Related papers: Nonadiabatic dynamics in semiquantal physics
Conical intersections are ubiquitous in polyatomic molecules and responsible for a wide range of phenomena in chemistry and physics. We introduce and implement a local diabatic representation for the correlated electron-nuclear dynamics…
We introduce non-adiabatic semiclassical dressed states for a quantum system interacting with an electromagnetic field of variable amplitude and phase, and presence of dumping. We also introduce a generalized adiabatic condition, which…
We consider non-adiabatic transitions in multiple dimensions, which occur when the Born-Oppenheimer approximation breaks down. We present a general, multi-dimensional algorithm which can be used to accurately and efficiently compute the…
We study the dynamics of a driven non-Hermitian superconducting qubit which is perturbed by quantum jumps between energy levels, a purely quantum effect with no classical correspondence. The quantum jumps mix the qubit states leading to…
In this thesis, it is presented a set of results in adiabatic dynamics (closed and open system) and transitionless quantum driving that promote some advances in our understanding on quantum control and Hamiltonian inverse engineering. In…
Starting form a microscopic system-environment model, we construct a quantum dynamical semigroup for the reduced evolution of the open system. The difference between the true system dynamics and its approximation by the semigroup has the…
Accurate description of nonadiabatic dynamics of molecules at metal surfaces involving electron transfer has been a longstanding challenge for theory. Here, we tackle this problem by first constructing high-dimensional neural network…
Employing a recently developed method that is numerically accurate within a model space simulating the real-time dynamics of few-body systems interacting with macroscopic environmental quantum fields, we analyze the full dynamics of an…
The meaning of statistical experiments with single microsystems in quantum mechanics is discussed and a general model in the framework of non-relativistic quantum field theory is proposed, to describe both coherent and incoherent…
An analytically solvable model for quasi-static transformations across quantum critical points featuring Bosonic quasi-particle excitations is presented. The model proves that adiabaticity breakdown is a general feature of universal slow…
The Born-Oppenheimer (BO) approximation has shaped our understanding on molecular dynamics microscopically in many physical and chemical systems. However, there are many cases that we must go beyond the BO approximation, particularly when…
We investigate the quantum mechanics of a single particle constrained to move along an arbitrary smooth reference curve by a confinement that is allowed to vary along the waveguide. The Schr\"odinger equation is evaluated in the adapted…
Following our previous paper, Bergeron et al, Smooth quantum dynamics of the mixmaster universe, Phys. Rev. D 92, 061302(R) (2015), concerning the quantization of the vacuum Bianchi IX model and the Born-Huang-Oppenheimer framework, we…
A non-adiabatic nuclear wavepacket dynamics simulation of the H$_2$O$^+$ de-excitation process is performed based on electronic structure calculations using the variational quantum eigensolver. The adiabatic potential energy surfaces and…
The decoherence of a two-state system coupled with a sub-Ohmic bath is investigated theoretically by means of the perturbation approach based on a unitary transformation. It is shown that the decoherence depends strongly and sensitively on…
In this letter we give a systematic derivation and justification of the semiclassical model for the slow degrees of freedom in adiabatic slow-fast systems first found by Littlejohn and Flynn [5]. The classical Hamiltonian obtains a…
With the aim of describing real-time electron dynamics, we introduce an adiabatic approximation for the equation of motion of the one-body reduced-density matrix (one-matrix). The eigenvalues of the one-matrix, which represent the…
In the context of the exact factorization of the electron-nuclear wave function, the coupling between electrons and nuclei beyond the adiabatic regime is encoded (i) in the time-dependent vector and scalar potentials and (ii) in the…
Dephasing in quantum systems is typically the result of its interaction with environmental degrees of freedom. We investigate within a spin-boson model the influence of a super-Ohmic environment on the dynamics of a quantum two-state…
An alternative approach to decoherence, named non-dynamical decoherence is developed and used to resolve the quantum measurement problem. According to decoherence, the observed system is open to a macroscopic apparatus(together with a…