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We suggest a random field based model for calculation of physical properties of mixed ferroelectric relaxors. Our model naturally incorporates the different orientations of electric dipoles (related to different solid solution components)…

Materials Science · Physics 2007-05-23 M. D. Glinchuk , E. A. Eliseev , V. A. Stephanovich , B. Hilczer

Specific heat studies of the Sr$_{1-x}$Ba$_x$Mn$_{1-y}$Ti$_y$O$_3$ polycrystalline samples performed by the relaxation and DSC methods over the temperature range 2 - 450 K are reported. Anomalies accompanying the…

Statistical Mechanics · Physics 2025-07-31 J. Wieckowski , A. Szewczyk , M. U. Gutowska , B. Dabrowski

Under a sufficiently high applied electric field, a non-polar antiferroelectric material, such as \ce{PbZrO3}, can undergo a rapid transformation to a polar ferroelectric phase. While this behavior is promising for energy storage and…

Magnetic state is a partial ordered state if only part of the electrons in the system give contribution to the magnetic order. We study Heisenberg model of two sublattice spin system, on the body-centered cubic lattice, with…

Strongly Correlated Electrons · Physics 2024-09-20 N. Karchev

A single crystal of lead-zirconate-titanate (PZT), composition Pb(Zr0.80Ti0.20)O3, was studied by polarized-Raman scattering as a function of temperature. Raman spectra reveal that the local structure deviates from the average structure in…

Materials Science · Physics 2015-06-23 J. Frantti , Y. Fujioka , A. Puretzky , Y. Xie , Z. -G. Ye , C. Parish , A. M. Glazer

Comprehensive review of investigations of substances with a small difference in the energies of the ferroelectric and antiferroelectric types of dipole ordering is presented. Detailed analysis of the stability of homogeneous phases and…

Materials Science · Physics 2018-01-11 V. M. Ishchuk , V. L. Sobolev

In this paper, we present a microscopic model for heterogeneous ferroelectric and an order parameter for relaxor phase. We write a Landau theory based on this model and its application to ferroelectric PbFe$_{1/2}$Ta$_{1/2}$O$_3$ (PFT) and…

Materials Science · Physics 2009-11-10 S. A. Prosandeev , I. P. Raevski , U. V. Waghmare

The structural and polar properties of BiFeO3 at finite temperature are investigated using an atomistic shell model fitted to first-principles calculations. Molecular Dynamics simulations show a direct transition from the low-temperature…

Materials Science · Physics 2015-06-23 M. Graf , M. Sepliarsky , S. Tinte , M. G. Stachiotti

We report on experimental studies of the character of phase transitions in the quasi-1D organic compound (TMTSF)2PF6 in the close vicinity of the borders between the paramagnetic metal PM, antiferromagnetic insulator AF, and superconducting…

Strongly Correlated Electrons · Physics 2009-11-10 A. V. Kornilov , V. M. Pudalov , Y. Kitaoka , K. Ishida , G. -q. Zheng , T. Mito , J. S. Qualls

Piezoelectric PZT solid solutions were studied as a function of pressure and temperature. Moderate pressure is found to induce phase transitions to monoclinic phases (Cm,Cc) for Ti-rich PZT, which are the same ferroelectric phases…

Materials Science · Physics 2009-05-14 Jérôme Rouquette , Julien Haines , Véronique Bornand , Philippe Papet

We investigate the charge and lattice states in a quasi-one-dimensional organic ferroelectric material, TTF-QCl$_{4}$, under pressures of up to 35 kbar by nuclear quadrupole resonance experiments. The results reveal a global…

We discuss a simple phenomenological Landau theory of phase transitions with two coupled single-component order parameters and compare the results with available experimental data. The model corresponds to the case of a ferroic system, in…

Strongly Correlated Electrons · Physics 2011-03-30 Olga Howczak , Jozef Spalek

Ferroelectrics are widely used for a broad array of technological applications due to their attractive electrical and electromechanical properties. In order to obtain large functional properties, material compositions are often designed to…

Materials Science · Physics 2025-01-31 Abhijit Pramanick , Laurent Daniel

The influence of the B-site ion substitutions in (1-x)(Bi1/2Na1/2)TiO3-xBaTiO3 system of solid solutions on the relative stability of the ferroelectric and antiferroelectric phases has been studied. The ions of zirconium, tin, along with…

Materials Science · Physics 2017-06-22 V. M. Ishchuk , D. V. Kuzenko , V. L. Sobolev

The results are presented of anelastic and dielectric spectroscopy measurements on large grain ceramic PZT with compositions near the two morphotropic phase boundaries (MPBs) that the ferroelectric (FE) rhombohedral phase has with the…

Materials Science · Physics 2013-03-27 F. Cordero , F. Trequattrini , F. Craciun , C. Galassi

One view of the cuprate high-transition temperature (high-Tc) superconductors is that they are conventional superconductors where the pairing occurs between weakly interacting quasiparticles, which stand in one-to-one correspondence with…

Strongly Correlated Electrons · Physics 2009-11-07 B Lake , HM Ronnow , NB Christensen , G Aeppli , K Lefmann , DF McMorrow , P Vorderwisch , P Smeibidl , N Mangkorntong , T Sasagawa , M. Nohara , H. Takagi , TE Mason

We report the effect of applied pressures on magnetic and superconducting order in single crystals of the aliovalent La-doped iron pnictide material Ca$_{1-x}$La$_{x}$Fe$_{2}$As$_{2}$. Using electrical transport, elastic neutron scattering…

Molecular dynamics simulations predict a giant electrocaloric effect at the ferroelectric-antiferroelectric phase boundary in PZT (PbTiO$_3$-PbZrO$_3$). These large-scale simulations also give insights into the atomistic mechanisms of the…

Materials Science · Physics 2019-07-24 A. V. Kimmel , O. T. Gindele , D. M. Duffy , R. E. Cohen

Several rare earth magnetic pyrochlore materials are well modeled by a spin-1/2 quantum Hamiltonian with anisotropic exchange parameters Js. For the Er2Ti2O7 material, the Js were recently determined from high-field inelastic neutron…

Strongly Correlated Electrons · Physics 2014-04-11 J. Oitmaa , R. R. P. Singh , A. G. R. Day , B. V. Bagheri , M. J. P. Gingras

The antipolar and antiferrodistortive (AFD) components of the antiferroelectric (AFE) transition in PbZr1-xTixO3 (x=0.054) can occur separately and with different kinetics, depending on the sample history, and are accompanied by elastic…

Materials Science · Physics 2014-06-16 F. Cordero , F. Trequattrini , F. Craciun , C. Galassi
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