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The idea that a thermodynamic glass transition of some sort underlies the observed glass formation has been highly debated since Kauzmann first stressed the hypothetical entropy crisis that could take place if one were able to equilibrate…

Disordered Systems and Neural Networks · Physics 2022-09-23 Chiara Cammarota , Misaki Ozawa , Gilles Tarjus

We analyze the properties of the energy landscape of {\it finite-size} fully connected p-spin-like models whose high temperature phase is described, in the thermodynamic limit, by the schematic Mode Coupling Theory of super-cooled liquids.…

Disordered Systems and Neural Networks · Physics 2009-10-31 A. Crisanti , F. Ritort

We use molecular dynamics computer simulations to investigate a critical temperature T_c for a dynamical glass transition as proposed by the mode-coupling theory (MCT) of dense liquids in a glass forming Ni_{0.8}Zr_{0.2}-system. The…

Materials Science · Physics 2007-08-09 A. B. Mutiara

We use computer simulations to study the thermodynamic properties of a glass former in which a fraction $c$ of the particles has been permanently frozen. By thermodynamic integration, we determine the Kauzmann, or ideal glass transition,…

Soft Condensed Matter · Physics 2018-02-28 Misaki Ozawa , Walter Kob , Atsushi Ikeda , Kunimasa Miyazaki

An undercooled liquid is unstable. The driving force of the glass transition at Tg is a change of the undercooled-liquid Gibbs free energy. The classical Gibbs free energy change for a crystal formation is completed including an enthalpy…

Disordered Systems and Neural Networks · Physics 2015-06-19 Robert Felix Tournier

In supercooled liquids, at a temperature between the glass transition temperature Tg and the melting point Tm, thermodynamic properties remain continuous, while dynamic behavior exhibits anomalies. The origin of such thermodynamics-dynamic…

Soft Condensed Matter · Physics 2025-06-17 X. R. Tian , D. M. Zhang , B. Zhang , D. Y. Sun , X. G. Gong

We study the statistical mechanics of supercooled liquids when the system evolves at a temperature $T$ with a field $\epsilon$ linearly coupled to its overlap with a reference configuration of the same liquid sampled at a temperature $T_0$.…

Statistical Mechanics · Physics 2022-04-05 Benjamin Guiselin , Ludovic Berthier , Gilles Tarjus

We give a brief introduction to the mode-coupling theory of the glass transition, a theory which was proposed a while ago to describe the dynamics of supercooled liquids. After presenting the basic equations of the theory, we review some of…

Statistical Mechanics · Physics 2008-02-03 W. Kob

We propose that glass-forming liquids are intrinsically under the influences of both fluctuating interactions and random fields well-known in the field of spin systems. This is due to the frustration between the isotropic and anisotropic…

Disordered Systems and Neural Networks · Physics 2009-10-30 Hajime Tanaka

We propose a novel model for a glass-forming liquid which allows to switch in a continuous manner from a standard three-dimensional liquid to a fully connected mean-field model. This is achieved by introducing k additional particle-particle…

Disordered Systems and Neural Networks · Physics 2023-02-15 Ujjwal Kumar Nandi , Walter Kob , Sarika Maitra Bhattacharyya

For the dynamical glassy transition in the $p$-spin mean field spin glass model a thermodynamic description is given. The often considered marginal states are not the relevant ones for this purpose. This leads to consider a cooling…

Disordered Systems and Neural Networks · Physics 2009-10-30 Th. M. Nieuwenhuizen

We review the Random First Order Transition Theory of the glass transition, emphasizing the experimental tests of the theory. Many distinct phenomena are quantitatively predicted or explained by the theory, both above and below the glass…

Disordered Systems and Neural Networks · Physics 2015-06-25 Vassiliy Lubchenko , P. G. Wolynes

We describe our perspective on the Structural Glass Transition (SGT) problem built on the premise that a viable theory must provide a consistent picture of the dynamics and statics, which are manifested by large increase in shear viscosity…

Soft Condensed Matter · Physics 2009-12-15 T. R. Kirkpatrick , D. Thirumalai

Random first order transition theory is used to determine the role of attractive and repulsive interactions in the dynamics of supercooled liquids. Self-consistent phonon theory, an approximate mean field treatment consistent with random…

Soft Condensed Matter · Physics 2007-09-13 Randall W. Hall , Peter G. Wolynes

The study of the properties of glass-forming liquids is difficult for many reasons. Analytic solutions of mean field models are usually available only for systems embedded in a space with an unphysically high number of spatial dimensions;…

Disordered Systems and Neural Networks · Physics 2015-02-26 Manuel Sebastian Mariani , Giorgio Parisi , Corrado Rainone

In this paper we propose a simple mean-field "toy" model for the liquid-glass phase transition. This is the system of $N$ point-like particles confined in a finite volume of a $D$-dimensional space interacting via infinite-range oscillating…

Disordered Systems and Neural Networks · Physics 2007-05-23 Victor Dotsenko

We show that the various crossovers between dynamical regimes observed in experiments and simulations of supercooled liquids can be explained in simple terms from the existence and statistical properties of dynamical heterogeneities. We…

Statistical Mechanics · Physics 2009-11-10 Ludovic Berthier , Juan P. Garrahan

We discuss the general link between mode-coupling like equations (which serve as the basis of some recent theories of supercooled liquids) and the dynamical equations governing mean-field spin-glass models, or the dynamics of a particle in…

Condensed Matter · Physics 2015-06-25 Jean-Philippe Bouchaud , Leticia Cugliandolo , Jorge Kurchan , Marc Mézard

We consider the relationship between the temperature at which averaged energy landscape properties change sharply ($T_{o}$), and the breakdown of mean-field treatments of the dynamics of supercooled liquids. First, we show that the solution…

Soft Condensed Matter · Physics 2009-11-10 Yisroel Brumer , David R. Reichman

We report a computer simulation study of the glass transition for water. To mimic the difference between standard and hyperquenched glass, we generate glassy configurations with different cooling rates and calculate the $T$ dependence of…

Soft Condensed Matter · Physics 2016-08-31 Nicolas Giovambattista , C. Austen Angell , Francesco Sciortino , H. Eugene Stanley
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