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Behavior of a dilute polymer solution in a random three-dimensional flow with an average shear is studied experimentally. Polymer contribution to the shear stress is found to be more than two orders of magnitude higher than in a laminar…

Chaotic Dynamics · Physics 2009-10-31 Alexander Groisman , Victor Steinberg

Polymers in nonuniform flows undergo strong deformation, which in the presence of persistent stretching can result in the coil-stretch transition. This phenomenon has been characterized by using the formalism of nonequilibrium statistical…

Soft Condensed Matter · Physics 2023-05-24 Stefano Musacchio , Victor Steinberg , Dario Vincenzi

The interaction of polymers with small-scale velocity gradients can trigger a coil-stretch transition in the polymers. We analyze this transition within a direct numerical simulation of shear turbulence with an Oldroyd-B model for the…

Chaotic Dynamics · Physics 2009-11-07 Bruno Eckhardt , Jochen Kronjaeger , Joerg Schumacher

The influence of an external flow on the relaxation dynamics of a single polymer is investigated theoretically and numerically. We show that a pronounced dynamical slowdown occurs in the vicinity of the coil-stretch transition, especially…

Chaotic Dynamics · Physics 2007-05-23 Antonio Celani , Alberto Puliafito , Dario Vincenzi

We analyze the conformational dynamics and statistical properties of an active polymer model. The polymer is described as a freely-jointed bead-rod chain subject to stochastic active force dipoles that act on the suspending solvent where…

Soft Condensed Matter · Physics 2022-02-09 Achal Mahajan , David Saintillan

A polymer in a turbulent flow undergoes the coil-stretch transition when the Weissenberg number, i.e. the product of the Lyapunov exponent of the flow and the relaxation time of the polymer, surpasses a critical value. The effect of…

Fluid Dynamics · Physics 2020-11-10 Dario Vincenzi

Stretched polymers with attractive interaction are studied in two and three dimensions. They are described by biased self-avoiding random walks with nearest neighbour attraction. The bias corresponds to opposite forces applied to the first…

Statistical Mechanics · Physics 2009-11-07 Peter Grassberger , Hsiao-Ping Hsu

Polymer stretching in random smooth flows is investigated within the framework of the FENE dumbbell model. The advecting flow is Gaussian and short-correlated in time. The stationary probability density function of polymer extension is…

Chaotic Dynamics · Physics 2007-05-23 M. Martins Afonso , D. Vincenzi

We consider the internal dynamics of the polymer molecule which is injected in the chaotic flow with strong mean shear component. The flow geometry corresponds to the recent experiments on the elastic turbulence (Groisman, Steinberg 2000).…

Chaotic Dynamics · Physics 2007-05-23 K. S. Turitsyn

The statistics of polymers advected by a turbulent flow are investigated. To limit the polymer lengths above to coil-stretch transition, a FENE-P type relaxation law is used. The turbulence is modeled by a random strain, delta-correlated in…

Chaotic Dynamics · Physics 2009-11-07 Jean-Luc Thiffeault

The stretching of a polymer chain by a large scale chaotic flow is considered. The steady state which emerges as a balance of the turbulent stretching and anharmonic resistance of the chain is quantitatively described, i.e. the dependency…

chao-dyn · Physics 2009-10-31 Michael Chertkov

Extensional rheometry and Brownian Dynamics simulations of flexible polymer solutions confirm predictions based on blob concepts that coil--stretch hysteresis in extensional flows increases with concentration, reaching a maximum at the…

Soft Condensed Matter · Physics 2020-07-03 Ranganathan Prabhakar , Chandi Sasmal , Duc At Nguyen , Tam Sridhar , J. Ravi Prakash

We study flexible polymer macromolecules in a crowded (porous) environment, modelling them as self-attracting self-avoiding walks (SASAW) on site-diluted percolative lattices in space dimensions d=2, 3. The influence of stretching force on…

Soft Condensed Matter · Physics 2009-12-09 V. Blavatska , W. Janke

When injected through a contraction, high molecular weight polymer solutions exhibit a sharp increase of apparent viscosity which originates from stretching polymer chains above a critical extension rate. This chain stretching can also…

Fluid Dynamics · Physics 2020-04-22 Sandeep Garrepally , Stephane Jouenne , Peter D. Olmsted , Francois Lequeux

The dynamics of polymers in a random smooth flow is investigated in the framework of the Hookean dumbbell model. The analytical expression of the time-dependent probability density function of polymer elongation is derived explicitly for a…

Chaotic Dynamics · Physics 2009-11-10 A. Celani , S. Musacchio , D. Vincenzi

Considering the dynamics of a polymer with finite extensibility placed in a chaotic flow with large mean shear, we explain how the statistics of polymer extension changes with Weissenberg number, ${\it Wi}$, defined as the product of the…

Statistical Mechanics · Physics 2007-05-23 M. Chertkov , I. Kolokolov , V. Lebedev , K. Turitsyn

We study the conformation and dynamics of a single polymer chain that is pulled by a constant force applied at its one end with the other end free. Such a situation is relevant to the growing technology of manipulating individual…

Soft Condensed Matter · Physics 2015-06-04 Takahiro Sakaue , Takuya Saito , Hirofumi Wada

The dynamics of elongated inertial particles in an extensional flow is studied numerically by performing simulations of freely jointed bead-rod chains. The coil-stretch transition and the tumbling instability are characterized as a function…

Fluid Dynamics · Physics 2018-08-29 Christophe Henry , Giorgio Krstulovic , Jérémie Bec

We theoretically investigate the kinetics of the folding transition of a single semiflexible polymer. In the folding transition, the growth rate decrease with an increase in the number of monomers in a collapsed domain, suggesting that the…

Soft Condensed Matter · Physics 2009-11-13 Natsuhiko Yoshinaga

We study the dynamics of the phase behavior of a polymer blend in the presence of shear flow. By adopting a two fluid picture and using a generalization of the concept of material derivative, we construct kinetic equations that describe the…

Soft Condensed Matter · Physics 2009-10-30 Tao Sun , Anna C. Balazs , David Jasnow
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