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The adiabatic connection formula of ground-state density functional theory relates the correlation energy to a coupling-constant integral over a purely potential contribution, and is widely used to understand and improve approximations. The…

Chemical Physics · Physics 2016-06-01 Aurora Pribram-Jones , Kieron Burke

The random phase approximation (RPA) has received a considerable interest in the field of modeling systems where noncovalent interactions are important. Its advantages over widely used density functional theory (DFT) approximations are the…

Chemical Physics · Physics 2019-12-04 Marcin Modrzejewski , Sirous Yourdkhani , Jiri Klimes

We present a method based on the Path Integral Monte Carlo formalism for the calculation of ground-state time correlation functions in quantum systems. The key point of the method is the consideration of time as a complex variable whose…

Statistical Mechanics · Physics 2015-06-24 Riccardo Rota , Joaquim Casulleras , Ferran Mazzanti , Jordi Boronat

The random phase approximation (RPA) is exact for the exchange energy of a many-electron ground state, but RPA makes the correlation energy too negative by about 0.5 eV/electron. That large short-range error, which tends to cancel out of…

Computational Physics · Physics 2020-06-24 Tim Gould , Adrienn Ruzsinszky , John P. Perdew

We present an efficient \textit{ab initio} method for calculating the electronic structure and total energy of strongly correlated electron systems. The method extends the traditional Gutzwiller approximation for one-particle operators to…

Strongly Correlated Electrons · Physics 2014-07-01 Y. X. Yao , J. Liu , C. Liu , W. C. Lu , C. Z. Wang , K. M. Ho

The article attempts to find an algebraic formula describing the correlation coefficients between random variables and the principal components representing them. As a result of the analysis, starting from selected statistics relating to…

Machine Learning · Computer Science 2023-10-11 Zenon Gniazdowski

We construct a reference benchmark set for atomic and molecular random-phase-approximation (RPA) correlation energies in a density functional theory (DFT) framework at the complete basis set limit. This set is used to evaluate the accuracy…

Chemical Physics · Physics 2013-02-22 E. Fabiano , F. Della Sala

In this chapter, we provide a review of ground-state Kohn-Sham density-functional theory of electronic systems and some of its extensions, we present exact expressions and constraints for the exchange and correlation density functionals,…

Chemical Physics · Physics 2022-09-12 Julien Toulouse

The phaseless Auxiliary Field Quantum Monte Carlo method provides a well established approximation scheme for accurate calculations of ground state energies of many-fermions systems. Here we apply the method to the calculation of imaginary…

Strongly Correlated Electrons · Physics 2015-06-17 M. Motta , D. E. Galli , S. Moroni , E. Vitali

In this work we propose a novel composite method for accurate calculation of the energies of many-electron atoms. The dominant contribution to the energy (pair energies) are calculated by using explicitly correlated factorisable coupled…

Atomic Physics · Physics 2018-12-12 Michal Przybytek , Michal Lesiuk

We study the electromagnetic responses of $^4$He within the framework of the self-consistent continuum random phase approximation theory. In this approach the ground state properties are described by a Hartree-Fock calculation. The single…

Nuclear Theory · Physics 2015-05-30 V. De Donno , M. Anguiano , G. Co' , A. M. Lallena

We present a general approach to justify the random phase approximation for the homogeneous Fermi gas in three dimensions in the mean-field scaling regime. We consider a system of $N$ fermions on a torus, interacting via a two-body…

Mathematical Physics · Physics 2023-11-14 Martin Ravn Christiansen , Christian Hainzl , Phan Thành Nam

Self-consistent correlation potentials for H$_2$ and LiH for various inter-atomic separations are obtained within the random phase approximation (RPA) of density functional theory. The RPA correlation potential shows a peak at the bond…

Chemical Physics · Physics 2015-05-30 M. Hellgren , D. R. Rohr , E. K. U. Gross

We propose a streamlined combination scheme of the transcorrelation (TC) and coupled cluster (CC) theory, which not only increases the convergence rate with respect to the basis set, but also extends the applicability of the lowest order CC…

Strongly Correlated Electrons · Physics 2021-07-28 Ke Liao , Thomas Schraivogel , Hongjun Luo , Daniel Kats , Ali Alavi

With a super-high-efficient numerical algorithm, we are able to self-consistently calculate the Green's function in the renormalized-ring-diagram approximation for a two-dimensional electron system with long-range Coulomb interactions. The…

Strongly Correlated Electrons · Physics 2011-11-09 Xin-Zhong Yan , C. S. Ting

Angular correlations for low-energy neutron induced $\gamma$ reactions are calculated using nuclear reaction formalism for multi level neutron capture with arbitrary multiplicities of $\gamma$ transitions. We confirm previous calculations…

Nuclear Theory · Physics 2025-09-22 Vladimir Gudkov , Hirohiko M. Shimizu

The response of a nucleus to an electromagnetic probe is a key quantity to simulate photabsorption or photodeexcitation processes. For large calculations at the scale of the entire mass table, this response can be estimated by linear…

Nuclear Theory · Physics 2024-04-05 Tong Li , Nicolas Schunck

We developed an efficient active-space particle-particle random phase approximation (ppRPA) approach to calculate accurate charge-neutral excitation energies of molecular systems. The active-space ppRPA approach constrains both indexes in…

Chemical Physics · Physics 2023-09-29 Jiachen Li , Jincheng Yu , Zehua Chen , Weitao Yang

Stochastic properties of loading and loss mechanism in a few atom trap are analyzed. An approximate formula is derived for the atom-number correlation function for the trapped atoms in the limit of reasonably small two-atom loss rate.…

Atomic Physics · Physics 2007-05-23 Youngwoon Choi , Seokchan Yoon , Sungsam Kang , Woongnae Kim , Jai-Hyung Lee , Kyungwon An

In recent years, energy correlators have emerged as powerful observables for probing the fragmentation dynamics of high-energy collisions. We introduce the first numerical strategy for calculating energy correlators using the Hamiltonian…

High Energy Physics - Phenomenology · Physics 2025-05-07 Kyle Lee , Francesco Turro , Xiaojun Yao
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