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Path optimization methods have been widely used and highly successful for the analysis of chemical reactions. Yet, they can fail to capture intrinsically multidimensional features of potential energy surfaces (PES). We introduce the nudged…

Statistical Mechanics · Physics 2026-04-23 Uday Sankar Manoj , Nicole Drew , Ismaila Dabo , Lukas Muechler

The extension of the adiabatic regularization method to spin-$1/2$ fields requires a self-consistent adiabatic expansion of the field modes. We provide here the details of such expansion, which differs from the WKB ansatz that works well…

General Relativity and Quantum Cosmology · Physics 2015-06-17 Aitor Landete , Jose Navarro-Salas , Francisco Torrenti

The dynamics of a charged relativistic particle in electromagnetic field of a rotating magnetized celestial body with the magnetic axis inclined to the axis of rotation is studied. The covariant Lagrangian function in the rotating reference…

High Energy Astrophysical Phenomena · Physics 2014-09-23 V. Epp , M. A. Masterova

A new scheme to study the properties of finite nuclei is proposed based on the Dirac-Brueckner-Hartree-Fock (DBHF) approach starting from a bare nucleon-nucleon interaction. The relativistic structure of the nucleon self-energies in nuclear…

We study the predictions of three mean-field theoretical approaches in the description of the ground state properties of some spherical nuclei far from the stability line. We compare binding energies, single particle spectra, density…

Nuclear Theory · Physics 2015-06-04 G. Co' , V. De Donno , P. Finelli , M. Grasso , M. Anguiano , A. M. Lallena , C. Giusti , A. Meucci , F. D. Pacati

Recent studies of optimization methods and GNC of spacecraft near small bodies focusing on descent, landing, rendezvous, etc., with key safety constraints such as line-of-sight conic zones and soft landings have shown promising results;…

Optimization and Control · Mathematics 2020-05-22 Steven van Leeuwen

Unknown constraints arise in many types of expensive black-box optimization problems. Several methods have been proposed recently for performing Bayesian optimization with constraints, based on the expected improvement (EI) heuristic.…

A mean field theory is developed for the calculation of the surface free energy of the staggered BCSOS, (or six vertex) model as function of the surface orientation and of temperature. The model approximately describes surfaces of crystals…

Statistical Mechanics · Physics 2009-10-31 Enrico Carlon , Henk van Beijeren

Charge transfer (CT) processes that are electronically non-adiabatic are ubiquitous in chemistry, biology, and materials science, but their theoretical description requires diabatic states or adiabatic excited states. For complex systems,…

Chemical Physics · Physics 2024-11-08 Sohang Kundu , Hong-Zhou Ye , Timothy C. Berkelbach

Electromagnetic metasurfaces offer the capability to realize almost arbitrary power conserving field transformations. These field transformations are governed by the generalized sheet transition conditions, which relate the tangential…

Applied Physics · Physics 2020-11-19 Stewart Pearson , Sean V. Hum

We train an equivariant machine learning model to predict energies and forces for a real-world study of hydrogen combustion under conditions of finite temperature and pressure. This challenging case for reactive chemistry illustrates that…

Chemical Physics · Physics 2023-06-16 Xingyi Guan , Joseph Heindel , Taehee Ko , Chao Yang , Teresa Head-Gordon

A procedure is developed to rigorously decompose experimental loss spectra of medium-energy electrons reflected from solid surfaces into contributions due to surface and volume electronic excitations. This can be achieved by analysis of two…

Materials Science · Physics 2009-11-11 Wolfgang S. M. Werner

Adiabatic quantum control protocols have been of wide interest to quantum computation due to their robustness and insensitivity to their actual duration of execution. As an extension of previous quantum learning algorithms, this work…

Quantum Physics · Physics 2023-03-03 Nannan Ma , Wenhao Chu , Jiangbin Gong

We develop a relativistic mean field (RMF) description of deformed nuclei with the pairing correlations in the BCS approximation. The treatment of the pairing correlations for nuclei with the Fermi surface being close to the threshold of…

Nuclear Theory · Physics 2009-11-10 L. S. Geng , H. Toki , S. Sugimoto , J. Meng

We propose a method that exploits sparse representation of potential energy surfaces (PES) on a polynomial basis set selected by compressed sensing. The method is useful for studies involving large numbers of PES evaluations, such as the…

Chemical Physics · Physics 2018-08-10 Prashant Rai , Khachik Sargsyan , Habib Najm , So Hirata

Relativistic mean field calculations have been performed to obtain nuclear density pro- file. Microscopic interactions have been folded with the calculated densities of finite nuclei to obtain a semi-microscopic potential. Life time values…

Nuclear Theory · Physics 2012-01-04 G. Gangopadhyay

A globally correct potential energy surface (PES) for the \hp\ molecular ion is presented. The Born-Oppenheimer (BO) \ai\ grid points of Pavanello et. al. [\textit{J. Chem. Phys.} {\bf 136}, 184303 (2012)] are refitted as BOPES75K, which…

Chemical Physics · Physics 2018-12-17 I. I. Mizus , O. L. Polyansky , Laura K. McKemmish , J. Tennyson , A. Alijah , N. F. Zobov

Mathematical mean-field approaches have been used in many fields, not only in Physics and Chemistry, but also recently in Finance, Economics, and Game Theory. In this paper we will study a new special mean-field problem in a purely…

Probability · Mathematics 2012-10-03 Juan Li

We propose a new block localized excitation (BLE) method to directly construct diabatic excited states without the need to first compute the adiabatic states. The new method is capable to keep any electrons, spins, and excitations localized…

Chemical Physics · Physics 2020-01-22 Peng Bao , Qiang Shi , Jiali Gao

Treating a many-body Fermi system in terms of a single particle in a deforming mean field. We relate adiabatic geometric phase to susceptibility for the noncyclic case, and to its derivative for the cyclic case. Employing the semiclassical…

chao-dyn · Physics 2009-10-31 Sudhir R. Jain , Arun K. Pati
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