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Related papers: RPA vs. exact shell-model correlation energies

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In principle, the Luttinger-Ward Green's function formalism allows one to compute simultaneously the total energy and the quasiparticle band structure of a many-body electronic system from first principles. We present approximate and exact…

Materials Science · Physics 2015-05-18 Sohrab Ismail-Beigi

We present an extension of the random--phase approximation (RPA) where the RPA phonons are used as building blocks to construct the excited states. In our model, that we call double RPA (DRPA), we include up to two RPA phonons. This is an…

Nuclear Theory · Physics 2016-02-17 D. Gambacurta , F. Catara , M. Grasso , M. Sambataro , M. V. Andrés , E. G. Lanza

We consider several spin-unrestricted random-phase approximation (RPA) variants for calculating correlation energies, with and without range separation, and test them on datasets of atomization energies and reaction barrier heights. We show…

Chemical Physics · Physics 2016-03-01 Bastien Mussard , Peter Reinhardt , Janos Angyan , Julien Toulouse

The direct random-phase approximation (dRPA) is used to calculate and compare atomization energies for the HEAT set and 10 selected molecules of the G2-1 set using both plane waves and Gaussian-type orbitals. We describe detailed procedures…

We recently introduced an efficient methodology to perform density-corrected Hartree-Fock density functional theory (DC(HF)-DFT) calculations and an extension to it we called "corrected" HF DFT (C(HF)-DFT). In this work, we take a further…

Chemical Physics · Physics 2023-11-10 Daniel Graf , Alex J. W. Thom

In a recent article [Phys. Rev. B 90, 125102 (2014)] we showed that the random phase approximation with exchange (RPAx) gives accurate total energies for a diverse set of systems including the high and low density regime of the homogeneous…

Strongly Correlated Electrons · Physics 2016-05-11 Nicola Colonna , Maria Hellgren , Stefano de Gironcoli

The action of the long-range residual force on the expectation value of observables in the nuclear ground states is evaluated by finding optimal values for the coefficients of the canonical transformation which connects the phonon vacuum…

Nuclear Theory · Physics 2015-06-12 S. Mishev

A fully self-consistent renormalized random-phase approximation is constructed based on the self-consistent Hartree-Fock mean field plus exact pairing solutions (EP). This approach exactly conserves the particle number and restores the…

Nuclear Theory · Physics 2019-06-06 L. Tan Phuc , N. Quang Hung , N. Dinh Dang

Nuclear state densities are important inputs to statistical models of compound-nucleus reactions. State densities are often calculated with self-consistent mean-field approximations that do not include important correlations and have to be…

Nuclear Theory · Physics 2021-06-16 P. Fanto , Y. Alhassid

We demonstrate that ground state energies approaching chemical accuracy can be obtained by combining the adiabatic connection fluctuation-dissipation theorem (ACFDT) with time-dependent density functional theory (TDDFT). The key ingredient…

Materials Science · Physics 2014-05-29 Thomas Olsen , Kristian S. Thygesen

We present an efficient implementation of the random phase approximation (RPA) for molecular systems within the domain-based local pair natural orbital (DLPNO) framework. With optimized parameters, DLPNO-RPA achieves approximately 99.9%…

Chemical Physics · Physics 2025-08-18 Yu Hsuan Liang , Xing Zhang , Garnet Kin-Lic Chan , Timothy C. Berkelbach , Hong-Zhou Ye

The effects of ground-state correlations on the damping of isovector giant dipole resonances in $LS$ closed shell nuclei $^{16}$O and $^{40}$Ca are studied using extended random-phase-approximation (RPA) approaches derived from the…

Nuclear Theory · Physics 2022-02-24 Mitsuru Tohyama

We calculate the ground state energies of a system of two dipolar fermions trapped in a harmonic oscillator potential. The dipoles are assumed to be aligned parallel to each other. We perform the calculations of ground state energy as a…

Atomic and Molecular Clusters · Physics 2014-10-09 Amit K. Das , Arup Banerjee

In wavefunction-based $\textit{ab-initio}$ quantum mechanical calculations, achieving absolute convergence with respect to the one-electron basis set is a long-standing challenge. In this work, using the random phase approximation (RPA)…

Materials Science · Physics 2025-10-17 Hao Peng , Xinguo Ren

We investigate various approximations to the correlation energy of a H$_2$ molecule in the dissociation limit, where the ground state is poorly described by a single Slater determinant. The correlation energies are derived from the density…

Strongly Correlated Electrons · Physics 2014-05-06 Thomas Olsen , Kristian S. Thygesen

The optimized effective potential (OEP) method presents an unambiguous way to construct the Kohn-Sham potential corresponding to a given diagrammatic approximation for the exchange-correlation functional. The OEP from the random-phase…

Materials Science · Physics 2023-07-18 Stefan Riemelmoser , Merzuk Kaltak , Georg Kresse

We recently demonstrated a connection between the random phase approximation (RPA) and coupled cluster theory [J. Chem. Phys. 129, 231101 (2008)]. Based on this result, we here propose and test a simple scheme for introducing long-range RPA…

Materials Science · Physics 2009-11-13 Benjamin G. Janesko , Thomas M. Henderson , Gustavo E. Scuseria

Starting from the general expression for the ground state correlation energy in the adiabatic connection fluctuation dissipation theorem (ACFDT) framework, it is shown that the dielectric matrix formulation, which is usually applied to…

Chemical Physics · Physics 2016-04-25 Bastien Mussard , Dario Rocca , Georg Jansen , Janos Angyan

A self-consistent random phase approximation (RPA) is proposed as an effective Hamiltonian method in Light-Front Field Theory (LFFT). We apply the general idea to the light-front massive Schwinger model to obtain a new bound state equation…

High Energy Physics - Theory · Physics 2009-10-31 Koji Harada

The relativistic mean field approach (RMF) is well known for describing accurately binding energies and nucleon distributions in atomic nuclei throughout the nuclear chart. The random phase approximation (RPA) built on top of the RMF is…

Nuclear Theory · Physics 2008-11-26 Nguyen Van Giai , Haozhao Liang , Jie Meng