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General relationship between mean Boltzmann entropy and Gibbs entropy is established. It is found that their difference is equal to fluctuation entropy, which is a Gibbs-like entropy of macroscopic quantities. The ratio of the fluctuation…

Statistical Mechanics · Physics 2018-04-19 Pasko Zupanovic , Domagoj Kuic

We study an entropy measure for quantum systems that generalizes the von Neumann entropy as well as its classical counterpart, the Gibbs or Shannon entropy. The entropy measure is based on hypothesis testing and has an elegant formulation…

Quantum Physics · Physics 2014-02-19 F. Dupuis , L. Kraemer , P. Faist , J. M. Renes , R. Renner

In this study we apply the maximum entropy principle to derive the properly scaled velocity distribution function of Boltzmann equations for mixtures, which leads to a non-isothermal Maxwell-Stefan diffusion model. We also analyze the…

Mathematical Physics · Physics 2021-10-22 Benjamin Anwasia , Srboljub Simić

A survey of the approach to Statistical Mechanics following Boltzmann's theory of ensembles and ergodic hypothesis leading to chaoticity as a unifying principle of equilibrium and nonequilibrium Statistical Mechanics.

Statistical Mechanics · Physics 2007-05-23 Giovanni Gallavotti

I show that the maximum entropy principle can be replaced by a more natural assumption, that there exists a phenomenological function of entropy consistent with the microscopic model. The requirement of existence provides then a unique…

Classical Physics · Physics 2014-07-22 Łukasz Rudnicki

The Shannon-Khinchin axioms for the ordinary information entropy are generalized in a natural way to the nonextensive systems based on the concept of nonextensive conditional entropy, and a complete proof of the uniqueness theorem for the…

Statistical Mechanics · Physics 2009-10-31 Sumiyoshi Abe

Information plays an important role in our understanding of the physical world. We hence propose an entropic measure of information for any physical theory that admits systems, states and measurements. In the quantum and classical world,…

Quantum Physics · Physics 2010-05-04 Anthony J. Short , Stephanie Wehner

Two new relative entropy quantities, called the min- and max-relative entropies, are introduced and their properties are investigated. The well-known min- and max- entropies, introduced by Renner, are obtained from these. We define a new…

Quantum Physics · Physics 2016-11-18 Nilanjana Datta

Entropy in nonequilibrium statistical mechanics is investigated theoretically so as to extend the well-established equilibrium framework to open nonequilibrium systems. We first derive a microscopic expression of nonequilibrium entropy for…

Statistical Mechanics · Physics 2007-06-13 Takafumi Kita

Meixner's historical remark in 1969 "... it can be shown that the concept of entropy in the absence of equilibrium is in fact not only questionable but that it cannot even be defined...." is investigated from today's insight. Several…

Statistical Mechanics · Physics 2018-10-17 Wolfgang Muschik

The notion of entropy penetrates much of science. A key feature of the all-important notion of Boltzmann-Gibbs-Shannon entropy is its extensivity (additivity over independent subsystems). However, there is a need for other quantities. In…

Mathematical Physics · Physics 2008-07-29 Flemming Topsoe

Within its range of applicability, the Boltzmann equation seems unique in its capacity to accurately describe the transition from almost any initial state to a self-equilibrated thermal state. Using information-theoretic methods to rephrase…

Statistical Mechanics · Physics 2025-10-07 Jürgen T. Stockburger

Entropy is a central concept in physics, but can be challenging to calculate even for systems that are easily simulated. This is exacerbated out of equilibrium, where generally little is known about the distribution characterizing simulated…

Statistical Mechanics · Physics 2024-05-09 Samuel D. Gelman , Guy Cohen

A number of inequalities for the weighted entropies is proposed, mirroring properties of a standard (Shannon) entropy and related quantities.

Information Theory · Computer Science 2015-10-12 Yuri Suhov , Salimeh Yasaei Sekeh

Since its origin in the thermodynamics of the 19th century, the concept of entropy has also permeated other fields of physics and mathematics, such as Classical and Quantum Statistical Mechanics, Information Theory, Probability Theory,…

Machine Learning · Statistics 2025-03-06 Salomé A. Sepúveda Fontaine , José M. Amigó

It is shown that Onsager's principle of the least dissipation of energy is equivalent to the maximum entropy production principle. It is known that solutions of the linearized Boltzmann equation make extrema of entropy production. It is…

Statistical Mechanics · Physics 2015-05-18 Pasko Zupanovic , Domagoj Kuic , Zeljana Bonacic Losic , Drazen Petrov , Davor Juretic , Milan Brumen

A dynamical estimate is given for the Boltzmann entropy of the Universe, under the simplifying assumptions provided by Newtonian cosmology. We first model the cosmological fluid as the probability fluid of a quantum-mechanical system. Next,…

Quantum Physics · Physics 2023-07-19 D. Cabrera , P. Fernandez de Cordoba , J. M. Isidro

A statistical-mechanical investigation is performed on Rayleigh-B\'enard convection of a dilute classical gas starting from the Boltzmann equation. We first present a microscopic derivation of basic hydrodynamic equations and an expression…

Statistical Mechanics · Physics 2007-05-23 Takafumi Kita

The microscopic explanation of entropy has been challenged from both experimental and theoretical point of view. The expression of entropy is derived from the first law of thermodynamics indicating that entropy or the second law of…

General Physics · Physics 2007-05-23 Jozsef Garai

The thermodynamic maximum principle for the Boltzmann-Gibbs-Shannon (BGS) entropy is reconsidered by combining elements from group and measure theory. Our analysis starts by noting that the BGS entropy is a special case of relative entropy.…

Statistical Mechanics · Physics 2008-11-26 Jörn Dunkel , Peter Talkner , Peter Hänggi