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After reviewing some fundamental results derived from the introduction of the generalized Gibbs canonical ensemble, such as the called thermodynamic uncertainty relation, it is described a physical scenario where such a generalized ensemble…

Statistical Mechanics · Physics 2007-05-23 L. Velazquez

Firstly, we calculate quantitatively decrease of entropy by the known formulas in the ordering phenomena and nucleation of thermodynamics of microstructure. They show again that a necessary condition of decrease of entropy in isolated…

General Physics · Physics 2009-05-04 Yi-Fang Chang

The approach is developed for the description of isolated Fermi-systems with finite number of particles, such as complex atoms, nuclei, atomic clusters etc. It is based on statistical properties of chaotic excited states which are formed by…

Statistical Mechanics · Physics 2009-08-18 V. V. Flambaum , F. M. Izrailev

We study mathematically the equilibrium properties of the Bose-Hubbard Hamiltonian in the limit of a vanishing hopping amplitude. This system conserves the energy and the number of particles. We establish the equivalence between the…

Statistical Mechanics · Physics 2019-10-23 François Huveneers , Elias Theil

We study statistical properties of matrix elements of observables written in the energy eigenbasis and truncated to small microcanonical windows. We present numerical evidence indicating that for all few body operators in chaotic many-body…

Statistical Mechanics · Physics 2025-06-10 Jiaozi Wang , Jonas Richter , Mats H. Lamann , Robin Steinigeweg , Jochen Gemmer , Anatoly Dymarsky

A heuristic generalization of the Boltzmann-Gibbs microcanonical entropy is proposed, able to describe meta-equilibrium features and evolution of macroscopic systems. Despite its simple-minded derivation, such a function of "collective…

Statistical Mechanics · Physics 2007-05-23 Piero Cipriani

Breaking of ensemble equivalence between the microcanonical ensemble and the canonical ensemble may occur for random graphs whose size tends to infinity, and is signaled by a non-zero specific relative entropy of the two ensembles. In [3]…

Statistical Mechanics · Physics 2018-08-22 Andrea Roccaverde

For a static, perfect fluid sphere with a general equation of state, we obtain the relativistic equation of hydrostatic equilibrium, namely the Tolman-Oppenheimer-Volkov equation, as the thermodynamical equilibrium in the microcanonical, as…

General Relativity and Quantum Cosmology · Physics 2013-05-14 Zacharias Roupas

We demonstrate the equilibration of isolated macroscopic quantum systems, prepared in non-equilibrium mixed states with significant population of many energy levels, and observed by instruments with a reasonably bound working range compared…

Statistical Mechanics · Physics 2009-11-13 Peter Reimann

We consider a system weakly interacting with a bath as a thermodynamic setting to establish a quantum foundation of statistical physics. It is shown that even if the composite system is initially in an arbitrary nonequilibrium pure quantum…

Quantum Physics · Physics 2010-04-28 Jaeyoon Cho , M. S. Kim

Entropy is critically examined as a fundamental concept in contemporary science and informatics. Although the typical Shannon entropy provides a proper framework for describing the canonical ensemble, it fails to represent adequately the…

Statistical Mechanics · Physics 2026-02-23 Roumen Tsekov

The Blume-Capel model with infinite-range interactions presents analytical solutions in both canonical and microcanonical ensembles and therefore, its phase diagram is known in both ensembles. This model exhibits nonequivalent solutions and…

Statistical Mechanics · Physics 2015-05-19 Rafael B. Frigori , Leandro G. Rizzi , Nelson A. Alves

In classical systems, we reexamine how macroscopic structures in equilibrium state connect with spatial con- straint on the systems: e.g., volume and density as the constraint for liquids in rigid box, and crystal lattice as the constraint…

Disordered Systems and Neural Networks · Physics 2016-05-25 Koretaka Yuge

It is well-known that the entropy of the microcanonical ensemble cannot be calculated as the Legendre transform of the canonical free energy when the entropy is nonconcave. To circumvent this problem, a generalization of the canonical…

Statistical Mechanics · Physics 2007-05-23 Marius Costeniuc , Richard S. Ellis , Hugo Touchette

Microcanonical ensemble theory of bosons is derived from quantum mechanics by making use of a hidden gauge structure. The relative phase interaction associated with this gauge structure, described by the Pegg-Barnett formalism, is shown to…

Statistical Mechanics · Physics 2009-11-07 Sumiyoshi Abe , Tsunehiro Kobayashi

Entropy, and its temporal evolution, play a central role in the foundations of quantum theory and in modern quantum technologies. Here we study, in particular, the relations between the --- in general, non-Markovian --- evolution of an open…

Quantum Physics · Physics 2018-09-18 Paolo Aniello , Joonwoo Bae , Dariusz Chruscinski

In the past several years, observational entropy has been developed as both a (time-dependent) quantum generalization of Boltzmann entropy, and as a rather general framework to encompass classical and quantum equilibrium and non-equilibrium…

Quantum Physics · Physics 2021-10-28 Dominik Šafránek , Anthony Aguirre , Joseph Schindler , J. M. Deutsch

We derive the microcanonical ensemble from the Maximum Entropy Principle (MEP) using the phase space volume entropy of P. Hertz. Maximizing this entropy with respect to the probability distribution with the constraints of normalization and…

Statistical Mechanics · Physics 2008-02-15 Michele Campisi , Donald H. Kobe

For classical nonequilibrium systems, the separation of the total entropy production into the adiabatic and nonadiabatic contributions is useful for understanding irreversibility in nonequilibrium thermodynamics. In this article, we…

Statistical Mechanics · Physics 2015-06-16 Jordan M. Horowitz , Juan M. R. Parrondo

The microcanonical entropy s(e,m) as a function of the energy e and the magnetization m is computed analytically for the anisotropic quantum Heisenberg model with Curie-Weiss-type interactions. The result shows a number of interesting…

Statistical Mechanics · Physics 2010-07-02 Michael Kastner