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We present a computationally efficient approach to perform systematically convergent real-space all-electron Kohn-Sham DFT calculations for solids using an enriched finite element (FE) basis. The enriched FE basis is constructed by…

Computational Physics · Physics 2021-08-18 Nelson D. Rufus , Bikash Kanungo , Vikram Gavini

Motivated by applications to numerical simulation of flows in highly heterogeneous porous media, we develop multiscale finite element methods for second order elliptic equations. We discuss a multiscale model reduction technique in the…

Numerical Analysis · Mathematics 2015-06-15 Y. Efendiev , J. Galvis , R. Lazarov , M. Moon , M. Sarkis

The ground state energy of a many-electron system can be approximated by an variational approach in which the total energy of the system is minimized with respect to one and two-body reduced density matrices (RDM) instead of many-electron…

Optimization and Control · Mathematics 2017-09-01 Yongfeng Li , Zaiwen Wen , Chao Yang , Yaxiang Yuan

Using the recently developed version of the GW method employing the one-site approximation and self-consistent quasiparticle basis set we calculated the electronic structure of 3d and 4d transition metals at experimental atomic volumes. The…

Strongly Correlated Electrons · Physics 2007-08-16 K. D. Belashchenko , V. P. Antropov , N. E. Zein

We introduce a functional of the local spectral electron density which can be used to to compute the total energy and the local spectral function of strongly-correlated materials. We illustrate the applicability of the method by using as an…

Strongly Correlated Electrons · Physics 2007-05-23 S. Y. Savrasov , G. Kotliar

The LDA+DMFT method is a very powerful tool for gaining insight into the physics of strongly correlated materials. It combines traditional ab-initio density-functional techniques with the dynamical mean-field theory. The core aspects of the…

Strongly Correlated Electrons · Physics 2017-11-22 Eva Pavarini

The Scaled Boundary Finite Element Method is a novel semi-analytical method jointly developed by Chongmin Song and John P Wolf to solve problems in elastodynamics and allied problems in civil engineering. This novel method has been recently…

Computational Physics · Physics 2007-05-23 V. S. Prasanna Rajan

Several methodologies are developed for large-scale atomistic simulations with fully quantum mechanical description of electron systems. The important methodological concepts are (i) generalized Wannier state, (ii) Krylov subspace and (iii)…

Materials Science · Physics 2007-05-23 Takeo Hoshi

A numerical scheme is presented for approximating fractional order Poisson problems in two and three dimensions. The scheme is based on reformulating the original problem posed over $\Omega$ on the extruded domain…

Numerical Analysis · Mathematics 2019-05-27 Mark Ainsworth , Christian Glusa

We develop a cut finite element method for a second order elliptic coupled bulk-surface model problem. We prove a priori estimates for the energy and $L^2$ norms of the error. Using stabilization terms we show that the resulting algebraic…

Numerical Analysis · Mathematics 2014-03-27 Erik Burman , Peter Hansbo , Mats G. Larson , Sara Zahedi

In this paper, we study an adaptive finite element method for a class of a nonlinear eigenvalue problems that may be of nonconvex energy functional and consider its applications to quantum chemistry. We prove the convergence of adaptive…

Numerical Analysis · Mathematics 2010-01-15 H. Chen , X. Gong , L. He , A. Zhou

We describe an efficient quantum embedding framework for realistic ab initio density matrix embedding (DMET) calculations in solids. We discuss in detail the choice of orbitals and mapping to a lattice, treatment of the virtual space and…

Strongly Correlated Electrons · Physics 2020-01-15 Zhi-Hao Cui , Tianyu Zhu , Garnet Kin-Lic Chan

The study of electronic transitions within a molecule connected to the absorption or emission of light is a common task in the process of the design of new materials. The transitions are complex quantum mechanical processes and a detailed…

Human-Computer Interaction · Computer Science 2021-06-03 Talha Bin Masood , Signe Sidwall Thygesen , Mathieu Linares , Alexei I. Abrikosov , Vijay Natarajan , Ingrid Hotz

We describe recent progress in developing practical ab initio methods for which the computer effort is proportional to the number of atoms: linear scaling or O(N) methods. It is shown that the locality property of the density matrix gives a…

Condensed Matter · Physics 2007-05-23 D. R. Bowler , I. J. Bush , M. J. Gillan

The computation of electronic structure properties at the quantum level is a crucial aspect of modern physics research. However, conventional methods can be computationally demanding for larger, more complex systems. To address this issue,…

Quantum Physics · Physics 2023-12-05 Nouhaila Innan , Muhammad Al-Zafar Khan , Mohamed Bennai

Finite Element discretizations of coupled multi-physics partial differential equation models require the handling of composed function spaces. In this paper we discuss software concepts and abstractions to handle the composition of function…

Mathematical Software · Computer Science 2025-08-15 Christian Engwer , Carsten Gräser , Steffen Müthing , Simon Praetorius , Oliver Sander

An approximate relativistic two-component Hamiltonian for use in molecular electronic structure calculations is derived in the form of a sum of fixed atom-centered kinetic and spin-orbit operators added to the non-relativistic Hamiltonian.…

Chemical Physics · Physics 2019-02-13 Dimitri N. Laikov

A novel method for performing model updating on finite element models is presented. The approach is particularly tailored to modal analyses of buildings, by which the lowest frequencies, obtained by using sensors and system identification…

Numerical Analysis · Mathematics 2018-07-18 Maria Girardi , Cristina Padovani , Daniele Pellegrini , Margherita Porcelli , Leonardo Robol

We present an implementation in a linear-scaling density-functional theory code of an electronic enthalpy method, which has been found to be natural and efficient for the ab initio calculation of finite systems under hydrostatic pressure.…

Mesoscale and Nanoscale Physics · Physics 2015-06-16 Niccolò R. C. Corsini , Andrea Greco , Nicholas D. M. Hine , Carla Molteni , Peter D. Haynes

In the last decade, computational studies of liquid water have mostly concentrated on ground state properties. However recent spectroscopic measurements have been used to infer the structure of water, and the interpretation of optical and…

Materials Science · Physics 2016-08-31 David Prendergast , Jeffrey C. Grossman , Giulia Galli