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Related papers: Local-energy density functionals for an N-dimensio…

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Density functional theory provides the most widespread framework for the realistic description of the electronic structure of solids, but the description of strongly-correlated systems has remained so far elusive. Here we consider a…

Strongly Correlated Electrons · Physics 2016-09-07 Zu-Jian Ying , Valentina Brosco , Giorgia Maria Lopez , Daniele Varsano , Paola Gori-Giorgi , José Lorenzana

It has long been postulated that within density-functional theory (DFT) the total energy of a finite electronic system is convex with respect to electron count, so that 2 E_v[N_0] <= E_v[N_0 - 1] + E_v[N_0 + 1]. Using the…

Chemical Physics · Physics 2023-12-25 Andrew C. Burgess , Edward Linscott , David D. O'Regan

Physically valid and numerically efficient approximations for the exchange and correlation energy are critical for reduced density-matrix functional theory to become a widely used method in electronic structure calculations. Here we examine…

Strongly Correlated Electrons · Physics 2016-03-23 A. Putaja , F. G. Eich , T. Baldsiefen , E. Rasanen

A fermion ground state energy functional is set up in terms of particle density, relative pair density, and kinetic energy tensor density. It satisfies a minimum principle if constrained by a complete set of compatibility conditions. A…

Chemical Physics · Physics 2009-10-17 Bin Liu , Jerome K. Percus

Recent work has established Moreau-Yosida regularization as a mathematical tool to achieve rigorous functional differentiability in density-functional theory. In this article, we extend this tool to paramagnetic current-density-functional…

Density functional theory (DFT), the most widely adopted method in modern computational chemistry, fails to describe accurately the electronic structure of strongly correlated systems. Here we show that DFT can be formally and practically…

Chemical Physics · Physics 2022-04-18 Daniel Gibney , Jan-Niklas Boyn , David A. Mazziotti

A formal proof to relate the concept of electromagnetic local density of states (LDOS) to the electric and magnetic dyadic Green's functions is provided. The expression for LDOS is obtained by relating the electromagnetic energy density at…

Other Condensed Matter · Physics 2011-04-13 Arvind Narayanaswamy , Gang Chen

We present for static density functional theory and time-dependent density functional theory calculations an all-electron method which employs high-order hierarchical finite element bases. Our mesh generation scheme, in which structured…

Materials Science · Physics 2009-08-06 Lauri Lehtovaara , Ville Havu , Martti Puska

Since the seminal works of Thomas and Fermi, researchers in the Density-Functional Theory (DFT) community are searching for accurate electron density functionals. Arguably, the toughest functional to approximate is the noninteracting…

Materials Science · Physics 2018-05-23 Wenhui Mi , Alessandro Genova , Michele Pavanello

In this work we study in a formal way the density dependent hadron field theory at finite temperature for nuclear matter. The thermodynamical potential and related quantities, as energy density and pressure are derived in two different…

Nuclear Theory · Physics 2008-11-26 S. S. Avancini , M. E. Bracco , M. Chiapparini , D. P. Menezes

We review the progress that has been recently made in the application of time-dependent density functional theory to thermoelectric phenomena. As the field is very young, we emphasize open problems and fundamental issues. We begin by…

Mesoscale and Nanoscale Physics · Physics 2017-04-26 F. G. Eich , M. Di Ventra , G. Vignale

An accurate expression of the kinetic energy density of an electronic distribution in terms of the single particle reduced density matrix for atomic and molecular systems is a long-standing problem in electron structure theory. Existing…

Chemical Physics · Physics 2024-10-30 Priya , Mainak Sadhukhan

An atom placed inside a cavity of finite dimension offers many interesting features, and thus has been a topic of great current activity. This work proposes a density functional approach to pursue both ground and excited states of a…

Quantum Physics · Physics 2022-05-20 Sangita Majumdar , Amlan K. Roy

We present a density-functional theory (DFT) approach to the study of the phase diagram of the maximum density droplet (MDD) in two-dimensional quantum dots in a magnetic field. Within the lowest Landau level (LLL) approximation, analytical…

Mesoscale and Nanoscale Physics · Physics 2009-10-30 M. Ferconi , G. Vignale

The accompanying Comment by A. Holas and N. H. March [Phys. Rev. A {\bf 66}, 066501 (2002)] is concerned with the issue of whether or not kinetic energy can be represented by an effective local potential, as required for an exact…

Atomic Physics · Physics 2007-05-23 R. K. Nesbet

The exchange-correlation energy in Kohn-Sham density functional theory can be expressed exactly in terms of the change in the expectation of the electron-electron repulsion operator when, in the many-electron hamiltonian, this same operator…

Strongly Correlated Electrons · Physics 2009-08-05 Paola Gori-Giorgi , Giovanni Vignale , Michael Seidl

A introduction into density-functional theory and electronic structure methods is given, that aims at providing an intuitive understanding of the underlying concepts for the novice as well as an entry point towards the more advanced…

Other Condensed Matter · Physics 2011-08-20 Peter E. Blöchl

Density functional theory, when applied to systems with $T\neq 0$, is based on the grand canonical extension of the Hohenberg-Kohn-Sham theorem due to Mermin (HKSM theorem). While a straightforward canonical ensemble generalization fails,…

Statistical Mechanics · Physics 2009-10-31 J. A. Hernando , L. Blum

We establish the consistency of the Fermi liquid description and find a relation between Fermi liquid constants for the two dimensional electron system near the point of full polarization due to a parallel magnetic field $H$. Our results…

Mesoscale and Nanoscale Physics · Physics 2016-01-11 G. Zala , B. N. Narozhny , I. L. Aleiner , Vladimir I. Fal'ko

Thermal density functional theory calculations often use the Mermin-Kohn-Sham scheme, but employ ground-state approximations to the exchange-correlation (XC) free energy. In the simplest solvable nontrivial model, an asymmetric Hubbard…

Strongly Correlated Electrons · Physics 2016-06-29 Justin C Smith , Aurora Pribram-Jones , Kieron Burke
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