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Multicomponent systems are defined as chemical systems that require a quantum mechanical description of two or more different types of particles. Non-Born-Oppenheimer electron-nuclear interactions in molecules, electron-hole interactions in…

Chemical Physics · Physics 2015-10-21 Benjamin H. Ellis , Somil Aggarwal , Arindam Chakraborty

We describe a modification of the stochastic coupled cluster algorithm that allows the use of multiple reference determinants. By considering the secondary references as excitations of the primary reference and using them to change the…

Chemical Physics · Physics 2020-10-22 Maria-Andreea Filip , Charles J. C. Scott , Alex J. W. Thom

This paper focuses on solving coupled problems of lumped parameter models. Such problems are of interest for the simulation of severe accidents in nuclear reactors~: these coarse-grained models allow for fast calculations for statistical…

Computational Engineering, Finance, and Science · Computer Science 2018-12-27 Louis Viot , Laurent Saas , Florian De Vuyst

Mixture models extend the toolbox of clustering methods available to the data analyst. They allow for an explicit definition of the cluster shapes and structure within a probabilistic framework and exploit estimation and inference…

Methodology · Statistics 2025-09-15 Bettina Grün

We investigate the basis-set convergence of electronic correlation energies calculated using coupled cluster theory and a recently proposed finite basis-set correction technique. The correction is applied to atomic and molecular systems and…

Chemical Physics · Physics 2019-10-03 Andreas Irmler , Andreas Grüneis

Arguably the most widely used approaches for obtaining highly accurate molecular ground-state energies are coupled cluster methods. Despite introducing two layers of approximation, a linear and a nonlinear one, coupled cluster methods…

Numerical Analysis · Mathematics 2026-05-22 Jonas Beck , Benjamin Stamm

We discuss the key steps that have to be followed to calculate coherent quantum transport in molecular and atomic-scale systems, making emphasis on the ab-initio Gaussian Embedded Cluster Method recently developed by the authors. We present…

Materials Science · Physics 2007-05-23 J. J. Palacios , A. J. Perez-Jimenez , E. Louis , J. A. Verges , E. SanFabian

Unitary coupled cluster (UCC), originally developed as a variational alternative to the popular traditional coupled cluster method, has seen a resurgence as a functional form for use on quantum computers. However, the number of excitors…

Chemical Physics · Physics 2021-01-07 Maria-Andreea Filip , Alex J. W. Thom

In this work we investigate methods to improve the efficiency and scalability of quantum algorithms for quantum chemistry applications. We propose a transformation of the electronic structure Hamiltonian in the second quantization framework…

The relation of quarteting and clustering in atomic nuclei is discussed based on symmetry-considerations. This connection enables us to predict a complete high-energy cluster spectrum from the description of the low-energy quartet part. As…

Nuclear Theory · Physics 2016-05-04 J. Cseh , G. Riczu

We extend the spherical coupled-cluster ab initio method for open-shell nuclei where two nucleons are removed from a shell subclosure. Following the recent implementation of the two-particle attached approach [Phys. Rev.C 110 (2024) 4,…

Nuclear Theory · Physics 2026-02-06 Francesco Marino , Francesca Bonaiti , Sonia Bacca , Gaute Hagen , Gustav R. Jansen

We present ab-initio calculations for 3H, 4He, 16O, and 40Ca based on two-nucleon low-momentum interactions Vlowk within coupled-cluster theory. For 3H and 4He, our results are within 70 keV and 10 keV of the corresponding Faddeev and…

Nuclear Theory · Physics 2008-11-26 G. Hagen , D. J. Dean , M. Hjorth-Jensen , T. Papenbrock , A. Schwenk

We propose a new Monte Carlo method called the pinhole trace algorithm for {\it ab initio} calculations of the thermodynamics of nuclear systems. For typical simulations of interest, the computational speedup relative to conventional…

We present and analyze results of the relativistic coupled-cluster calculation of energies, hyperfine constants, and dipole matrix elements for the $2s$, $2p_{1/2}$, and $2p_{3/2}$ states of Li atom. The calculations are complete through…

Atomic Physics · Physics 2011-07-13 A. Derevianko , S. G. Porsev , K. Beloy

We report the implementation of equation-of-motion coupled-cluster (EOMCC) method in the four-component relativistic framework with the spherical atomic potential to generate the excited states from a closed-shell atomic configuration. This…

Atomic Physics · Physics 2015-06-19 D. K. Nandy , Yashpal Singh , B. K. Sahoo

The initial-state geometry in relativistic heavy-ion collisions provides a novel probe to nuclear cluster structure. For $^{20}$Ne, a novel approach is proposed to distinguish between the cluster configurations (5$\alpha$ versus $\alpha +…

Nuclear Theory · Physics 2026-03-03 Pei Li , Bo Zhou , Guo-Liang Ma

A version of the method of accurate calculations for few valence-electron atoms which combines linearized single-double coupled cluster method with the configuration interaction technique is presented. The use of the method is illustrated…

Atomic Physics · Physics 2015-06-19 V. A. Dzuba

Coupled cluster methods are widely regarded as the gold standard of computational quantum chemistry as they are perceived to offer the best compromise between computational cost and a high-accuracy resolution of the ground state eigenvalue…

Numerical Analysis · Mathematics 2025-12-03 Muhammad Hassan , Yvon Maday

This is a preliminary draft of Chapters 4-5 of our forthcoming textbook "Introduction to Cluster Algebras." Chapters 1-3 have been posted as arXiv:1608.05735. This installment contains: Chapter 4. New patterns from old Chapter 5. Finite…

Combinatorics · Mathematics 2021-08-31 Sergey Fomin , Lauren Williams , Andrei Zelevinsky

The coupled-channels method has been a standard tool in analyzing heavy-ion fusion reactions at energies around the Coulomb barrier. We investigate three simplifications usually adopted in the coupled-channels calculations. These are i) the…

Nuclear Theory · Physics 2016-06-22 K. Hagino , J. M. Yao
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