Related papers: The hydrogen atom in an electric field: Closed-orb…
Bifurcations of classical orbits introduce divergences into semiclassical spectra which have to be smoothed with the help of uniform approximations. We develop a technique to extract individual energy levels from semiclassical spectra…
With increasing energy the diamagnetic hydrogen atom undergoes a transition from regular to chaotic classical dynamics, and the closed orbits pass through various cascades of bifurcations. Closed orbit theory allows for the semiclassical…
Semiclassical periodic-orbit theory and closed-orbit theory represent a quantum spectrum as a superposition of contributions from individual classical orbits. Close to a bifurcation, these contributions diverge and have to be replaced with…
A systematic study of closed classical orbits of the hydrogen atom in crossed electric and magnetic fields is presented. We develop a local bifurcation theory for closed orbits which is analogous to the well-known bifurcation theory for…
The S-matrix theory formulation of closed-orbit theory recently proposed by Granger and Greene is extended to atoms in crossed electric and magnetic fields. We then present a semiclassical quantization of the hydrogen atom in crossed…
Closed orbit theory is generalized to the semiclassical calculation of cross-correlated recurrence functions for atoms in external fields. The cross-correlation functions are inverted by a high resolution spectral analyzer to obtain the…
The quantum spectra of hydrogen atoms in various magnetic fields have been calculated with the closed orbit theory. The magnitude of the magnetic field decreases from 5.96 T to 0.56T with a step of 0.6T. We demonstrate schematically that…
The standard closed-orbit theory is extended for the photodetachment of negative ions in a time-dependent electric field. The time-dependent photodetachment rate is specifically studied in the presence of a single-cycle terahertz pulse,…
We undertake a semiclassical analysis of the spectral properties (modulations of photoabsorption spectra, energy level statistics) of a simple Rydberg molecule in static fields within the framework of Closed-Orbit/Periodic-Orbit theories.…
The multiphoton ionization of hydrogen by a strong bichromatic microwave field is a complex process prototypical for atomic control research. Periodic orbit analysis captures this complexity: Through the stability of periodic orbits we can…
We investigate the multiphoton ionization of hydrogen driven by a strong bichromatic microwave field. In a regime where classical and quantum simulations agree, periodic orbit analysis captures the mechanism: Through the linear stability of…
A hierarchical ordering is demonstrated for the periodic orbits in a strongly coupled multidimensional Hamiltonian system, namely the hydrogen atom in crossed electric and magnetic fields. It mirrors the hierarchy of broken resonant tori…
We study the Hydrogen atom as a quantum mechanical system with a Coulomb like potential, with a semiclassical approach based on an effective description of quantum mechanics. This treatment allows us to describe the quantum state of the…
Hydrogen atom is studied as a quantum-classical hybrid system, where the proton is treated as a classical object while the electron is regarded as a quantum object. We use a well known mean-field approach to describe this hybrid hydrogen…
A method is presented for determining the initial conditions of classical orbits from the quantum spectra of the diamagnetic hydrogen atom. Each classical trajectory which is closed at the nucleus produces a sinusoidal fluctuation in the…
The hydrogen molecule contains the basic ingredients to understand the chemical bond, i.e, a pair of electrons. We show a step to understand The Correspondence Principle for chaotic system in the Chemical World. The hydrogen molecule is…
We study the spectrum of the hydrogen atom in Snyder space in a semiclassical approximation based on a generalization of the Born-Sommerfeld quantization rule. While the corrections to the standard quantum mechanical spectrum arise at first…
We develop a semiclassical theory for the spectral rigidity of non-hydrogenic Rydberg atoms in electric fields and evaluate the significant deviations from the well-known Poissonian behaviour in the hydrogenic case. The resulting formula is…
Real atomic systems, like the hydrogen atom in a magnetic field or the helium atom, whose classical dynamics are chaotic, generally present both discrete and continuous symmetries. In this letter, we explain how these properties must be…
Quasi-static models of barrier suppression have played a major role in our understanding of the ionization of atoms and molecules in strong laser fields. Despite their success, in the case of diatomic molecules these studies have so far…