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We study the time evolution of a system of $N$ spinless fermions in $\mathbb{R}^3$ which interact through a pair potential, e.g., the Coulomb potential. We compare the dynamics given by the solution to Schr{\"o}dinger's equation with the…

Mathematical Physics · Physics 2019-10-08 Volker Bach , Sébastien Breteaux , Sören Petrat , Peter Pickl , Tim Tzaneteas

In this paper we motivate, formulate and analyze the Multi-Configuration Time-Dependent Hartree-Fock (MCTDHF) equations for molecular systems under Coulomb interaction. They consist in approximating the N-particle Schrodinger wavefunction…

Mathematical Physics · Physics 2015-05-13 C. Bardos , I. Catto , N. Mauser , S. Trabelsi

We study the quantum dynamics of a large number of interacting fermionic particles in a constant magnetic field. In a coupled mean-field and semiclassical scaling limit, we show that solutions of the many-body Schr\"odinger equation…

Mathematical Physics · Physics 2025-03-24 Niels Benedikter , Chiara Boccato , Domenico Monaco , Ngoc Nhi Nguyen

We introduce a new method for deriving the time-dependent Hartree or Hartree-Fock equations as an effective mean-field dynamics from the microscopic Schroedinger equation for fermionic many-particle systems in quantum mechanics. The method…

Mathematical Physics · Physics 2016-11-29 Sören Petrat , Peter Pickl

In this work, we derive the time-dependent Hartree(-Fock) equations as an effective dynamics for fermionic many-particle systems. Our main results are the first for a quantum mechanical mean-field dynamics for fermions; in previous works,…

Mathematical Physics · Physics 2014-05-23 Sören Petrat

Certain aspects of some unitary quantum systems are well-described by evolution via a non-Hermitian effective Hamiltonian, as in the Wigner-Weisskopf theory for spontaneous decay. Conversely, any non-Hermitian Hamiltonian evolution can be…

High Energy Physics - Lattice · Physics 2021-12-01 Jay Hubisz , Bharath Sambasivam , Judah Unmuth-Yockey

In many approximate approaches to fermionic quantum many-body systems, such as Hartree-Fock and density functional theory, solving a system of non-interacting fermions coupled to some effective potential is the computational bottleneck. In…

Strongly Correlated Electrons · Physics 2021-12-21 Alex Meiburg , Bela Bauer

The solutions of the Wigner-transformed time-dependent Hartree--Fock--Bogoliubov equations are studied in the constant-$\Delta$ approximation. This approximation is known to violate particle-number conservation. As a consequence, the…

Nuclear Theory · Physics 2008-11-26 V. I. Abrosimov , D. M. Brink , A. Dellafiore , F. Matera

The time-dependent Hartree-Fock equations are derived from the N-particle Schr\"odinger equation with mean-field scaling in the infinite particle limit, for initial data that are like Slater determinants. Only the case of bounded…

Mathematical Physics · Physics 2015-02-25 Claude Bardos , Francois Golse , Alex D. Gottlieb , Norbert J. Mauser

We study the dynamics of a Fermi gas with a Coulomb interaction potential, and show that, in a mean-field limiting regime, the dynamics is described by the Hartree-Fock equation. This extends previous work of Bardos et al. to the case of…

Mathematical Physics · Physics 2011-08-30 Juerg Froehlich , Antti Knowles

The time-dependent Hartree and Hartree-Fock equations provide effective mean-field descriptions for the dynamics of large fermionic systems and play a fundamental role in many areas of physics. In this work, we rigorously derive the…

Mathematical Physics · Physics 2025-07-17 Duc Viet Hoang , David Mitrouskas , Peter Pickl

We present numerical methods to solve the Generalized Hartree-Fock theory for fermionic systems in lattices, both in thermal equilibrium and out of equilibrium. Specifically, we show how to determine the covariance matrix corresponding to…

Quantum Physics · Physics 2013-04-10 Christina V. Kraus , J. Ignacio Cirac

Hamiltonian and Schrodinger evolution equations on finite-dimensional projective space are analyzed in detail. Hartree-Fock (HF) manifold is introduced as a submanifold of many electron projective space of states. Evolution equations, exact…

Chemical Physics · Physics 2011-11-10 A. I. Panin

We prove existence and uniqueness results for the time-dependent Hartree approximation arising in quantum dynamics. The Hartree equations of motion form a coupled system of nonlinear Schr{\"o}dinger equations for the evolution of product…

Analysis of PDEs · Mathematics 2023-05-24 Rémi Carles , Clotilde Fermanian Kammerer , Caroline Lasser

We give general conditions for the existence of a Hamiltonian operator whose discrete time evolution matches the partition function of certain solvable lattice models. In particular, we examine two classes of lattice models: the classical…

Representation Theory · Mathematics 2024-05-30 Andrew Hardt

We consider a class of evolution equations in Lindblad form, which model the dynamics of dissipative quantum mechanical systems with mean-field interaction. Particularly, this class includes the so-called Quantum Fokker-Planck-Poisson…

Mathematical Physics · Physics 2009-11-10 Anton Arnold , Christof Sparber

We present a density matrix approach for computing global solutions of Hartree-Fock theory, based on semidefinite programming (SDP), that gives upper and lower bounds on the Hartree-Fock energy of quantum systems. Equality of the upper- and…

Chemical Physics · Physics 2014-02-11 Srikant Veeraraghavan , David A. Mazziotti

We revisit the derivation of the time-dependent Hartree-Fock equation for interacting fermions in a regime coupling a mean-field and a semiclassical scaling, contributing two comments to the result obtained in 2014 by Benedikter, Porta, and…

Mathematical Physics · Physics 2022-07-19 Niels Benedikter , Davide Desio

We consider a two-dimensional gas of interacting fermions in presence of an external constant magnetic field: the system is extended and homogeneous, and thus assumed to be invariant under magnetic translations. Working within the…

Mathematical Physics · Physics 2026-02-18 Horia D. Cornean , Emanuela Laura Giacomelli , Domenico Monaco , Mikkel Hviid Thorn

We present a density matrix approach for computing global solutions of restricted open-shell Hartree-Fock theory, based on semidefinite programming (SDP), that gives upper and lower bounds on the Hartree-Fock energy of quantum systems.…

Chemical Physics · Physics 2014-04-22 Srikant Veeraraghavan , David A. Mazziotti
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