Related papers: On the Helmholtz Potential metric: The Isotherm Le…
The main goal of this paper is to reach an explicit formulation and possible interpretation of thermodynamic length in a thermodynamic state space with two degrees of freedom. Using the energy and entropy metric in a general form, we get…
The purpose of this paper is to study thermodynamic length of an isochoric two dimensional thermodynamic system with constant heat capacity. We find that length is related to the heat flow into the substance. We give examples of Ideal gas…
For 1D Hamiltonian systems with periodic solutions, Helmholtz formalism provides a tantalizing interpretation of classical thermodynamics, based on time integrals of purely mechanical quantities and without need of statistical description.…
We present the full thermodynamics of a fluid confined by an arbitrary external potential based on the virial expansion of the grand potential. The fluid may be classical or quantum and it is assumed that interatomic interactions are…
In this paper we derive an equation of state for liquid cesium based on a suggested potential function in accord to the characteristics large attraction and soft repulsion at the asymptotes of interaction potentials. By considering the…
We present the fundamentals of geometrothermodynamics, an approach to study the properties of thermodynamic systems in terms of differential geometric concepts. It is based, on the one hand, upon the well-known contact structure of the…
Thermodynamic length is a metric distance between equilibrium thermodynamic states that asymptotically bounds the dissipation induced by a finite time transformation of a thermodynamic system. By means of thermodynamic length, we first…
In this paper we study thermodynamic length of an isentropic Ideal and quasi-Ideal Gas using Weinhold metric in a two-dimensional state space. We give explicit relation between length at constant entropy and work.
The excess work performed in a heat-engine process with given finite operation time \tau is bounded by the thermodynamic length, which measures the distance during the relaxation along a path in the space of the thermodynamic state.…
Thermodynamic length is a path function that generalizes the notion of length to the surface of thermodynamic states. Here, we show how to measure thermodynamic length in far-from-equilibrium single molecule experiments using the work…
Through experimental investigation into the behaviour of a polar dielectric working fluid, an ideal quasi-thermodynamic cycle has been established. Particular stages of this cycle are described in terms of a condensed-matter analogue of the…
For an understanding of a heat engine working in the microscopic scale, it is often necessary to estimate the amount of reversible work extracted by isothermal expansion of the quantum gas used as its working substance. We consider an…
We generalize the second law of thermodynamics in its maximum work formulation for a nonequilibrium initial distribution. It is found that in an isothermal process, the Boltzmann relative entropy (H-function) is not just a Lyapunov function…
We show that for any liquid or solid with strong correlation between its $NVT$ virial and potential-energy equilibrium fluctuations, the temperature is a product of a function of excess entropy per particle and a function of density,…
Thermodynamic length is a metric distance between equilibrium thermodynamic states. Among other interesting properties, this metric asymptotically bounds the dissipation induced by a finite time transformation of a thermodynamic system. It…
We propose a new way to relate the black hole thermodynamics and geometry by generalizing the Euclidean formalism to include "virtual geometries", which do not necessarily satisfy Einstein equations. This provides a physically well…
Ewald summation and physically equivalent methods such as particle-mesh Ewald, kubic-harmonic expansions, or Lekner sums are commonly used to calculate long-range electrostatic interactions in computer simulations of polar and charged…
The potential concept that is successful in classical electrodynamics should also be applicable to the nonlinear electromagnetic forces acting on matter. The obvious method of determining these potentials should be provided by Helmholtz's…
This paper investigates the asymptotic behavior of the Helmholtz free energy of mixtures at small compressibility. We start from a general representation for the local free energy that is valid in stable subregions of the phase diagram. On…
We study the flexibility of the pressure function of a continuous potential (observable) with respect to a parameter regarded as the inverse temperature. The points of non-differentiability of this function are of particular interest in…