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We develop a theory for the analytic computation of the free energy of band insulators in the presence of a uniform and constant electric field. The two key ingredients are a perturbation-like expression of the Wannier-Stark energy spectrum…

Strongly Correlated Electrons · Physics 2017-02-01 Frédéric Combes , Maximilian Trescher , Frédéric Piéchon , Jean-Noël Fuchs

Leveraging data collected from smart meters in buildings can aid in developing policies towards energy conservation. Significant energy savings could be realised if deviations in the building operating conditions are detected early, and…

Machine Learning · Computer Science 2023-03-29 Durga Prasad Pydi , S. Advaith

Modern statistical analysis often encounters high-dimensional problems but with a limited sample size. It poses great challenges to traditional statistical estimation methods. In this work, we adopt auxiliary learning to solve the…

Statistics Theory · Mathematics 2025-01-08 Hanchao Yan , Feifei Wang , Chuanxin Xia , Hansheng Wang

We present a new rigorous method for estimating statistical quantities in fluid dynamics such as the (average) energy dissipation rate directly from the equations of motion. The method is tested on shear flow, channel flow,…

Fluid Dynamics · Physics 2023-07-19 Christian Seis

Subsampling algorithms for various parametric regression models with massive data have been extensively investigated in recent years. However, all existing studies on subsampling heavily rely on clean massive data. In practical…

Statistics Theory · Mathematics 2025-06-11 Jiangshan Ju , Mingqiu Wang , Shengli Zhao

Calculating thermodynamic potentials and observables efficiently and accurately is key for the application of statistical mechanics simulations to materials science. However, naive Monte Carlo approaches, on which such calculations are…

Statistical Mechanics · Physics 2021-07-15 James Damewood , Daniel Schwalbe-Koda , Rafael Gomez-Bombarelli

A key science goal of upcoming dark energy surveys is to seek time evolution of the dark energy. This problem is one of {\em model selection}, where the aim is to differentiate between cosmological models with different numbers of…

The free energetics of water density fluctuations in bulk water, at interfaces, and in hydrophobic confinement inform the hydration of hydrophobic solutes as well as their interactions and assembly. The characterization of such free…

Statistical Mechanics · Physics 2018-03-15 Erte Xi , Sean M. Marks , Suruchi Fialoke , Amish J. Patel

From the onset of fundamental statistical mechanical constructs formulated in the late 19th century, alchemical free-energy methods slowly emerged and transitioned to become operational tools of biomolecular simulation applicable to a wide…

Computational Physics · Physics 2025-10-31 Daniele Macuglia , Giovanni Ciccotti , Benoît Roux

The recent development of compressed sensing has led to spectacular advances in the understanding of sparse linear estimation problems as well as in algorithms to solve them. It has also triggered a new wave of developments in the related…

Information Theory · Computer Science 2016-07-05 Christophe Schülke

Approximate Bayesian computation (ABC) has become an essential part of the Bayesian toolbox for addressing problems in which the likelihood is prohibitively expensive or entirely unknown, making it intractable. ABC defines a…

Methodology · Statistics 2020-07-14 Hien D. Nguyen , Julyan Arbel , Hongliang Lü , Florence Forbes

Real-time measurements on the occupancy status of indoor and outdoor spaces can be exploited in many scenarios (HVAC and lighting system control, building energy optimization, allocation and reservation of spaces, etc.). Traditional systems…

Networking and Internet Architecture · Computer Science 2019-05-17 Paolo Galluzzi , Edoardo Longo , Alessandro E. C. Redondi , Matteo Cesana

Estimating the free energy in molecular simulation requires, implicitly or explicitly, counting how many times the system is observed in a finite region. If the simulation is biased by an external potential, the weight of the configurations…

Chemical Physics · Physics 2021-12-22 Matteo Carli , Alessandro Laio

Molecular dynamics (MD) simulations are useful in obtaining thermodynamic and kinetic properties of bio-molecules but are limited by the timescale barrier, i.e., we may be unable to efficiently obtain properties because we need to run…

Chemical Physics · Physics 2017-08-23 Surl-Hee Ahn , Jay W. Grate , Eric F. Darve

The theoretical analysis of many problems in physics, astronomy and applied mathematics requires an efficient numerical exploration of multimodal parameter spaces that exhibit broken ergodicity. Monte Carlo methods are widely used to deal…

Statistical Mechanics · Physics 2014-09-02 Stefano Martiniani , Jacob D. Stevenson , David J. Wales , Daan Frenkel

Entropy and free-energy estimation are key in thermodynamic characterization of simulated systems ranging from spin models through polymers, colloids, protein structure, and drug-design. Current techniques suffer from being model specific,…

Statistical Mechanics · Physics 2019-10-30 Ram Avinery , Micha Kornreich , Roy Beck

We present predictions for the statistical error due to finite sampling in the presence of thermal fluctuations in molecular simulation algorithms. Specifically, we establish how these errors depend on Mach number, Knudsen number, number of…

Statistical Mechanics · Physics 2009-11-07 Nicolas Hadjiconstantinou , Alejandro L. Garcia , Martin Z. Bazant , Gang He

We study the problem of optimal sampling in an edge-based video analytics system (VAS), where sensor samples collected at a terminal device are offloaded to a back-end server that processes them and generates feedback for a user. Sampling…

Information Theory · Computer Science 2023-02-22 Vishnu Narayanan Moothedath

The present paper proposes an adaptive biasing potential for the computation of free energy landscapes. It is motivated by statistical learning arguments and unifies the tasks of biasing the molecular dynamics to escape free energy wells…

Mathematical Physics · Physics 2018-03-05 I. Bilionis , P. S. Koutsourelakis

Energy-Based Models (EBMs) offer a versatile framework for modeling complex data distributions. However, training and sampling from EBMs continue to pose significant challenges. The widely-used Denoising Score Matching (DSM) method for…

Machine Learning · Statistics 2024-03-20 Mingtian Zhang , Alex Hawkins-Hooker , Brooks Paige , David Barber