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Non-adiabatic effects play an important role in many chemical processes. In order to study the underlying non-adiabatic potential-energy surfaces (PESs), we present a locally-constrained density-functional theory approach, which enables us…

Materials Science · Physics 2015-06-25 Joerg Behler , Bernard Delley , Karsten Reuter , Matthias Scheffler

We show that chemically-accurate potential energy surfaces (PESs) can be generated from quantum computers by measuring only the density along an adiabatic transition between different molecular geometries. In lieu of using phase estimation,…

Quantum Physics · Physics 2024-10-08 James Brown

The theory of gravitationally induced adiabatic particle production offers an alternative approach to exploring the accelerating expansion of the universe. However, existing models generally lack a well-defined field-action formulation.…

General Relativity and Quantum Cosmology · Physics 2025-12-10 Souvik Pramanik

We propose a simple scheme to estimate potential energy surface (PES) with which the accuracy can be easily controlled and improved up to the level of the density functional theory (DFT) calculations. It is based on a model selection within…

Materials Science · Physics 2014-07-11 Atsuto Seko , Akira Takahashi , Isao Tanaka

A new model that includes the time-dependent dynamics of the single-particle (s.p.) motion in conjunction with the macroscopic evolution of the system is proposed for describing the compound nucleus (CN) formation in fusion of heavy nuclei.…

Nuclear Theory · Physics 2009-11-10 Alexis Diaz-Torres

The microscopically constrained relativistic mean field theory is used to investigate the superdeformation for Pb isotopes. The calculations show that there exists a clear superdeformed minimum in the potential energy surfaces with four…

Nuclear Theory · Physics 2007-05-23 Jian-You Guo , Zong-Qiang Sheng , Xiang-Zheng Fang

We compute highly accurate first principle based \textit{ab initio} adiabatic potential energy surfaces (PESs) using State-Averaged Multi-Configurational Self-Consistent Field (SA-MCSCF) followed by internally contracted Multi-Reference…

Chemical Physics · Physics 2026-03-10 Avik Guchait , Gourhari Jana , Satyam Ravi , Koushik Naskar , Satrajit Adhikari

The present study introduce a novel approach, the Chebyshev shape parametrization, to describe the geometric configurations of atomic nuclei, with a particular emphasis on fission dynamics. In this framework, the nuclear surface is…

Nuclear Theory · Physics 2025-08-11 K. Jyothish , M. S. Suryan Sivadas , A. K. Rhine Kumar

A systematic Bayesian framework is developed for physics constrained parameter inference ofstochastic differential equations (SDE) from partial observations. The physical constraints arederived for stochastic climate models but are…

Data Analysis, Statistics and Probability · Physics 2016-11-25 Daniel Peavoy , Christian L. E. Franzke , Gareth O. Roberts

The relativistic mean field approach, within a theoretical framework known as the chiral confining model incorporating chiral symmetry breaking and quark confinement effects, is applied for the first time to finite nuclei. Model parameters…

Nuclear Theory · Physics 2026-05-27 M. Chamseddine , J. -P. Ebran , E. Khan , B. K. Pradhan , J. Margueron , H. Hansen , G. Chanfray

The structure and dynamics of a molecular system is governed by its potential energy surface (PES), representing the total energy as a function of the nuclear coordinates. Obtaining accurate potential energy surfaces is limited by the…

Chemical Physics · Physics 2023-09-29 Karl P. Horn , Luis Itza Vazquez-Salazar , Christiane P. Koch , Markus Meuwly

A rich literature has been produced on the quantum states of atoms and molecules confined into infinite potential wells with a specified symmetry. Apart from their interest as basic quantum systems, confined atoms and molecules are useful…

Chemical Physics · Physics 2019-04-03 Savino Longo , Gaia Micca Longo , Domenico Giordano

Background: Average energies of nuclear collective modes may be efficiently and accurately computed using a non-relativistic constrained approach without reliance on a random phase approximation (RPA). Purpose: To extend the constrained…

Nuclear Theory · Physics 2015-06-15 Wei-Chia Chen , J. Piekarewicz , M. Centelles

By breaking both the axial and the spatial reflection symmetries, we develop multidimensionally constrained relativistic mean field (MDC-RMF) models. The nuclear shape is assumed to be invariant under the reversion of $x$ and $y$ axes,…

Nuclear Theory · Physics 2014-02-05 Bing-Nan Lu , Jie Zhao , En-Guang Zhao , Shan-Gui Zhou

The potential curve, dissociation energy, equilibrium internuclear distance, and spectroscopic constants for the ground state of the Ca2 molecule are calculated with the help of the generalized relativistic effective core potential method…

Chemical Physics · Physics 2012-12-27 N. S. Mosyagin , A. N. Petrov , A. V. Titov , A. V. Zaitsevskii

The standard relativistic mean-field model is extended by including dynamical effects that arise in the coupling of single-nucleon motion to collective surface vibrations. A phenomenological scheme, based on a linear ansatz for the energy…

Nuclear Theory · Physics 2009-11-07 D. Vretenar , T Niksic , P. Ring

Questions are raised about certain experimental and theoretical claims that atoms may be stabilized into their bound states, and prevented from achieving full ionization, by the application of adiabatic, ultraintense, high-frequency laser…

Atomic Physics · Physics 2009-09-29 Sydney Geltman , Mircea Fotino

A central problem of materials science is to determine whether a hypothetical material is stable without being synthesized, which is mathematically equivalent to a global optimization problem on a highly non-linear and multi-modal potential…

Applications · Statistics 2023-05-02 Arvind Krishna , Huan Tran , Chaofan Huang , Rampi Ramprasad , V. Roshan Joseph

The idea of a Potential Energy Surface (PES) forms the basis of almost all accounts of the mechanisms of chemical reactions, and much of theoretical molecular spectroscopy. It is assumed that, in principle, the PES can be calculated by…

Quantum Physics · Physics 2013-04-10 Brian Sutcliffe , R. Guy Woolley

First principles calculations based on density functional theory are having an incerasing impact on our understanding of molecule-surface interactions. For example, calculations of the multi-dimensional potential energy surface have…

Materials Science · Physics 2007-05-23 O. Gulseren , D. M. Bird , S. E. Humphreys
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