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The self-assembly of copolymeric vesicles and micelles in micromixers is studied by External Potential Dynamics (EPD) simulations -- a dynamic density functional approach that explicitly accounts for the polymer architecture both at the…

Soft Condensed Matter · Physics 2018-04-10 Simon Kessler , Klaus Drese , Friederike Schmid

We study the coalescence of nanoscale metal clusters in an inert-gas atmosphere using constant-energy molecular dynamics. The coalescence proceeds via atomic diffusion with the release of surface energy raising the temperature. If the…

Condensed Matter · Physics 2007-05-23 Shaun C. Hendy , Simon A. Brown , Michael Hyslop

We investigate analytically and numerically a system of clusters evolving via collisions with clusters of minimal mass (monomers). Each collision either leads to the addition of the monomer to the cluster or the chipping of a monomer from…

Statistical Mechanics · Physics 2024-03-06 Roman R. Dyachenko , Sergey A. Matveev , P. L. Krapivsky

Because final properties of nanoscale polymeric structures are largely determined by the solid-state microstructure of the confined polymer, it is imperative not only to understand how the microstructure of polymers develops under nanoscale…

We demonstrate a remarkable equivalence in structure measured by total X-ray scattering methods between very small metallic nanoparticles and bulk metallic glasses (BMGs), thus connecting two disparate fields, shedding new light on both.…

Block copolymer melts self-assemble in the bulk into a variety of nanostructures, making them perfect candidates to template the position of nanoparticles. The morphological changes of block copolymers are studied in the presence of a…

Soft Condensed Matter · Physics 2019-10-31 Javier Diaz , Marco Pinna , Andrei V. Zvelindovsky , Ignacio Pagonabarraga

A unique property of metal nanoclusters is the "superatom" shell structure of their delocalized electrons. The electronic shell levels are highly degenerate and therefore represent sharp peaks in the density of states. This can enable…

Superconductivity · Physics 2015-12-17 Avik Halder , Vitaly V. Kresin

Nanostructured films obtained by the assembling of preformed atomic clusters are of strategic importance for a wide variety of applications. The deposition of clusters produced in the gas phase onto a substrate offers the possibility to…

Mesoscale and Nanoscale Physics · Physics 2018-04-18 Francesca Borghi , Alessandro Podestà , Claudio Piazzoni , Paolo Milani

Controlled assembly of single-crystal, colloidal maghemite nanoparticles is facilitated via a high-temperature polyol-based pathway. Structural characterization shows that size-tunable nanoclusters of 50 and 86 nm diameters (D), with high…

We propose a unifying, analytical theory accounting for the self-organization of colloidal systems in nano- or micro-cluster phases. We predict the distribution of cluter sizes with respect to interaction parameters and colloid…

Soft Condensed Matter · Physics 2009-11-13 Nicolas Destainville , Lionel Foret

We introduce a new experimental approach to study the structural transitions of large numbers of nanoparticle-coated droplets as their volume is reduced. We use an emulsion system where the dispersed phase is slightly soluble in the…

Soft Condensed Matter · Physics 2012-09-28 Sujit S. Datta , Ho Cheung Shum , David A. Weitz

We present modeling approaches to explain mechanisms of control of uniformity (narrow distribution) of sizes and shapes in synthesis of nanosize crystals and micron-size colloids. We consider those situations when the nanocrystals are…

Soft Condensed Matter · Physics 2010-11-29 Vyacheslav Gorshkov , Vladimir Privman

Metal clusters are partway between molecular and bulk systems and thus exhibit special physical and chemical properties. Atoms can rearrange within a cluster to form different structural isomers. Internal degrees of freedom and the…

Materials Science · Physics 2019-07-31 Barbara A. J. Lechner , Fabian Knoller , Alexander Bourgund , Ueli Heiz , Friedrich Esch

Ample experimental evidence has been accumulated demonstrating that the formation of monodispersed colloids proceeds through a more complex mechanism, than the generally excepted diffusional "burst nucleation" process. Instead, the…

Materials Science · Physics 2010-09-22 Jongsoon Park , Vladimir Privman , Egon Matijevic

Control of the crystallization process at the microscopic level makes it possible to generate the nanocrystalline samples with the desired structural and morphological properties, that is of great importance for modern industry. In the…

Materials Science · Physics 2019-03-25 Bulat N. Galimzyanov , Dinar T. Yarullin , Anatolii V. Mokshin

We investigate the effect of the size of nanoparticles on the behaviour of equilibrium polymers (Wormlike micelles) and nanoparticle system. The self-organised structures of nanoparticles in the system show a morphological change from…

Soft Condensed Matter · Physics 2018-06-08 Sk. Mubeena

We present an experimental study of the statistical properties of millimeter-size spheres floating on the surface of a turbulent flow. The flow is generated in a layer of liquid metal by an electromagnetic forcing. By using two magnet…

Fluid Dynamics · Physics 2016-07-04 Pablo Gutiérrez , Sébastien Aumaître

We study the dynamics of a suspension of magnetic nanoparticles. Their relaxation times are strongly size-dependent. The dominant mode of relaxation is also governed by the size of the particles. As a result the dynamics is greatly altered…

Soft Condensed Matter · Physics 2012-08-21 Vanchna Singh , Varsha Banerjee , Manish Sharma

With scanning tunneling microscopy, we study the very early stage of Si deposition on a Pb monolayer covered Si(111) surface. We find a special type of Si magic clusters which are highly mobile on the defect-free surface but may be trapped…

We present a detailed molecular-dynamics study of the melting, freezing, and coalescence of gold nanoclusters within the framework of the embedded-atom method. Concerning melting, we find the process to first affect the surface…

Materials Science · Physics 2009-10-30 Laurent J. Lewis , Pablo Jensen , Jean-Louis Barrat