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We present a new outlook on the climate system thermodynamics, studying some of its macroscopic properties in terms of the 1st and 2nd laws of thermodynamics. We review and clarify the notion of efficiency of the climate system by…

Atmospheric and Oceanic Physics · Physics 2011-10-11 Valerio Lucarini

Deriving the laws of thermodynamics from a microscopic picture is a central quest of statistical mechanics. This tutorial focuses on the derivation of the first and second law for closed and open quantum systems far from equilibrium, where…

Quantum Physics · Physics 2021-08-31 Philipp Strasberg , Andreas Winter

The proper definition of entropy is fundamental to the relationship between statistical mechanics and thermodynamics. It also plays a major role in the recent debate about the validity of the concept of negative temperature. In this paper,…

Statistical Mechanics · Physics 2015-11-18 Robert H. Swendsen

Every production-recycling iteration accumulates an inevitable proportion of its matter-energy in the environment, lest the production process itself would be a system in perpetual motion, violating the second law of Thermodynamics. Such…

Physics and Society · Physics 2013-11-06 Henrique N. Sá Earp , Ademar R. Romeiro

We formulate, under general conditions, the problem of maximisation of the total entropy of the system, assumed to be in a composable form, for fixed total value of the constrained quantity. We derive the general form of the composability…

Statistical Mechanics · Physics 2009-11-10 Ramandeep S. Johal

From a new rigorous formulation of the general axiomatic foundations of thermodynamics we derive an operational definition of entropy that responds to the emergent need in many technological frameworks to understand and deploy thermodynamic…

Mathematical Physics · Physics 2014-11-21 Gian Paolo Beretta , Enzo Zanchini

Recent literature in the last Maximum Entropy workshop introduced an analogy between cumulative probability distributions and normalized utility functions. Based on this analogy, a utility density function can de defined as the derivative…

Artificial Intelligence · Computer Science 2009-11-10 Ali E. Abbas

A major part of the many thermally driven processes in our natural environment as well as in engineering solutions of Carnot-type machinery is based on the second law of thermodynamics (or principle of entropy increase). An interesting link…

General Physics · Physics 2010-09-29 Hans R. Moser

The maximum entropy principle can be used to assign utility values when only partial information is available about the decision maker's preferences. In order to obtain such utility values it is necessary to establish an analogy between…

Statistical Finance · Quantitative Finance 2009-11-13 Andreia Dionisio , A. Heitor Reis

The second law of classical thermodynamics, based on the positivity of the entropy production, only holds for deterministic processes. Therefore the Second Law in stochastic quantum thermodynamics may not hold. By making a fundamental…

Quantum Physics · Physics 2019-11-14 B. Ahmadi , S. Salimi , A. S. Khorashad

Free energy and entropy are examined in detail from the standpoint of classical thermodynamics. The approach is logically based on the fact that thermodynamic work is mediated by thermal energy through the tendency for nonthermal energy to…

Physics Education · Physics 2015-06-26 Clinton D. Stoner

Thermodynamic entropy is determined by a heat measurement through the Clausius equality. The entropy then formalizes a fundamental limitation of operations by the second law of thermodynamics. The entropy is also expressed as the Shannon…

Statistical Mechanics · Physics 2015-06-17 Shin-ichi Sasa

We revisit the conjecture of a generalized second law of thermodynamics which states that the combined entropy of matter and horizons must grow. In an expanding universe a generalized second law restricts the equation of state. In…

Astrophysics · Physics 2007-05-23 Wilfried Buchmuller , Joerg Jaeckel

We argue that the entanglement entropy for a very small subsystem obeys a property which is analogous to the first law of thermodynamics when we excite the system. In relativistic setups, its effective temperature is proportional to the…

High Energy Physics - Theory · Physics 2013-03-14 Jyotirmoy Bhattacharya , Masahiro Nozaki , Tadashi Takayanagi , Tomonori Ugajin

In the scientific and engineering literature, the second law of thermodynamics is expressed in terms of the behavior of entropy in reversible and irreversible processes. According to the prevailing statistical mechanics interpretation the…

Quantum Physics · Physics 2007-05-23 Elias P. Gyftopoulos , Gian Paolo Beretta

The second law of thermodynamics is discussed and reformulated from a quantum information theoretic perspective for open quantum systems using relative entropy. Specifically, the relative entropy of a quantum state with respect to…

Quantum Physics · Physics 2020-11-11 Neil Dowling , Stefan Floerchinger , Tobias Haas

A classical and quantum mechanical generalized second law of thermodynamics in cosmology implies constraints on the effective equation of state of the universe in the form of energy conditions, obeyed by many known cosmological solutions,…

General Relativity and Quantum Cosmology · Physics 2009-10-31 Ram Brustein

Thermodynamics is commonly presented as a theory of macroscopic systems in stable equilibrium, built upon assumptions of extensivity and scaling with system size. In this paper, we present a universal formulation of the elementary…

Quantum Physics · Physics 2026-03-26 Gian Paolo Beretta

We investigate the validity of the generalized second law of thermodynamics, in the cosmological scenario where dark energy interacts with both dark matter and radiation. Calculating separately the entropy variation for each fluid component…

High Energy Physics - Theory · Physics 2010-07-20 Mubasher Jamil , Emmanuel N. Saridakis , M. R. Setare

Recently, there has been a considerable progress on the issue of the thermodynamic second law, which is known as the law of entropy increase or irreversibility. In particular, a novel symmetry known as the Gallavotti-Cohen symmetry is found…

Statistical Mechanics · Physics 2018-08-01 Hyunggyu Park