Related papers: Semi-classical analysis of real atomic spectra bey…
We develop a semiclassical theory for the spectral rigidity of non-hydrogenic Rydberg atoms in electric fields and evaluate the significant deviations from the well-known Poissonian behaviour in the hydrogenic case. The resulting formula is…
We extend a theory of first order hbar corrections to Gutzwiller's trace formula for systems with a smooth potential to systems with discrete symmetries and, as an example, apply the method to the two-dimensional hydrogen atom in a uniform…
A brief review of the manifestations of classical chaos observed in atomic systems is presented. Particular attention is paid to the analysis of atomic spectra by periodic orbit-type theories. For diamagnetic non-hydrogenic Rydberg atoms,…
Since its first appearance in 1971, Gutzwiller's trace formula has been extended to systems with continuous symmetries, in which not all periodic orbits are isolated. In order to avoid the divergences occurring in connection with symmetry…
We study the Hydrogen atom as a quantum mechanical system with a Coulomb like potential, with a semiclassical approach based on an effective description of quantum mechanics. This treatment allows us to describe the quantum state of the…
Semiclassical periodic-orbit theory and closed-orbit theory represent a quantum spectrum as a superposition of contributions from individual classical orbits. Close to a bifurcation, these contributions diverge and have to be replaced with…
The existence of periodic orbit bunches is proven for the diamagnetic Kepler problem. Members of each bunch are reconnected differently at self-encounters in phase space but have nearly equal classical action and stability parameters.…
The appearance of tracks, close to classical orbits, left by charged quantum particles propagating inside a detector, such as a cavity periodically illuminated by light pulses, is studied for a family of idealized models. In the…
Although hydrogen in external fields is a paradigm for the application of periodic orbits and the Gutzwiller trace formula to a real system, the trace formula has never been applied successfully to other Rydberg atoms. We show that spectral…
Closed-orbit theory provides a general approach to the semiclassical description of photo-absorption spectra of arbitrary atoms in external fields, the simplest of which is the hydrogen atom in an electric field. Yet, despite its apparent…
The application of a classical approach to various quantum problems - the secular perturbation approach to quantization of a hydrogen atom in external fields and a helium atom, the adiabatic switching method for calculation of a…
Hydrogen atom is studied as a quantum-classical hybrid system, where the proton is treated as a classical object while the electron is regarded as a quantum object. We use a well known mean-field approach to describe this hybrid hydrogen…
Bifurcations of classical orbits introduce divergences into semiclassical spectra which have to be smoothed with the help of uniform approximations. We develop a technique to extract individual energy levels from semiclassical spectra…
The S-matrix theory formulation of closed-orbit theory recently proposed by Granger and Greene is extended to atoms in crossed electric and magnetic fields. We then present a semiclassical quantization of the hydrogen atom in crossed…
Gutzwiller's trace formula and Bogomolny's formula are applied to a non--specific, non--scalable Hamiltonian system, a two--dimensional anharmonic oscillator. These semiclassical theories reproduce well the exact quantal results over a…
We give a method to compute the smooth part of the density of states in a semi-classical expansion, when the Hamiltonian contains a Coulomb potential and non-cartesian coordinates are appropriate. We apply this method to the case of the…
We extend the Gutzwiller trace formula to systems of noninteracting identical particles. The standard relation for isolated orbits does not apply since the energy of each particle is separately conserved causing the periodic orbits to occur…
We analyze strong field atomic dynamics semiclassically, based on a full time-dependent description with the Hermann-Kluk propagator. From the properties of the exact classical trajectories, in particular the accumulation of action in time,…
We have extended the semi-classical theory to include a general account of matrix valued Hamiltonians, i.e. those that describe quantum systems with internal degrees of freedoms, based on a generalization of the Gutzwiller trace formula for…
Gutzwiller's trace formula has a central place in quantum chaos because it provides semiclassical approximations for quantum energy levels in classically chaotic systems by linking them to classical periodic orbits. In this didactic…