Related papers: Quantum Electrodynamics of the Helium Atom
We give a lower bound for the energy of a quantum particle in the infinite square well. We show that the bound is exact and identify the well-known element that fulfils the equality. Our approach is not directly dependent on the…
Calculation of higher-order two-loop corrections is now a limiting factor in development of the bound state QED theory of the Lamb shift in the hydrogen atom and in precision determination of the Rydberg constant. Progress in the study of…
We consider two models where the wave equation can be reduced to the effective Schr\"odinger equation whose potential contains both harmonic and the Coulomb terms, $\omega^{2}r^{2}-a/r$. The equation reduces to the biconfluent Heun's…
The hyperspherical harmonics (HH) provide a complete basis for the expansion of atomic wave functions, but even for two particles the number of harmonics for a given order is not trivial and, as the number of electrons increases, this…
A study is made of nuclear size corrections to the energy levels of single-electron atoms for the ground state of hydrogen like atoms. We consider Fermi charge distribution to the nucleus and calculate atomic energy level shift due to the…
We present a new hydrodynamic analogy of nonrelativistic quantum particles in potential wells. Similarities between a real variant of the Schr\"odinger equation and gravity-capillary shallow water waves are reported and analyzed. We show…
Schr\"odinger operator on half-line with complex potential and the corresponding evolution are studied within perturbation theoretic approach. The total number of eigenvalues and spectral singularities is effectively evaluated. Wave…
Exact solution of Schrodinger equation for the pseudoharmonic potential is obtained for an arbitrary angular momentum. The energy eigenvalues and corresponding eigenfunctions are calculated by Nikiforov-Uvarov method. Wavefunctions are…
We present the derivation of the effective higher-order Hamiltonian, which gives $m \alpha^6$ contribution to energy levels of an arbitrary light atom. The derivation is based on the Foldy-Wouthuysen transformation of the one-particle Dirac…
The semi-exponential basis set of radial functions (A.M. Frolov, Physics Letters A {\bf 374}, 2361 (2010)) is used for variational computations of bound states in three-electron atomic systems. It appears that semi-exponential basis set has…
We report a detailed study of high-order harmonic generation (HHG) in helium. When comparing predictions from a single-active-electron model with those from all-electron simulations, such as ATTOMESA and R-matrix with time-dependence, which…
In this work we propose a novel composite method for accurate calculation of the energies of many-electron atoms. The dominant contribution to the energy (pair energies) are calculated by using explicitly correlated factorisable coupled…
Results are presented for highly accurate ab initio variational calculation of the rotation - vibration energy levels of H2O2 in its electronic ground state. These results use a recently computed potential energy surface and the variational…
Accurate ab initio calculations of the energy levels of the superheavy elements Z=112 are presented. Relativistic Hartree-Fock and configuration interaction methods are combined with the many-body perturbation theory to construct the…
We determine the low-energy behaviour of the scattering operator of two-dimensional Schr\"odinger operators with any type of obstructions at 0-energy. We also derive explicit formulas for the wave operators in the absence of p-resonances,…
The direct solution of the many-particle Schr\"odinger equation is computationally inaccessible for more than very few electrons. In order to surpass this limitation, one of the authors [X. Oriols, Phys. Rev. Lett. 2007, 98 (066803)] has…
Helium (He) is the ideal atom to perform tests of ab-initio calculations in two-electron systems that consider all known effects, including quantum-electrodynamics and nuclear-size contributions. Recent state-of-the-art calculations and…
We show that the Schr\"odinger equation can be solved exactly based only on classical least action. Fundamental postulates of quantum mechanics can in turn be derived directly from this construction. The results extend to the relativistic…
The particle in an expanding/contracting 1-dimension box is revisited in action-angle like variables with direct thermodynamic interpretation. An angle dependent potential is proposed accurately describing the mechanical behavior while also…
A photoelectron, emitted due to the absorption of light quanta as described by the photoelectric effect, is often characterized experimentally by a classical quantity, its momentum. However, since the photoelectron is a quantum object, its…