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Related papers: Chlorine adsorption on the Cu(111) surface

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The adsorption of CO on unreconstructed and reconstructed Ir{100} has been studied, using a combination of density functional theory and thermodynamics, to determine the relative stability of the two phases as a function of CO coverage,…

Materials Science · Physics 2009-11-13 Prasenjit Ghosh , Shobhana Narasimhan , Stephen J. Jenkins , David A. King

The geometrical and electronic properties of the monolayer (ML) of tetracene (Tc) molecules on Ag(111) are systematically investigated by means of DFT calculations with the use of localized basis set. The bridge and hollow adsorption…

Mesoscale and Nanoscale Physics · Physics 2016-11-09 N. L. Zaitsev , I. A. Nechaev , U. Höfer , E. V. Chulkov

A lattice gas model is used to study the equilibrium properties and desorption kinetics of CO on Ru(0001). With interactions obtained from density functional theory (DFT) the phase diagram and temperature programmed desorption (TPD) spectra…

Statistical Mechanics · Physics 2007-05-23 J. -S. McEwen , A. Eichler

In this work, we have studied theoretically the effects of gold adsorption on the Al(001) surface, using {\it ab initio} pseudo-potential method in the framework of the density functional theory. Having found the hollow sites at the Al(001)…

Materials Science · Physics 2009-11-13 N. Zare Dehnavi , M. Payami

Adsorption of para-Hydrogen on the outer surface of a single fullerene is studied theoretically, by means of ground state Quantum Monte Carlo simulations. We compute energetics and radial density profiles of para-Hydrogen for various…

Statistical Mechanics · Physics 2009-11-10 Joseph D. Turnbull , Massimo Boninsegni

The structure of the adsorbed layer of alkali ions on the surface of colloidal silica solutions with a particle size of ~27 nm has been studied by reflectometry and diffuse scattering of synchrotron radiation with a photon energy of about…

Ionization of polar liquids and glasses often yields metastable electron centers collectively known as weakly bound (wb) electrons that absorb to the red of the ground state of the solvated/trapped electron. Formation of these species is…

Chemical Physics · Physics 2022-04-26 Ilya A. Shkrob

Graphynes are 2D porous structures deriving from graphene featuring triangular and regularly distributed subnanometer pores, which may be exploited to host small gaseous species. First principles adsorption energies of molecular hydrogen…

Chemical Physics · Physics 2015-10-06 Massimiliano Bartolomei , Estela Carmona-Novillo , Giacomo Giorgi

The adsorption and dissociation of isolated water molecule on Zr(0001) surface are theoretically investigated for the first time by using density-functional theory calculations. Two kinds of adsorption configurations with almost the same…

Materials Science · Physics 2015-05-27 Shuang-Xi Wang , Ping Zhang , Peng Zhang , Jian Zhao , Shu-Shen Li

A systematic fieldtheoretic description of critical adsorption on curved objects such as spherical or rodlike colloidal particles immersed in a fluid near criticality is presented. The temperature dependence of the corresponding order…

Statistical Mechanics · Physics 2009-10-31 A. Hanke , S. Dietrich

We study light absorption by weakly rough metal surfaces with the roughness amplitude and correlation length smaller than the skin depth in metal. We develop a systematic perturbative approach for calculation of the absorptance in such…

Mesoscale and Nanoscale Physics · Physics 2022-11-16 Zhyrair S. Gevorkian , Ludvig S. Petrosyan , Tigran V. Shahbazyan

Understanding the molecular and electronic structure of electrolytes at interfaces requires an analysis of the interactions between the electrode surface, the ions, and the solvent environment on equal footing. Here, we tackle this…

Mesoscale and Nanoscale Physics · Physics 2023-03-16 Christopher Penschke , John Thomas , Cord Bertram , Angelos Michaelides , Karina Morgenstern , Peter Saalfrank , Uwe Bovensiepen

Motivated by the recent realization of graphene sensors to detect individual gas molecules, we investigate the adsorption of H2O, NH3, CO, NO2, and NO on a graphene substrate using first-principles calculations. The optimal adsorption…

Materials Science · Physics 2009-11-13 O. Leenaerts , B. Partoens , F. M. Peeters

This paper reports state-of-the-art electronic structure calculations of La adsorption on the Si(001) surface. We predict La chains in the low coverage limit, which condense in a stable phase at a coverage of 1/5 monolayer. At 1/3 monolayer…

Materials Science · Physics 2007-05-23 Christopher R. Ashman , Clemens J. Foerst , Karlheinz Schwarz , Peter E. Bloechl

The structure of AgCl formed in the course of chlorine adsorption on Ag(111) surface was studied by STM. For the first time atomic resolution STM images of silver chloride were obtained. The silver chloride was detected as small (30-60 A in…

Materials Science · Physics 2009-10-31 B. V. Andryushechkin , K. N. Eltsov , V. M. Shevlyuga

We demonstrate that 100% light absorption can take place in a single patterned sheet of doped graphene. General analysis shows that a planar array of small lossy particles exhibits full absorption under critical-coupling conditions provided…

The adsorption of three different polycations at the negatively charged surface of tubular J-aggregates of the amphiphilic cyanine dye 3,3'-bis(2-sulfopropyl)-5,5',6,6'-tetrachloro-1,1'-dioctylbenzimidacarbocyanine (C8S3) is investigated by…

Our ab initio calculations of CO adsorption energies on low miller index (111), (100), stepped (211), and kinked (532) gold surfaces show a strong dependence on local coordination with a reduction in Au atom coordination leading to higher…

Materials Science · Physics 2009-11-13 F. Mehmood , A. Kara , T. S. Rahman , C. R. Henry

Nonspecific molecular adsorption like airborne contamination occurs on most surfaces including those of 2D materials and alters their properties. While the surface contamination is studied using a plethora of techniques, the effect of…

The adsorption equilibrium constants of monovalent and divalent cations to material surfaces in aqueous media are central to many technological, natural, and geochemical processes. Cation adsorption/desorption is often proposed to occur in…