Related papers: Classical and semiclassical studies of the hydroge…
When placed in parallel magnetic and electric fields, the electron trajectories of a classical hydrogen atom are chaotic. The classical escape rate of such a system can be computed with classical trajectory Monte Carlo techniques, but these…
Excitons, i.e. the bound states of an electron and a positively charged hole are the solid state analogue of the hydrogen atom. As such they exhibit a Rydberg series, which in cuprous oxide has been observed up to high principal quantum…
We study a stiff quasi-periodic orbit of the electromagnetic two-body problem of Dirac's electrodynamics of point charges. We expand the delay equations of motion about circular orbits to obtain the variational equations up to nonlinear…
Spectra of the geometric collective model of atomic nuclei are analyzed to identify chaotic correlations among nonrotational states. The model has been previously shown to exhibit a high degree of variability of regular and chaotic…
A new model of quantum mechanics, Classical Quantum Mechanics, is based on the (nearly heretical) postulate that electrons are physical objects that obey classical physical laws. Indeed, ionization energies, excitation energies etc. are…
The quantum mechanical description of the chemical bond is generally given in terms of delocalized bonding orbitals, or, alternatively, in terms of correlations of occupations of localised orbitals. However, in the latter case, multiorbital…
The multiphoton ionization of hydrogen by a strong bichromatic microwave field is a complex process prototypical for atomic control research. Periodic orbit analysis captures this complexity: Through the stability of periodic orbits we can…
In the current study, the existence of periodic orbits around a fixed homogeneous cube is investigated, and the results have powerful implications for examining periodic orbits around non-spherical celestial bodies. In the two different…
In the context of two-dimensional spacetime within a helium atom, both 1s electrons are characterized by wave functions that observe duality equation. They are symmetric, orthogonal and interwoven, forming a dynamic rope structure at any…
A fully analytical approximation for the observable characteristics of many-electron atoms is developed via a complete and orthonormal hydrogen-like basis with a single-effective charge parameter for all electrons of a given atom. The basis…
In the field of molecular electronics, particularly in quantum transport studies, the orientation of molecules plays a crucial role. This orientation, with respect to the electrodes, can be defined through the cavity of ring-shaped…
We study the formation of molecular states in a two-electron quantum dot as a function of the barrier potential dividing the dot. The increasing barrier potential drives the two electron system from an artificial helium atom to an…
New ways to treat electron correlation in electronic structure problems are discussed in the context of many-electron theory. The present work focuses primarily on static correlation. In related work, a method for including dynamical…
We present a unified view of orientational ordering in phases I, II, and III of solid hydrogen. Phases II and III are orientationally ordered, while the ordering objects in phase II are angular momenta of rotating molecules, and in phase…
The hydrogen atom theory is developed for the de Sitter and anti de Sitter spaces on the basis of the Klein-Gordon-Fock wave equation in static coordinates. In both models, after separation of the variables, the problem is reduced to the…
We report benchmark results for one-dimensional (1D) atomic and molecular systems interacting via the Coulomb operator $|x|^{-1}$. Using various wavefunction-type approaches, such as Hartree-Fock theory, second- and third-order…
The S-matrix theory formulation of closed-orbit theory recently proposed by Granger and Greene is extended to atoms in crossed electric and magnetic fields. We then present a semiclassical quantization of the hydrogen atom in crossed…
Isolated electrons resting above a helium surface are predicted to have a bound spectrum corresponding to a one-dimensional hydrogen atom. But in fact, the observed spectrum is closer to that of a quantum-defect atom. Such a model is…
Recently, the correlation theory of the chemical bond was developed, which applies concepts of quantum information theory for the characterization of chemical bonds, based on the multiorbital correlations within the molecule. Here for the…
Quantum-classical correspondence in chaotic systems is a long-standing problem. We describe a method to quantify Bohr's correspondence principle and calculate the size of quantum numbers for which we can expect to observe quantum-classical…