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We use the path-integral Monte Carlo (PIMC) method and state-of-the-art two-body and three-body potentials to calculate the fourth virial coefficients $D(T)$ of $^4$He and $^3$He as functions of temperature from 2.6K to 2000K. We derive…

Atomic and Molecular Clusters · Physics 2021-03-24 Giovanni Garberoglio , Allan H. Harvey

A simple algorithm is described to sample permutations of identical particles in Path Integral Monte Carlo (PIMC) simulations of continuum many-body systems. The sampling strategy illustrated here is fairly general, and can be easily…

Computational Physics · Physics 2009-11-11 Massimo Boninsegni

The effect of pressure on structural and thermodynamic properties of ice Ih has been studied by means of path-integral molecular dynamics simulations at temperatures between 50 and 300 K. Interatomic interactions were modeled by using the…

Materials Science · Physics 2012-01-05 Carlos P. Herrero , Rafael Ramirez

In this paper we present a Path Integral Monte Carlo (PIMC) simulation of the orthorhombic phase of crystalline polyethylene, using an explicit atom force field with unconstrained bond lengths and angles. This work represents a quantum…

Materials Science · Physics 2009-10-30 R. Martonak , W. Paul , K. Binder

The quantum theory of the Friedmann cosmological model with dust and cosmological constant ($\Lambda$) is not exactly solvable analytically. We apply Path Integral Monte Carlo (PIMC) techniques to study its quantum dynamics using the…

General Relativity and Quantum Cosmology · Physics 2020-09-10 Masooma Ali , Syed Moeez Hassan , Viqar Husain

We present extensive new \emph{ab initio} path integral Monte Carlo (PIMC) results for a variety of structural properties of warm dense hydrogen and beryllium. To deal with the fermion sign problem -- an exponential computational bottleneck…

The strongly coupled electron liquid provides a unique opportunity to study the complex interplay of strong coupling with quantum degeneracy effects and thermal excitations. To this end, we carry out extensive \textit{ab initio} path…

Computational Physics · Physics 2020-02-05 Tobias Dornheim , Travis Sjostrom , Shigenori Tanaka , Jan Vorberger

The accurate description of non-ideal quantum many-body systems is of prime importance for a host of applications within physics, quantum chemistry, material science, and related disciplines. At finite temperatures, the gold standard is…

This chapter is devoted to the computation of equilibrium (thermodynamic) properties of quantum systems. In particular, we will be interested in the situation where the interaction between particles is so strong that it cannot be treated as…

Mesoscale and Nanoscale Physics · Physics 2016-02-03 Alexei Filinov , Jens Böning , Michael Bonitz

In this work we calculate the thermodynamic properties of hydrogen-helium plasmas with different mass fractions of helium by the direct path integral Monte Carlo method. To avoid unphysical approximations we use the path integral…

Plasma Physics · Physics 2009-11-11 P. R. Levashov , V. S. Filinov , M. Bonitz , V. E. Fortov

We present diffusion Monte Carlo (DMC) and path-integral Monte Carlo (PIMC) calculations of a one-dimensional Bose system with realistic interparticle interactions in a periodic external potential. Our main aim is to test the predictions of…

Quantum Gases · Physics 2020-02-19 K. Dzelalija , L. Vranjes Markic

Path integral Monte Carlo (PIMC) simulations have become an important tool for the investigation of the statistical mechanics of quantum systems. I discuss some of the history of applying the Monte Carlo method to non-relativistic quantum…

History and Philosophy of Physics · Physics 2016-11-23 Tilman Sauer

Path integral quantum Monte Carlo (PIMC) is a method for estimating thermal equilibrium properties of stoquastic quantum spin systems by sampling from a classical Gibbs distribution using Markov chain Monte Carlo. The PIMC method has been…

Quantum Physics · Physics 2021-02-22 Elizabeth Crosson , Aram W. Harrow

We performed simulations for solid molecular hydrogen at high pressures (250GPa$\leq$P$\leq$500GPa) along two isotherms at T=200 K (phases III and VI) and at T=414 K (phase IV). At T=200K we considered likely candidates for phase III, the…

Materials Science · Physics 2017-11-22 Giovanni Rillo , Miguel A. Morales , David M. Ceperley , Carlo Pierleoni

The ground-state properties of two-dimensional liquid $^4$He at zero temperature are studied by means of a quadratic diffusion Monte Carlo method. As interatomic potential we use a revised version of the HFDHE2 Aziz potential which is…

Condensed Matter · Physics 2009-10-28 S. Giorgini , J. Boronat , J. Casulleras

Restricted path integral Monte Carlo simulations have been used to calculate the equilibrium properties of deuterium for two densities: 0.674 and 0.838 gcm^-3 (rs = 2.00 and 1.86) in the temperature range of 10000 < T < 1000000 K. Using the…

Plasma Physics · Physics 2009-11-06 B. Militzer , D. M. Ceperley

We introduce a Path Integral Monte Carlo (PIMC) approach that uses the angular momentum representation for the description of interacting rotor systems. Such a choice of representation allows the calculation of momentum properties without…

Chemical Physics · Physics 2025-10-22 Estêvão de Oliveira , Muhammad Shaeer Moeed , Pierre-Nicholas Roy

In this article we present the second part of our historical survey on quantum Monte Carlo methods. IWe focus on the simulations performed at a finite temperature and based on the path-integral formulation of quantum mechanics. We introduce…

History and Philosophy of Physics · Physics 2021-09-29 Michel Mareschal

Experimental investigation of cavitation in liquid helium 3 has revealed a singular behaviour in the degenerate region at low temperature. As the temperature decreases below 80 mK, the cavitation pressure becomes significantly more…

Soft Condensed Matter · Physics 2007-05-23 Frederic Caupin , Sebastien Balibar , Humphrey J. Maris

We carry out highly accurate \emph{ab initio} path integral Monte Carlo (PIMC) simulations to directly estimate the free energy of various warm dense matter systems including the uniform electron gas and hydrogen without any nodal…

Quantum Gases · Physics 2024-07-02 Tobias Dornheim , Zhandos Moldabekov , Sebastian Schwalbe , Jan Vorberger