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The most important recent results in the theory of phase transitions and quantum effects in quantum anharmonic crystals are presented and discussed. In particular, necessary and sufficient conditions for a phase transition to occur at some…

Statistical Mechanics · Physics 2015-06-04 Sergio Albeverio , Yuri Kozitsky , Yuri Kondratiev , Michael Roeckner

We establish an analytical criterion for dynamical thermalization within harmonic systems, applicable to both classical and quantum models. Specifically, we prove that thermalization of various observables, such as particle energies in…

Statistical Mechanics · Physics 2025-07-29 Marco Cattaneo , Marco Baldovin , Dario Lucente , Paolo Muratore-Ginanneschi , Angelo Vulpiani

The laws of thermodynamics provide a clear concept of the temperature for an equilibrium system in the continuum limit. Meanwhile, the equipartition theorem allows one to make a connection between the ensemble average of the kinetic energy…

Statistical Mechanics · Physics 2009-11-13 Alex V. Popov , Rigoberto Hernandez

Heat, work and entropy production: the statistical distribution of such quantities are constrained by the fluctuation theorems (FT), which reveal crucial properties about the nature of non-equilibrium dynamics. In this paper we report…

Quantum Physics · Physics 2021-10-15 K. Khan , J. Sales Araújo , W. F. Magalhães , G. H. Aguilar , B. de Lima Bernardo

The generalized uncertainty connection between the fluctuations of a quantum observable and its temporal derivative is derived in this study, we demonstrate that the product of an observable's uncertainties and its time derivative is…

Quantum Physics · Physics 2025-08-26 Tarek Yehia

Time-asymmetric behavior as embodied in the second law of thermodynamics is observed in {\it individual macroscopic} systems. It can be understood as arising naturally from time-symmetric microscopic laws when account is taken of a) the…

Statistical Mechanics · Physics 2007-09-06 Joel L. Lebowitz

Various dualities are summarized. Based on the universal wave-particle duality, along an opposite direction of the developed quantum mechanics, we use a method where the wave quantities frequency and wave length are replaced on various…

General Physics · Physics 2010-08-18 Yi-Fang Chang

Quantum non-local correlations and the acausal, spooky action at a distance suggest a discord between quantum theory and special relativity. We propose a resolution for this discord by first observing that there is a problem of time in…

General Relativity and Quantum Cosmology · Physics 2016-11-15 Shreya Banerjee , Sayantani Bera , T. P. Singh

Understanding thermodynamics and statistical mechanics in the full general relativistic context is an open problem. I give tentative definitions of equilibrium state, mean values, mean geometry, entropy and temperature, which reduce to the…

General Relativity and Quantum Cosmology · Physics 2013-05-01 Carlo Rovelli

Temperature uncertainty of a quantum system in canonical ensemble is inversely determined by its energy fluctuation, which is known as the temperature-energy uncertainty relation. No such uncertainty relation was discovered for a…

Quantum Physics · Physics 2022-05-03 Ning Zhang , Si-Yuan Bai , Chong Chen

The essential postulates of classical thermodynamics are formulated, from which the second law is deduced as the principle of increase of entropy in irreversible adiabatic processes that take one equilibrium state to another. The entropy…

Soft Condensed Matter · Physics 2009-10-30 Elliott H. Lieb , Jakob Yngvason

A general quantum theory encompassing Mechanics, Thermodynamics and irreversible dynamics is presented in two parts. The first part is concerned exclusively with the description of the states of any individual physical system. It is based…

Quantum Physics · Physics 2007-05-23 Gian Paolo Beretta

Fluctuation theorems are fundamental extensions of the second law of thermodynamics for small systems. Their general validity arbitrarily far from equilibrium makes them invaluable in nonequilibrium physics. So far, experimental studies of…

The uncertainty principle guarantees a non-zero value for the positional uncertainty, $\left\langle \Delta x^2\right\rangle > 0$, even without thermal fluctuations. This implies that quantum fluctuations inherently enhance positional…

Statistical Mechanics · Physics 2025-09-08 Harukuni Ikeda

We discuss how the thermalization of an elementary quantum system is modified when the system is placed in an environment out of thermal equilibrium. To this aim we provide a detailed investigation of the dynamics of an atomic system placed…

Quantum Physics · Physics 2013-01-16 Bruno Bellomo , Riccardo Messina , Didier Felbacq , Mauro Antezza

The existence of Davies-Unruh temperature in a uniformly accelerated frame shows that quantum fluctuations of the inertial vacuum state appears as thermal fluctuations in the accelerated frame. Hence thermodynamic experiments cannot…

General Relativity and Quantum Cosmology · Physics 2018-06-20 Sanved Kolekar , T. Padmanabhan

Textbook quantum mechanics treats time as a classical parameter, and not as a quantum observable with an associated Hermitian operator. For this reason, to make sense of usual time-energy uncertainty relations such as $\Delta {t}\Delta…

Quantum Physics · Physics 2021-12-08 Matteo Fadel , Lorenzo Maccone

By computing the local energy expectation values with respect to some local measurement basis we show that for any quantum system there are two fundamentally different contributions: changes in energy that do not alter the local von Neumann…

Quantum Physics · Physics 2008-08-04 Hendrik Weimer , Markus J. Henrich , Florian Rempp , Heiko Schröder , Günter Mahler

What is the major difference between large and small systems? At small length-scales the dynamics is dominated by fluctuations, whereas at large scales fluctuations are irrelevant. Therefore, any thermodynamically consistent description of…

Statistical Mechanics · Physics 2025-01-13 Akira Sone , Kanu Sinha , Sebastian Deffner

The classical and quantum dynamics of simple time-reparametrization- invariant models containing two degrees of freedom are studied in detail. Elimination of one ``clock'' variable through the Hamiltonian constraint leads to a description…

General Relativity and Quantum Cosmology · Physics 2009-10-28 Ian D. Lawrie , Richard J. Epp