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Structural transformations, electronic spectra and ballistic transport in pulled gold nanowires are investigated with ab initio simulations, and correlated with recent measurements. Strain-induced yield of an initial double-strand wire…

Materials Science · Physics 2007-05-23 H. Hakkinen , R. N. Barnett , A. G. Scherbakov , U. Landman

The discovery of long bonds in gold atom chains has represented a challenge for physical interpretation. In fact, interatomic distances frequently attain 3.0-3.6 A values and, distances as large as 5.0 A may be seldom observed. Here, we…

Atomic and Molecular Clusters · Physics 2009-11-07 Sergio B. Legoas , Douglas S. Galvao , Varlei Rodrigues , Daniel Ugarte

Monatomic metal (e.g. silver) structures could form preferably at graphene edges. We explore their structural and electronic properties by performing density functional theory based first-principles calculations. The results show that…

Mesoscale and Nanoscale Physics · Physics 2017-09-13 Ning Wei , Cheng Chang , Hongwei Zhu , Zhiping Xu

The stability and electronic structure of a single monatomic Al wire has been studied using the ab initio pseudopotential method. The Al wire undergoes two structural rearrangements under compression, i.e., zigzag configurations at angles…

Materials Science · Physics 2015-06-24 Jin-Cheng Zheng , Hui-Qiong Wang , A. T. S. Wee , C. H. A. Huan

Strongly correlated electron systems host a variety of poorly understood correlations in their high temperature normal state. Unlike ordered phases defined by order parameters, these normal state phases are often defined through…

Quantized conductance behavior of gold nano wires was studied under electrochemical potential control. We fabricated 1 nm long mono atomic wires in solution at room temperature. Electrochemical potential significantly affected the stability…

Materials Science · Physics 2007-05-23 Manabu Kiguchi , Tatsuya Konishi , Kei Murakoshi

Using first principles simulations we perform a detailed study of the structural, electronic and transport properties of monoatomic platinum chains, sandwiched between platinum electrodes. First we demonstrate that the most stable atomic…

Materials Science · Physics 2007-05-23 V. M. Garcia-Suarez , A. R. Rocha , S. W. Bailey , C. J. Lambert , S. Sanvito , J. Ferrer

Electronic structure calculations for atomic wire of metals like Al, Ga and In are performed for a patterned dihydrogeneted Si(001):1 $\times$ 1 in search of structures with metallic behavior. The dihydrogeneted Si(001) is patterned by…

Materials Science · Physics 2009-11-11 Bikash C Gupta , Inder P. Batra

We performed density functional theory and tight-binding molecular dynamics calculations to investigate the formation of suspended linear atom chains when stretching gold nanowires along the [110] crystal orientation. We determined that…

Materials Science · Physics 2007-05-23 F. Tavazza , A. Hasmy , L. E. Levine , A. M. Chaka , L. Rincon , M. Marquez , C. Gonzalez

A comprehensive first-principles theoretical study of the electronic properties and half-metallic nature of finite zigzag carbon nanotubes is presented. Unlike previous reports, we find that all nanotubes studied present a spin-polarized…

Materials Science · Physics 2008-11-29 Oded Hod , Gustavo E. Scuseria

We study the stability of conductance oscillations in monatomic sodium wires with respect to structural variations. The geometry, the electronic structure and the electronic potential of sodium wires suspended between two sodium electrodes…

Materials Science · Physics 2009-11-11 Petr A. Khomyakov , Geert Brocks

The formation of gold nanowires in vacuum at room temperature reveals a periodic spectrum of exceptionally stable diameters. This is identified as shell structure similar to that which was recently discovered for alkali metals at low…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 A. I. Mares , A. F. Otte , L. G. Soukiassian , R. H. M. Smit , J. M. van Ruitenbeek

The authors introduce a geometry for ultrathin Au and Ag wires that ab initio calculations indicate to be more stable than previously considered planar geometries for these systems, by about 0.1 eV per atom. This structure is insulating for…

Materials Science · Physics 2010-09-02 Frederico Fioravante , R. W. Nunes

We consider interacting electrons in a quantum wire in the case of a shallow confining potential and low electron density. In a certain range of densities, the electrons form a two-row (zigzag) Wigner crystal whose spin properties are…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 A. D. Klironomos , Julia S. Meyer , T. Hikihara , K. A. Matveev

Gold clusters Aun of size n = 2 to 12 atoms were studied by the density-functional theory with an ab-initio pseudopotential and a generalized gradient approximation. Geometry optimizations starting from a number of initial candidate…

Other Condensed Matter · Physics 2007-05-23 Prashant K. Jain

The temperature dependence of structural properties for infinitely long gold nanowires is studied. The molecular dynamics simulation method and the embedded-atom potential are used. The wires constructed at T=0 K with a face-centered cubic…

Materials Science · Physics 2009-10-31 G. Bilalbegovic

The existence of Wigner crystallization, one of the most significant hallmarks of strong electron correlations, has to date only been definitively observed in two-dimensional systems. In one-dimensional (1D) quantum wires Wigner crystals…

Recent experiments showed that the last, single channel conductance step in monatomic gold contacts exhibits significant fluctuations as a function of stretching. From simulations of a stretched gold nanowire linked to deformable tips, we…

Materials Science · Physics 2009-11-10 F. Picaud , V. Pouthier , C. Girardet , E. Tosatti

We have studied Peierls instability in an atomically thin wire of sodium atoms using first-principles density-functional methods. A Na wire has a stable uniform linear structure over a range of inter-atomic distances. At smaller…

Materials Science · Physics 2009-11-11 Prasenjit Sen

The process of creating an atomically defined and robust metallic tip is described and quantified using measurements of contact conductance between gold electrodes and numerical simulations. Our experiments show how the same conductance…

Materials Science · Physics 2012-05-30 C. Sabater , C. Untiedt , J. J. Palacios , M. J. Caturla