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We present the results of first-principles calculations on two possible terminations of the (001) surfaces of SrTiO3 (STO), BaTiO3 (BTO), and PbTiO3 (PTO) perovskite crystals. Atomic structure and the electronic configurations were…

Materials Science · Physics 2009-09-29 S. Piskunov , E. A. Kotomin , E. Heifets

We have recently analyzed theoretically the main characteristics of the edge depolarizing electric field (EDEF), in the vicinity of a non-polar face of a pyroelectric. In this work we measured and characterized the EDEF, excited by a…

Other Condensed Matter · Physics 2015-05-14 A. V. Butenko , V. Sandomirsky , G. Chaniel , B. Shapiro , Y. Schlesinger , A. Jarov , V. A. Sablikov

The local structural distortions in polydomain ferroelectric PbTiO3/SrTiO3 superlattices are investigated by means of high spatial and energy resolution electron energy loss spectroscopy combined with high angle annular dark field imaging.…

The ground-state polarization of PbTiO3 thin films is studied using a microscopic effective Hamiltonian with parameters obtained from first-principles calculations. Under short-circuit electrical boundary conditions, (001) films with…

Materials Science · Physics 2009-10-31 Ph. Ghosez , K. M. Rabe

PbZr0.52Ti0.48O3/La0.67Sr0.33MnO3(PZT/LSMO) bilayer with surface roughness ~ 1.8 nm thin films have been grown by pulsed laser deposition on LaAlO3(LAO) substrates. High remnant polarization (30-54 micro C/cm2), dielectric…

Materials Science · Physics 2015-05-18 Sandra Dussan , Ashok Kumar , J. F. Scott , Ram S. Katiyar

The (001) surfaces of polar perovskites BaTiO$_3$ and PbTiO$_3$ have been studied from first principles at T=0 K. For both cases of polarization, the most stable TiO-terminated interfaces show intrinsic ferroelectricity. In the topmost…

Materials Science · Physics 2008-03-12 M. Fechner , S. Ostanin , I. Mertig

The surface structure of the SrTiO$_3$(110) polar surface is studied by scanning tunneling microscopy and X-ray photoelectron spectroscopy. Monophased reconstructions in (5$\times$1), (4$\times$1), (2$\times$8), and (6$\times$8) are…

Materials Science · Physics 2015-05-20 Zhiming Wang , Fang Yang , Zhiqiang Zhang , Yuanyuan Tang , Jiagui Feng , Kehui Wu , Qinlin Guo , Jiandong Guo

The symmetric studies on the structure-property relationship of the unpoled and poled states of 0.67BiFeO3-0.33BaTiO3 (0.67BF-0.33BT) were conducted to understand the origin of the morphotropic phase boundary (MPB) in BF-BT. A typical…

Materials Science · Physics 2020-03-24 Yongxing Wei , Jiahao Shen , Chenxing Bai , Changqing Jin , Weitong Zhu , Ye Tian , Gang Xu

The topographic and electronic structure of cleaved SrTiO3(001) surfaces were studied, employing samples that either had or had not been coated with Ti on their outer surfaces prior to fracture. In both cases, SrO- and TiO2-terminated…

Materials Science · Physics 2015-09-16 Wattaka Sitaputra , Marek Skowronski , Randall M. Feenstra

The electronic structure of SrBi2Ta2O9 is investigated from first-principles, within the local density approximation, using the full-potential linearized augmented plane wave (LAPW) method. The results show that, besides the large…

Materials Science · Physics 2009-10-31 M. G. Stachiotti , C. O. Rodriguez , C. Ambrosch-Draxl , N. E. Christensen

Results from dielectric and structural measurements on epitaxial SrTiO$_3$/BaZrO$_3$ superlattices reveal properties that cannot be explained simply in terms of those measured on single films of the constituent materials. For large…

Materials Science · Physics 2009-11-10 Hans M. Christen , Eliot D. Specht , Sherwood S. Silliman , K. S. Harshavardhan

A detailed defect energy level map was investigated for heterostructures of 26 unit cells of LaAlO3 on SrTiO3 prepared at a low oxygen partial pressure of 10-6 mbar. The origin is attributed to the presence of dominating oxygen defects in…

Strongly Correlated Electrons · Physics 2014-11-04 X. Renshaw Wang , J. Q. Chen , A. Roy Barman , S. Dhar , Q. -H. Xu , T. Venkatesan , Ariando

Above-bandgap femtosecond optical excitation of a ferroelectric/dielectric BaTiO3/CaTiO3 superlattice leads to structural responses that are a consequence of the screening of the strong electrostatic coupling between the component layers.…

Structural studies on ultrathin SrRuO3/BaTiO3/SrRuO3 capacitors, with BaTiO3 thicknesses of between 5 nm and 30 nm, show well-defined interfaces between ferroelectric BaTiO3 and electrode SrRuO3 layers. In these capacitors, we cannot…

A fundamental understanding of the interplay between lattice structure, polarization and electrons is pivotal to the optical control of ferroelectrics. The interaction between light and matter enables the remote and wireless control of the…

The structural and electronic properties of $A$TiO$_3$ ($A$=Ca, Sr, Ba) have been investigated under strain-free situation and with realistic constraints using first-principles calculations. We endeavored to find out the interplay between…

Materials Science · Physics 2020-09-08 Patrick Ning'i , Stephen Chege , James Sifuna , George Amolo

The electronic and geometric properties of bulk fcc delta-plutonium and the quantum size effects in the surface energies and the work functions of the (001) ultra thin films (UTF) up to 7 layers have been investigated with periodic density…

Strongly Correlated Electrons · Physics 2009-11-10 Xueyuan Wu , Asok K. Ray

Rearrangement of atoms due to broken translational symmetries at the surface of SrTiO$_3$ is scarcely debatable in the present day scenario. Actual concern demands to unveil the true structure and precise mechanism responsible for atomic…

Materials Science · Physics 2018-11-08 Adeel Y Abid , Ning Li , Ayaz Arif , Peng Gao

The temperature dependence of the electrical resistivity of the heterostructures consisting of single crystalline LaMnO$_3$ samples with different crystallographic orientations covered by the epitaxial ferroelectric…

Strongly Correlated Electrons · Physics 2017-10-20 D. P. Pavlov , I. I. Piyanzina , V. M. Mukhortov , A. M. Balbashov , D. A. Tayurskii , I. A. Garifullin , R. F. Mamin

Using the method of anharmonic lattice statics, we calculate the equilibrium structure of steps on 180^o ferroelectric domain walls (DW) in PbTiO_3. We consider three different types of steps: i) Ti-Ti step that joins a Ti-centered DW to a…

Materials Science · Physics 2015-05-20 Arzhang Angoshtari , Arash Yavari