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The crystal structure of Fe3O4 below the 122 K Verwey transition has been refined using high-resolution X-ray and neutron powder diffraction data. The refinements give direct evidence for charge ordering (CO) over four independent…

Strongly Correlated Electrons · Physics 2009-11-07 J. P. Wright , J. P. Attfield , P. G. Radaelli

The optical conductivity of the undoped PrMnO$_3$ manganite has been investigated in details at various temperatures between 300 and 4 K. Its low energy spectrum exhibits an optical gap, and is characterized by a single broad peak centered…

Strongly Correlated Electrons · Physics 2007-05-23 R. Sopracase , G. Gruener , C. Autret-Lambert , V. Ta Phuoc , V. Brize , J. C. Soret

The charge and orbital ordering in Pr_{0.5} Ca_{0.5} MnO_3 is studied for the first time by ^{17}O NMR. This local probe is sensitive to spin, charge and orbital correlations. Two transitions exist in this system: the charge and orbital…

Strongly Correlated Electrons · Physics 2009-11-07 A. Yakubovskii , A. Trokiner , S. Verkhovskii , A. Gerashenko , D. Khomskii

In quantum materials, charge orders typically stabilize in specific crystallographic orientations, though their formation mechanisms may vary. Here, using low-temperature scanning tunneling microscopy (STM), we discover a lattice-decoupled…

The temperature evolution of structural effects associated with charge (CO) and spin order (SO) in La$_{1.67}$Sr$_{0.33}$NiO$_{4}$ has been investigated using neutron powder diffraction. We report an anomalous shrinking of the $c/a$ lattice…

Strongly Correlated Electrons · Physics 2015-03-17 A. M. Milinda Abeykoon , Emil S. Božin , Wei-Guo Yin , Genda Gu , John P. Hill , John M. Tranquada , Simon J. L. Billinge

Novel electronic phenomena frequently form in heavy fermions as a consequence of the mutual nature of localization and itineracy of f electrons. On the magnetically ordered side of the heavy fermion phase diagram, f moments are expected to…

55Mn and 139La NMR measurements on a high quality single crystal of ferromagnetic (FM) La0.80Ca20MnO3 demonstrate the formation of localized Mn(3+,4+) states below 70 K, accompanied with strong anomalous increase of certain FM neutron Bragg…

Strongly Correlated Electrons · Physics 2009-11-07 G. Papavassiliou , M. Belesi , M. Fardis , M. Pissas , J. Dolinsek , C. Dimitropoulos , J. P. Ansermet

We report detailed magnetization measurements on the perovskite oxide NdNiO$_3$. This system has a first order metal-insulator (M-I) transition at about 200 K which is associated with charge ordering. There is also a concurrent paramagnetic…

Strongly Correlated Electrons · Physics 2016-01-11 Devendra Kumar , K. P. Rajeev , J. A. Alonso , M. J. Martinez-Lope

We report inelastic neutron scattering results on the spin dynamics in the 50 % hole-doped manganites, Pr{1/2}Sr{1/2}MnO3 and Nd{1/2}Sr{1/2}MnO3. In the paramagnetic phase, these systems exhibit a ridge-type diffuse scattering, indicating a…

Strongly Correlated Electrons · Physics 2007-05-23 H. Kawano , R. Kajimoto , H. Yoshizawa , Y. Tomioka , H. Kuwahara , Y. Tokura

We present diffraction data on a single-layered manganite La(0.42)Sr(1.58)MnO4 with hole doping (x>0.5). Overdoped La(0.42)Sr(1.58)MnO4 exhibits a complex ordering of charges, orbitals and spins. Single crystal neutron diffraction…

Strongly Correlated Electrons · Physics 2012-01-12 H. Ulbrich , D. Senff , P. Steffens , O. J. Schumann , Y. Sidis , P. Reutler , A. Revcolevschi , M. Braden

Two distinct ferromagnetic phases of LaMn$_{0.5}$Co$_{0.5}$O$_{3}$ having monoclinic structure with distinct physical properties have been studied. The ferromagnetic ordering temperature $\textit{T}_{c}$ is found to be different for both…

Strongly Correlated Electrons · Physics 2010-09-08 M. Viswanathan , P. S. Anil Kumar , Venkata Srinu Bhadram , Chandrabhas Narayana , A. K. Bera , S. M. Yusuf

We report femtosecond resonant soft X-ray diffraction measurements of the dynamics of the charge order and of the crystal lattice in non-superconducting, stripe-ordered La1.875Ba0.125CuO4. Excitation of the in-plane Cu-O stretching phonon…

The recently discovered lithium-rich antiperovskites (Li$_2$Fe)SeO and (Li$_2$Fe)SO host lithium and iron ions on the same atomic position which octahedrally coordinates to central oxygens. In a cubic antiperovskite these sites form Kagome…

Modulations in manganites attributed to stripes of charge/orbital/spin order are thought to result from strong electron-lattice interactions that lock the superlattice and parent lattice periodicities. Surprisingly in La1-xCaxMnO3(x>0.5, 90…

Strongly Correlated Electrons · Physics 2007-05-23 J. C. Loudon , S. Cox , A. J. Williams , J. P. Attfield , P. B. Littlewood , P. A. Midgley , N. D. Mathur

Contrary to conventional wisdom, our purified La2-2xSr1+2xMn2O7 crystals exhibit CE-type orbital and charge order as the low-temperature ground state for a hole doping level h = 0.5. For small deviations from h = 0.5, the high temperature…

Strongly Correlated Electrons · Physics 2007-05-23 Qing'An Li , K. E. Gray , H. Zheng , H. Claus , S. Rosenkranz , S. Nyborg Ancona , R. Osborn , J. F. Mitchell , Y. Chen , J. W. Lynn

Microstructure properties, phase transitions, and charge ordering in the LuFe2O4 materials have been extensively investigated by means of transmission electron microscopy (TEM). The (001) twins as a common defect frequently appear in the…

Strongly Correlated Electrons · Physics 2007-05-23 Y. Zhang , H. X. Yang , C. Ma , H. F. Tian , J. Q. Li *

We have utilized the resonant x-ray diffraction technique at the Mn L-edge in order to directly compare magnetic and orbital correlations in the Mn sub-lattice of Pr0.6Ca0.4MnO3. The resonant line shape is measured below T_OO ~ 240 K at the…

Strongly Correlated Electrons · Physics 2009-11-10 K. J. Thomas , J. P. Hill , Y-J. Kim , S. Grenier , P. Abbamonte , L. Venema , A. Rusydi , Y. Tomioka , Y. Tokura , D. F. McMorrow , M. van Veenendaal

A hypothetical layered oxide La_2NiMO_6 where NiO_2 and MO_2 planes alternate along the c-axis of ABO_3 perovskite lattice is considered theoretically. Here, M denotes a trivalent cation Al, Ga,... such that MO_2 planes are insulating and…

Strongly Correlated Electrons · Physics 2010-05-11 Jiri Chaloupka , Giniyat Khaliullin

We report on the lattice evolution of BiFeO3 as function of temperature using far infrared emissivity, reflectivity, and X-ray absorption local structure. A power law fit to the lowest frequency soft phonon in the magnetic ordered phase…

Chalcogenide perovskites have emerged as promising lead free materials for photovoltaic and thermoelectric applications. Among them, BaZrS3 has attracted particular attention due to its thermal and chemical stability, favorable…

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