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The random phase approximation (RPA) has emerged as a prominent first-principles method in material science, particularly to study the adsorption and chemisorption of small molecules on surfaces. However, its widespread application is…

Materials Science · Physics 2025-09-01 Edoardo Spadetto , Pier Herman Theodoor Philipsen , Arno Förster , Lucas Visscher

We compare the fixed-phase approximation with the better known, but closely related fixed-node approximation on several testing examples. We found that both approximations behave very similarly with the fixed-phase results being very close…

Computational Physics · Physics 2017-11-29 Cody A. Melton , Lubos Mitas

In this paper, we propose a framework based on the Retrospective Approximation (RA) paradigm to solve optimization problems with a stochastic objective function and general nonlinear deterministic constraints. This framework sequentially…

Optimization and Control · Mathematics 2025-05-27 Albert S. Berahas , Raghu Bollapragada , Shagun Gupta

Given a random sample from a continuous multivariate distribution, Stute's representation is obtained for empirical copula processes constructed from a broad class of smooth, possibly data-adaptive nonparametric copula estimators. The…

Statistics Theory · Mathematics 2022-04-26 Ivan Kojadinovic

This article offers sharp spatial and temporal mean-square regularity results for a class of semi-linear parabolic stochastic partial differential equations (SPDEs) driven by infinite dimensional fractional Brownian motion with the Hurst…

Numerical Analysis · Mathematics 2020-08-04 Xiaojie Wang , Ruisheng Qi , Fengze Jiang

We study robust convex quadratic programs where the uncertain problem parameters can contain both continuous and integer components. Under the natural boundedness assumption on the uncertainty set, we show that the generic problems are…

Optimization and Control · Mathematics 2018-12-19 Areesh Mittal , Can Gokalp , Grani A. Hanasusanto

The optimized effective potential (OEP) method presents an unambiguous way to construct the Kohn-Sham potential corresponding to a given diagrammatic approximation for the exchange-correlation functional. The OEP from the random-phase…

Materials Science · Physics 2023-07-18 Stefan Riemelmoser , Merzuk Kaltak , Georg Kresse

This Ph.D. thesis derives the equations of the Faddeev Random Phase Approximation (FRPA) and applies the method to a set of small atoms and molecules. The occurence of RPA instabilities in the dissociation limit is addressed in molecules…

Chemical Physics · Physics 2015-06-11 Matthias Degroote

Finite version of Random Domino Automaton (FRDA) - recently proposed a toy model of earthquakes - is investigated. Respective set of equations describing stationary state of the FRDA is derived and compared with infinite case. It is shown…

Cellular Automata and Lattice Gases · Physics 2012-08-30 Mariusz Bialecki

The mean spherical approximation (MSA) can be solved semi-analytically for the Gaussian core model (GCM) and yields - rather surprisingly - exactly the same expressions for the energy and the virial equations. Taking advantage of this…

Soft Condensed Matter · Physics 2016-08-31 Bianca M. Mladek , Gerhard Kahl , Martin Neumann

Remote physiological measurement (RPM) has emerged as a promising non-invasive method for monitoring physiological signals using the non-contact device. Although various domain adaptation and generalization methods were proposed to promote…

Computer Vision and Pattern Recognition · Computer Science 2025-11-11 Xiao Yang , Jiyao Wang , Yuxuan Fan , Can Liu , Houcheng Su , Weichen Guo , Zitong Yu , Dengbo He , Kaishun Wu

We apply the analytically solvable model of two electrons in two orbitals to diradical molecules, characterized by two unpaired electrons. The effect of the doubly occupied and empty orbitals is taken into account by means of random phase…

Chemical Physics · Physics 2025-11-20 Reza G. Shirazi , Vladimir V. Rybkin , Michael Marthaler , Dmitry S. Golubev

The fully self-consistent Random Phase Approximation (RPA) is constructed within the Unitary Correlation Operator Method (UCOM), which describes the dominant interaction-induced short-range central and tensor correlations by a unitary…

Nuclear Theory · Physics 2009-11-11 N. Paar , P. Papakonstantinou , R. Roth , H. Hergert

Difference schemes are considered for dynamical systems $ \dot x = f (x) $ with a quadratic right-hand side, which have $t$-symmetry and are reversible. Reversibility is interpreted in the sense that the Cremona transformation is performed…

Classical Analysis and ODEs · Mathematics 2024-12-03 Mikhail Malykh , Leonid Sevastianov

Using the adiabatic connection, we formulate the free energy in terms of the correlation function of a fictitious system, $h_{\lambda}({\bf r},{\bf r}')$, where $\lambda$ determines the interaction strength. To obtain $h_{\lambda}({\bf…

Statistical Mechanics · Physics 2016-06-15 Derek Frydel , Manman Ma

A novel approximation scheme is proposed to describe the dynamics of the spin-boson problem. Being nonperturbative in the coupling strength nor in the tunneling frequency, it gives reliable results over a wide regime of temperatures and…

Statistical Mechanics · Physics 2009-11-13 Francesco Nesi , Elisabetta Paladino , Michael Thorwart , Milena Grifoni

Simultaneous perturbation stochastic approximation (SPSA) has proven to be efficient for recursive optimization. SPSA uses a centered difference approximation to the gradient based on two function evaluations regardless of the dimension of…

Methodology · Statistics 2014-05-06 Xumeng Cao

Based on the real-time formalism, especially, on Thermo Field Dynamics, we derive the Schwinger-Dyson gap equation for the fermion propagator in QED and Four-Fermion model at finite-temperature and -density. We discuss some advantage of the…

High Energy Physics - Theory · Physics 2015-06-26 K. -I. Kondo , K. Yoshida

We present a real-space method for computing the random phase approximation (RPA) correlation energy within Kohn-Sham density functional theory, leveraging the low-rank nature of the frequency-dependent density response operator. In…

Computational Physics · Physics 2025-04-03 Boqin Zhang , Shikhar Shah , John E. Pask , Edmond Chow , Phanish Suryanarayana

Recently the damping of the collective charge (and spin) modes of interacting fermions in one spatial dimension was studied. It results from the nonlinear correction to the energy dispersion in the vicinity of the Fermi points. To…

Strongly Correlated Electrons · Physics 2009-11-13 K. Schönhammer
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