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Transition metal complexes for photochemical applications often feature a high density of electron-vibrational states characterized by nonadiabatic and spin-orbit couplings. Overall, the dynamics after photoexcitation is shaped by rapid…

Chemical Physics · Physics 2023-05-16 Olga Bokareva , Oliver Kühn

Isothermal-isobaric molecular dynamics simulations have been performed to examine a broad set of properties of the model water-1,2-dimethoxyethane (DME) mixture as a function of composition. The SPC-E and TIP4P-Ew water models and the…

Soft Condensed Matter · Physics 2017-10-04 J. Gujt , H. Dominguez , S. Sokolowski , O. Pizio

Modeling the electronic and optical properties of organic semiconductors remains a challenge for theory, despite the remarkable progress achieved in the last three decades. The complexity of these systems, including structural (dis)order…

Materials Science · Physics 2023-02-15 Caterina Cocchi , Michele Guerrini , Jannis Krumland , Ngoc Trung Nguyen , Ana M. Valencia

Discrete particle simulations are used to model segregation in granular mixtures of three different particle species in a horizontal rotating drum. Axial band formation is observed, with medium-size particles tending to be located between…

Soft Condensed Matter · Physics 2009-11-13 D. C. Rapaport

Various-thickness Ag islands were prepared on Si(111)-7$\times$7 using the one-step deposition at a high substrate temperature. An electronic state centered at -0.40$\sim$-0.15eV versus E$_{Fermi}$, detectable on the surface of the Ag…

Materials Science · Physics 2011-02-08 Fang Cheng , Xiong Zhou , Yang He , Qian Shen , Hailing Liang , Heng Li , Jianlong Li , Wei Ji , Kai Wu

Because of consuming energy to drive their motion, systems of active colloids are intrinsically out of equilibrium. In the past decade, a variety of intriguing dynamic patterns have been observed in systems of active colloids, and they…

Soft Condensed Matter · Physics 2020-04-16 Zhan Ma , Mingcheng Yang , Ran Ni

We report the results of ab initio molecular dynamics simulations of liquid Ga_xAs_{1-x} alloys at five different concentrations, at a temperature of 1600 K, just above the melting point of GaAs. The liquid is predicted to be metallic at…

Condensed Matter · Physics 2009-10-31 R. V. Kulkarni , D. Stroud

We present a computational study of the electronic properties of amorphous SiO2. The ionic configurations used are the ones generated by an earlier molecular dynamics simulations in which the system was cooled with different cooling rates…

Disordered Systems and Neural Networks · Physics 2009-10-30 Thorsten Koslowski , Walter Kob , Katharina Vollmayr

We simulate the liquid silicon surface with first-principles molecular dynamics in a slab geometry. We find that the atom-density profile presents a pronounced layering, similar to those observed in low-temperature liquid metals like Ga and…

Soft Condensed Matter · Physics 2009-10-31 G. Fabricius , E. Artacho , D. Sanchez-Portal , P. Ordejon , D. A. Drabold , J. M. Soler

Despite the widespread use of zeolites in chemical industry, their formation process is not fully understood due to the complex and heterogeneous structure of traditional synthesis media. Hydrated silicate ionic liquids (HSILs) have been…

We study the structural, dynamical and electronic properties of amorphous Si\sub{1-x}Ge\sub{x}:H alloys using first principles local basis molecular dynamics simulation. The network topology and defects in the amorphous network have been…

Materials Science · Physics 2007-05-23 T. A. Abtew , D. A. Drabold

Suspensions of self-propelled particles, such as swimming micro-organisms, are known to undergo complex dynamics as a result of hydrodynamic interactions. This fluid dynamics video presents a numerical simulation of such a suspension, based…

Fluid Dynamics · Physics 2009-10-20 David Saintillan , Amir Alizadeh Pahlavan

In an effort to build a stronger microscopic foundation for radiation damage models in gallium arsenide (GaAs), the electronic properties of radiation-induced damage clusters are studied with atomistic simulations. Molecular dynamics…

Materials Science · Physics 2025-10-07 Jonathan E. Moussa , Stephen M. Foiles , Peter A. Schultz

We use the ``isoconfigurational ensemble'' [Phys. Rev. Lett. {\bf 93}, 135701 (2004)] to analyze both dynamical and structural properties in simulations of a glass forming molecular liquid. We show that spatially correlated clusters of low…

Materials Science · Physics 2009-11-11 Gurpreet S. Matharoo , M. S. Gulam Razul , Peter H. Poole

Aqueous solutions of LiCl are probably the most studied electrolyte solutions related to the complexity of liquid water at low temperatures. Despite the large amount of available experimental data hardly any computational studies were…

Soft Condensed Matter · Physics 2020-04-29 Philip H. Handle

We present a quantum Monte Carlo study of the structure and energetics of silver doped helium clusters AgHe$_n$ for $n$ up to 100. Our simulations show the first solvation shell of the Ag atom to be composed by roughly 20 He atoms, and to…

Atomic and Molecular Clusters · Physics 2009-11-07 Massimo Mella , Maria Carola Colombo , Gabriele Morosi

We present linear ensembles of dangling bond chains on a hydrogen terminated Si(100) surface, patterned in the closest spaced arrangement allowed by the surface lattice. Local density of states maps over a range of voltages extending…

Mesoscale and Nanoscale Physics · Physics 2016-07-21 John A. Wood , Mohammad Rashidi , Mohammad Koleini , Jason L. Pitters , Robert A. Wolkow

Bettini et al. [Nature Nanotech 1, 182 (2006)] reported the first experimental realization of linear atomic chains (LACs) composed of different atoms (Au and Ag). Different contents of Au and Ag were observed in the chains from what found…

Materials Science · Physics 2015-06-16 Pedro Alves da Silva Autreto , Douglas S. Galvao , Emilio Artacho

In this paper, we present new models of germanium selenide chalcogenide glasses heavily doped with silver. The models were readily obtained with ab initio molecular dynamics and their structure agrees closely with diffraction measurements.…

Disordered Systems and Neural Networks · Physics 2009-11-11 De Nyago Tafen , D. A. Drabold , M. Mitkova

Dissociative electron attachment, that is, the cleavage of chemical bonds induced by low-energy electrons, is difficult to model with standard quantum-chemical methods because the involved anions are not bound but subject to autodetachment.…

Chemical Physics · Physics 2022-10-03 Jerryman A. Gyamfi , Thomas -C. Jagau