K. Fenech , P. Dyke , T. Peppler , M. G. Lingham , S. Hoinka , H. Hu , C. J. Vale

Macroscopic thermodynamics of equilibrium is constructed for systems obeying power-law canonical distributions. With this, the connection between macroscopic thermodynamics and microscopic statistical thermodynamics is generalized. This is…

Statistical Mechanics · Physics 2009-10-31 Sumiyoshi Abe , A. K. Rajagopal

A new variational method for studying the equilibrium states of an interacting particles system has been proposed. The statistical description of the system is realized by means of a density matrix. This method is used for description of…

General Physics · Physics 2014-12-19 Boris Bondarev

Introduction to the theory of decoherence. Contents: 1. The phenomenon of decoherence: superpositions, superselection rules, decoherence by "measurements". 2. Observables as a derivable concept. 3. The measurement problem. 4. Density…

Quantum Physics · Physics 2008-02-03 H. D. Zeh

Ten "themes" of viscous liquid physics are discussed with a focus on how they point to a general description of equilibrium viscous liquid dynamics (i.e., fluctuations) at a given temperature. This description is based on standard…

Soft Condensed Matter · Physics 2009-11-11 Jeppe C. Dyre

We show how the macroscopic state variables pressure, entropy and temperature of equilibrium thermodynamics can be consistently derived from the (quantum) chaotic spectral structure of one or two particles in two-dimensional domains. This…

The hydrodynamic equations for a crystals with interstitials, taking into account the dissipative processes of the viscosity, heat conduction and the interstitial diffusion are derived. To achieve that we use the phenomenological approach…

Materials Science · Physics 2007-05-23 G. L. Buchbinder