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The similarity transformed equation of motion coupled cluster (STEOM-CC) method is benchmarked against CC3 and EOM-CCSDT-3 for a large test set of valence excited states of organic molecules studied by Schreiber et al. [M. Schreiber, M.R.…

Chemical Physics · Physics 2018-01-09 J. Sous , P. Goel , M. Nooijen

The pair coupled cluster doubles (pCCD) method (where the excitation manifold is restricted to electron pairs) has a series of interesting features. Among others, it provides ground-state energies very close to what is obtained with…

We present a nucleus-dependent valence-space approach for calculating ground and excited states of nuclei, which generalizes the shell-model in-medium similarity renormalization group to an ensemble reference with fractionally filled…

Nuclear Theory · Physics 2017-01-24 S. R. Stroberg , A. Calci , H. Hergert , J. D. Holt , S. K. Bogner , R. Roth , A. Schwenk

Recently, we have determined surface distributions of $\alpha$ clusters in the ground state of $^{20}\mathrm{Ne}$ from $\alpha$-transfer cross sections, without investigating the properties of its excited states. In this paper we extend our…

We apply a three-body model consisting of two valence neutrons and the core nucleus $^{14}$C in order to investigate the ground state properties and the electronic quadrupole transition of the $^{16}$C nucleus. The discretized continuum…

Nuclear Theory · Physics 2009-11-11 K. Hagino , H. Sagawa

The molecule-like structure of the C isotopes (A=12, 14, 16) is investigated using a microscopic $\alpha+\alpha+\alpha+n+n+\cdot \cdot \cdot$ model. The valence neutrons are classified based on the molecular-orbit (MO) model, and both…

Nuclear Theory · Physics 2009-11-07 N. Itagaki , S. Okabe , I. Ikeda , I. Tanihata

Using a schematic solvable many-body Hamiltonian, one studies a new type of proton-neutron excitations within a time dependent variational approach. Classical equations of motion are linearized and subsequently solved analytically. The…

Nuclear Theory · Physics 2009-11-11 A. A. Raduta , C. M. Raduta , B. Codirla

We present a reduced-cost equation-of-motion coupled-cluster method for excited states, built on a new state-specific frozen natural orbital (SS-FNO) framework. This approach enables systematic and controllable truncation of the virtual…

Chemical Physics · Physics 2025-07-24 Amrita Manna , Achintya Kumar Dutta

The transition energies and properties of the Ir$^{17+}$ ion are calculated using the Kramers-restricted configuration-interaction (KRCI) and Fock-space coupled-cluster (FSCC) methods within the Dirac-Coulomb-Gaunt Hamiltonian framework.…

Atomic Physics · Physics 2025-02-11 H. X. Liu , Y. M. Yu , B. B. Suo , Y. F. Ge , Y. Liu

Recent progress in the numerical solution of the nuclear many-body problem and in the development of nuclear Hamiltonians rooted in Quantum Chromodynamics, has opened the door to first-principle computations of nuclear reactions. In this…

Nuclear Theory · Physics 2020-07-24 J. Rotureau

We generalize the coupled-cluster (CC) approach with singles, doubles, and the non-iterative treatment of triples termed $\Lambda$CCSD(T) to Hamiltonians containing three-body interactions. The resulting method and the underlying CC…

Nuclear Theory · Physics 2013-11-22 Sven Binder , Piotr Piecuch , Angelo Calci , Joachim Langhammer , Petr Navrátil , Robert Roth

In this work, we use modern electronic structure methods to model the catalytic mechanism of different variants of the molybdenum cofactor (Moco). We investigate the dependence of various Moco model systems on structural relaxation and the…

Doubly occupied configuration interaction (DOCI) with optimized orbitals often accurately describes strong correlations while working in a Hilbert space much smaller than that needed for full configuration interaction. However, the scaling…

Chemical Physics · Physics 2016-02-25 Thomas M. Henderson , Ireneusz W. Bulik , Tamar Stein , Gustavo E. Scuseria

We demonstrate the accuracy of ground-state energies of the transcorrelated Hamiltonian, employing sophisticated Jastrow factors obtained from variational Monte Carlo, together with the coupled cluster and distinguishable cluster methods at…

We perform coupled-cluster calculations of ground- and dipole excited-state properties of the 8He halo nucleus with nucleon-nucleon and three-nucleon interactions from chiral effective field theory, both with and without explicit delta…

Nuclear Theory · Physics 2022-03-16 Francesca Bonaiti , Sonia Bacca , Gaute Hagen

We compute the binding energy of neutron-rich oxygen isotopes and employ the coupled-cluster method and chiral nucleon-nucleon interactions at next-to-next-to-next-to-leading order with two different cutoffs. We obtain rather well-converged…

Nuclear Theory · Physics 2009-09-11 G. Hagen , T. Papenbrock , D. J. Dean , M. Hjorth-Jensen , B. Velamur Asokan

We review the latest variational calculations of the ground state properties of doubly closed shell nuclei, from $^{12}$C to $^{208}$Pb, with semirealistic and realistic two- and three-nucleon interactions. The studies are carried on within…

Nuclear Theory · Physics 2011-04-15 A. Fabrocini , F. Arias de Saavedra , G. P. Co'

We present an approach to derive effective shell-model interactions from microscopic nuclear forces. The similarity-transformed coupled-cluster Hamiltonian decouples the single-reference state of a closed-shell nucleus and provides us with…

Nuclear Theory · Physics 2018-12-05 Z. H. Sun , T. D. Morris , G. Hagen , G. R. Jansen , T. Papenbrock

We report quantum Monte Carlo calculations of ground and low-lying excited states for A=8 nuclei using a realistic Hamiltonian containing the Argonne v18 two-nucleon and Urbana IX three-nucleon potentials. The calculations begin with…

Nuclear Theory · Physics 2008-11-26 R. B. Wiringa , Steven C. Pieper , J. Carlson , V. R. Pandharipande

We propose a many-body quantum engine powered by the energy difference between the entangled ground state of the interacting system and local separable states. Performing local energy measurements on an interacting many-body system can…

Quantum Physics · Physics 2023-08-24 Étienne Jussiau , Léa Bresque , Alexia Auffèves , Kater W. Murch , Andrew N. Jordan