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First principles density functional calculations of the electronic and magnetic properties of spinel-structure LiV$_{2}$O$_{4}$ have been performed using the full potential linearized augmented planewave method. The calculations show that…

Strongly Correlated Electrons · Physics 2009-10-31 D. J. Singh , P. Blaha , K. Schwarz , I. I. Mazin

We analyze in detail the electronic properties of high pressure hydrogen around the liquid-liquid phase transition based on Coupled Electron-Ion Monte Carlo calculations. Computing the off-diagonal single particle density matrix and the…

Materials Science · Physics 2022-01-26 Carlo Pierleoni , Giovanni Rillo , David M. Ceperley , Markus Holzmann

A new two-pole approximation, which allows to describe the transition from an insulating state to a metallic one at increase of bandwidth, and also the observable in some compounds transition from a metalic state to an insulating one with…

Strongly Correlated Electrons · Physics 2007-05-23 Leonid Didukh

Quantum confinement endows two-dimensional (2D) layered materials with exceptional physics and novel properties compared to their bulk counterparts. Although certain two- and few-layer configurations of graphene have been realized and…

We study the electronic and lattice dynamical properties of compressed solid germane in the pressure range up to 200 GPa with density functional theory. A stable metallic structure, Aba2, with a base-centered orthorhombic symmetry was found…

Superconductivity · Physics 2008-05-01 Chao Zhang , Yanling Li , Xiaojia Chen , Ruiqin Zhang , Haiqing Lin

The electronic structures of element cerium under high pressure remain unclear all the time. We tried to calculate the electronic structures of $\alpha'$, $\alpha"$, and $\epsilon$-Ce which only exist in the presence of pressure, by using…

Strongly Correlated Electrons · Physics 2018-11-02 Haiyan Lu , Li Huang

We report Raman scattering and visible to near-infrared absorption spectra of solid hydrogen under static pressure up to 285 GPa at 85-140 K. We obtain pressure dependences of vibron and phonon modes in agreement with previously determined…

Materials Science · Physics 2009-11-07 Alexander F. Goncharov , Eugene Gregoryanz , Russell J. Hemley , Ho-kwang Mao

Electronic band structures in hydrogenated graphene are theoretically investigated by means of first-principle calculations and an effective tight-binding model. It is shown that regularly designed hydrogenation to graphene gives rise to a…

Mesoscale and Nanoscale Physics · Physics 2024-08-05 Yong-Cheng Jiang , Toshikaze Kariyado , Xiao Hu

Electronic correlation is believed to play an important role in exotic phenomena such as insulator-metal transition, colossal magneto resistance and high temperature superconductivity in correlated electron systems. Recently, it has been…

Knowledge of the behavior of hydrogen in metal hydrides is the key for understanding their electronic properties. So far, no experimental methods exist to access these properties beyond 100 GPa, where high-Tc superconductivity emerges.…

Being the simplest element with just one electron and proton the electronic structure of the Hydrogen atom is known exactly. However, this does not hold for the complex interplay between them in a solid and in particular not at high…

Materials Science · Physics 2014-06-23 Sam Azadi , Thomas D. Kühne

We investigate the influence of hydrogen on the electronic structure of a binary transition metallic glass of V$_{80}$Zr$_{20}$. We examine the hybridization between the hydrogen and metal atoms with the aid of hard x-ray photoelectron…

Materials Science · Physics 2024-03-21 Johan Bylin , Rebecka Lindblad , Lennart Spode , Ralph H. Scheicher , Gunnar K. Pálsson

Atomic metallic hydrogen has been produced in the laboratory at high pressure and low temperature, prompting further investigations of its different properties. However, purely experimental approaches are infeasible because of the extreme…

Materials Science · Physics 2018-05-29 Bo Peng , Ke Xu , Hao Zhang , Hezhu Shao , Gang Ni , Jing Li , Liangcai Wu , Hongliang Lu , Qingyuan Jin , Heyuan Zhu

Characterization of the first ever laboratory produced metallic hydrogen sample relies on measurements of optical spectra. Here we present first-principles calculations of the reflectivity of hydrogen between 400 and 600 GPa in the…

Superconductivity · Physics 2018-02-07 Miguel Borinaga , Julen Ibañez-Azpiroz , Aitor Bergara , Ion Errea

Topological insulators host spin-polarized surface states which robustly span the band gap and hold promise for novel applications. Recent theoretical predictions have suggested that topologically protected surface states may similarly span…

Strongly Correlated Electrons · Physics 2013-08-28 Michael M. Yee , Yang He , Anjan Soumyanarayanan , Dae-Jeong Kim , Zachary Fisk , Jennifer E. Hoffman

We present an accurate study of the static-nucleus electronic energy band gap of solid molecular hydrogen at high pressure. The excitonic and quasiparticle gaps of the $C2/c$, $Pc$, $Pbcn$, and $P6_3/m$ structures at pressures of 250, 300,…

Materials Science · Physics 2017-01-25 Sam Azadi , N. D. Drummond , W. M. C. Foulkes

The flat electronic bands in magic-angle twisted bilayer graphene (MATBG) host a variety of correlated insulating ground states, many of which are predicted to support charged excitations with topologically non-trivial spin and/or valley…

Recent experiments on the two dimensional electron gas in various semiconductor devices have revealed an unexpected metal-insulator transition and have challenged the previously held assumption that there is no such transition in two…

Strongly Correlated Electrons · Physics 2017-02-08 Sudip Chakravarty , Steven Kivelson , Chetan Nayak , Klaus Voelker

While graphene is a semi-metal, a recently synthesized hydrogenated graphene called graphane, is an insulator. We have probed the transformation of graphene upon hydrogenation to graphane within the framework of density functional theory.…

Mesoscale and Nanoscale Physics · Physics 2012-10-05 Prachi Chandrachud , Bhalchandra S Pujari , Soumyajyoti Haldar , Biplab Sanyal , D G Kanhere

We study the electronic excitation spectra in solid molecular hydrogen (phase I) at ambient temperature and 5-90 GPa pressures using Quantum Monte Carlo methods and Many-Body Perturbation Theory. In this range, the system changes from a…

Materials Science · Physics 2024-05-21 Vitaly Gorelov , Markus Holzmann , David M. Ceperley , Carlo Pierleoni