Related papers: Random phase approximation and its extension for t…
Spontaneous rhythmic oscillations are widely observed in various real-world systems. In particular, biological rhythms, which typically arise via synchronization of many self-oscillatory cells, often play important functional roles in…
We study the asymptotic behavior of the spectrum of a quantum system which is a perturbation of a spherically symmetric anharmonic oscillator in dimension 2. We prove that a large part of its eigenvalues can be obtained by Bohr-Sommerfeld…
In this thesis are shown developments in the random phase approximation (RPA) in the context of range-separated theories. We present advances in the formalism of the RPA in general, and particularly in the "dielectric matrix" formulation of…
Properties of solutions of the RPA equation is reanalyzed mathematically, which is defined as a generalized eigenvalue problem of the stability matrix $\mathsf{S}$ with the norm matrix $\mathsf{N}=\mathrm{diag.}(1,-1)$. As well as physical…
In this article, we revisit the question of the validity of Hartree-Fock and random-phase approximations. We show that there is a connection between the two and while the RPA as it is known in much of the physics literature is of limited…
We have studied the precession mode, the rotational excitation built on the high-$K$ isomeric state, in comparison with the recently identified wobbling mode. The random-phase-approximation (RPA) formalism, which has been developed for the…
The quantum quartic anharmonic oscillator with the Hamiltonian $H=\frac{1}{2}\left( p^{2}+x^{2}\right) +\lambda x^{4}$ is a classical and fundamental model that plays a key role in various branches of physics, including quantum mechanics,…
The convergence of the Rayleigh-Ritz method with nonlinear parameters optimized through minimization of the trace of the truncated matrix is demonstrated by a comparison with analytically known eigenstates of various quasi-solvable systems.…
By using the Feynman-Hibbs prescription for the evolution amplitude, we quantize the system of a damped harmonic oscillator coupled to its time-reversed image, known as Bateman's dual system. The time-dependent quantum states of such a…
A new pseudoperturbative (artificial in nature) methodical proposal [15] is used to solve for Schrodinger equation with a class of phenomenologically useful and methodically challenging anharmonice oscillator potentials V(q)=\alpha_o q^2 +…
Based on a linearization approximation coupled with path integral formalism, we propose a method derived from the propagation of quasi-classical trajectories to simulate resonance Raman spectra. This method is based on a ground state…
The renormalization group method is applied for obtaining the asymptotic form of the wave function of the quantum anharmonic oscillator by resumming the perturbation series. It is shown that the resumed series is the cumulant of the naive…
Oscillators are ubiquitous in nature, and usually associated with the existence of an asymptotic phase that governs the long-term dynamics of the oscillator. % We show that asymptotic phase can be estimated using a carefully chosen series…
The ground-state correlation energy calculated in the random-phase approximation (RPA) is known to be identical to that calculated using a subset of terms appearing in coupled-cluster theory with double excitations. In particular, this…
Practical applications of fragment embedding and closely related local correlation methods critically depend on a judicious choice of a low-level theory to define the local embedding subspace and to capture long-range electrostatic and…
This Ph.D. thesis derives the equations of the Faddeev Random Phase Approximation (FRPA) and applies the method to a set of small atoms and molecules. The occurence of RPA instabilities in the dissociation limit is addressed in molecules…
For the general $D$-dimensional radial anharmonic oscillator with potential $V(r)= \frac{1}{g^2}\,\hat{V}(gr)$ the Perturbation Theory (PT) in powers of coupling constant $g$ (weak coupling regime) and in inverse, fractional powers of $g$…
We present a new method to compute resonance Raman spectra based on ab initio level calculations using the frequency-dependent Placzek approximation. We illustrate the efficiency of our hybrid quantum-classical method by calculating the…
Phase reduction is a well-established technique used to analyze the timing of oscillations in response to weak external inputs. In the preceding decades, a wide variety of results have been obtained for weakly perturbed oscillators that…
Raman spectroscopy stands as a cornerstone technique for probing collective excitations and emergent quantum phases in solids. While polarization-resolved Raman scattering has been widely used to extract symmetry information of eigenmodes,…