Related papers: Surface defreezing of glasses
The glass transition refers to the non-equilibrium process by which an equilibrium liquid is transformed to a non-equilibrium disordered solid, or vice versa. Associated response functions, such as heat capacities, are markedly different on…
We report a wavelike fracture pattern in a Zr-based bulk metallic glass that has been deformed under quasi-static uniaxial tensions at temperatures between room temperature (300 K) and liquid nitrogen temperature (77 K). We attribute this…
Monte Carlo or Molecular Dynamics calculations of surfaces of Lennard-Jones systems often indicate, apart from a gradual disordering of the surface called surface melting, the presence of a phase transition at the surface, but cannot…
Collective motion over increasing length scales is a signature of the vitrification process of liquids. We demonstrate the emergence of distinct static and dynamic length scales probed near the free surface in fully equilibrated…
The dynamics of a dense binary mixture of soft dumbbells, each subject to an active propulsion force and thermal fluctuations, shows a sudden arrest, first to a translational then to a rotational glass, as one reduces temperature $T$ or the…
We develop a transferable machine learning model which predicts structural relaxation from amorphous supercooled liquid structures. The trained networks are able to predict dynamic heterogeneity across a broad range of temperatures and time…
Based on the Elastically Collective Nonlinear Langevin Equation theory of bulk relaxation in glass-forming liquids, and our recent ideas of how interface-nucleated modification of caging constraints are spatially transferred into the…
The existence of a 'crossover region' in glass-forming liquids has long been considered as a general phenomenon that is as important as the glass transition. One potential origin for the crossover behavior is a liquid-to-liquid phase…
We measured the shear viscosity of 14 metallic glasses differing with their mixing entropy $\Delta S_{mix}$. It is found that the viscosity at the glass transition temperature $T_g$ significantly increases with $\Delta S_{mix}$. Using…
We analyze the displacements of the particles of a glass-forming molecular liquid perpendicular to a confining solid surface, using extensive molecular dynamics simulations with atomistic models. In the vicinity of an attractive surface,…
A universal dynamical crossover temperature, Tcr, in glassy liquids, associated with the {\alpha}-\b{eta} bifurcation temperature, TB, has been observed in dielectric spectroscopy and other experiments. Tcr lies significantly above the…
Glasses and gels are the two dynamically arrested, disordered states of matter. Despite their importance, their similarities and differences remain elusive, especially at high density. We identify dynamical and structural signatures which…
The crystallisation that occurs when a drop is placed in contact with a cold surface is a particularly challenging phenomenon to capture experimentally and describe theoretically. The situation of a liquid-liquid interface, where crystals…
Stability of thin lubricating fluid coated slippery surfaces depends on the surface energy of the underlying solid surface. High energy solid surfaces, coated with thin lubricating oil, lead to the dewetting of the oil films upon depositing…
We computed a Lennard Jones frozen liquid with a free surface using classical molecular dynamics. The structure factor curves on the free surface of this sample was calculated for different depths knowing that we have periodic boundary…
Surface bubbles are present in many industrial processes and in nature, as well as in CO$_2$ beverage. They have motivated many theoretical, numerical and experimental works. This paper presents the current knowledge on the physics of…
The levitation of a volatile droplet on a highly superheated surface is known as the Leidenfrost effect. Wetting state during transition from full wetting of a surface by a droplet at room temperature to Leidenfrost bouncing, i.e.,…
The surface freezing and surface melting transitions exhibited by a model two-dimensional soft matter system is studied. The behaviour when confined within a wedge is also considered. The system consists of particles interacting via a soft…
In stark contrast with the conventional understanding of the glass transition, where the transition from glass to liquid appears as a dynamic process where atoms/molecules cooperatively relax into the equilibrium phase, we experimentally…
The dynamics of a thin layer of liquid, between a flat solid substrate and an infinitely-thick layer of saturated vapor, is examined. The liquid and vapor are two phases of the same fluid, governed by the diffuse-interface model. The…