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The relation between the distribution of work performed on a classical system by an external force switched on an arbitrary timescale, and the corresponding equilibrium free energy difference, is generalized to quantum systems. Using the…

Statistical Mechanics · Physics 2007-05-23 Shaul Mukamel

This article sets up a new formalism to investigate stochastic thermodynamics of out-of-equilibrium quantum systems, where stochasticity primarily comes from quantum measurement. In the absence of any bath, we define a purely quantum…

Quantum Physics · Physics 2016-10-17 Cyril Elouard , David Herrera Marti , Maxime Clusel , Alexia Auffèves

In self-gravitating stars, two dimensional or geophysical flows and in plasmas, long range interactions imply a lack of additivity for the energy; as a consequence, the usual thermodynamic limit is not appropriate. However, by contrast with…

Statistical Mechanics · Physics 2009-11-13 Freddy Bouchet , Julien Barré , Antoine Venaille

We discuss the conditions for which the non-equilibrium work relation is valid by means of thermodynamic and microscopic arguments.

Statistical Mechanics · Physics 2009-11-13 I. Santamaria-Holek , A. Perez-Madrid

We study Langevin dynamics describing nonequilibirum steady states. Employing the phenomenological framework of steady state thermodynamics constructed by Oono and Paniconi [Prog. Theor. Phys. Suppl. {\bf130}, 29 (1998)], we find that the…

Statistical Mechanics · Physics 2007-05-23 Takahiro Hatano , Shin-ichi Sasa

We experimentally verify the Jarzynski and W\"ojcik quantum heat exchange fluctuation relation by implementing the interferometric technique in liquid-state Nuclear Magnetic Resonance setup and study the exchange heat statistics between two…

Statistical Mechanics · Physics 2019-10-30 Soham Pal , T S Mahesh , Bijay Kumar Agarwalla

In previous papers we have introduced a natural nonequilibrium free energy by considering the functional describing the large fluctuations of stationary nonequilibrium states. While in equilibrium this functional is always convex, in…

Statistical Mechanics · Physics 2015-12-18 L. Bertini , A. De Sole , D. Gabrielli , G. Jona-Lasinio , C. Landim

We illustrate the Jarzynski equality on the exactly solvable model of a one-dimensional ideal gas in uniform expansion or compression. The analytical results for the probability density $P(W)$ of the work $W$ performed by the gas are…

Statistical Mechanics · Physics 2009-11-11 I. Bena , C. Van den Broeck , R. Kawai

Work is a process-based quantity, and its measurement typically requires interaction with a measuring device multiple times. While classical systems allow for non-invasive and accurate measurements, quantum systems present unique challenges…

Quantum Physics · Physics 2025-06-17 Giulia Rubino , Karen V. Hovhannisyan , Paul Skrzypczyk

The first part of the paper is devoted to the foundations, that is the mathematical and physical justification, of equilibrium statistical mechanics. It is a pedagogical attempt, mostly based on Khinchin's presentation, which purpose is to…

Statistical Mechanics · Physics 2007-05-23 Dragi Karevski

In this paper we give a pedagogical introduction to the ideas of quantum thermodynamics and work fluctuations, using only basic concepts from quantum and statistical mechanics. After reviewing the concept of work, as usually taught in…

Quantum Physics · Physics 2018-05-03 Wellington L. Ribeiro , Gabriel T. Landi , Fernando Semião

Aspects of the modern dynamical systems approach to thermodynamics of stationary states out of equilibrium with attention to the original conceptions which arose at the beginnings of Statistical Mechanics

Statistical Mechanics · Physics 2019-01-28 Giovanni Gallavotti

We consider a time-dependent quantum linear oscillator coupled to a bath at an arbitrary strength. We then introduce a generalized Jarzynski equality (GJE) which includes the terms reflecting the system-bath coupling. This enables us to…

Statistical Mechanics · Physics 2014-03-03 Ilki Kim

We consider the problem of constructing a thermodynamic theory of non-equilibrium steady states as a formal extension of the equilibrium theory. Specifically, studying a particular system, we attempt to construct a phenomenological theory…

Statistical Mechanics · Physics 2009-06-11 Glenn C. Paquette

The Jarzynski equality (JE) provides a nonequilibrium method to measure and calculate the free energy difference (FED). Note that if two systems share the same Hamiltonian at two equilibrium states, respectively, they share the same FED…

Statistical Mechanics · Physics 2020-07-16 Liyun Zhu , Jiao Wang

Stochastic thermodynamics extends the notions and relations of classical thermodynamics to small systems that experience strong fluctuations. The definitions of work and heat and the microscopically reversible condition are two key concepts…

Statistical Mechanics · Physics 2019-07-23 Geng Li , Z. C. Tu

The work performed on a system in a microcanonical state by changes in a control parameter is characterized in terms of its statistics. The transition probabilities between eigenstates of the system Hamiltonians at the beginning and the end…

Statistical Mechanics · Physics 2014-01-21 Peter Talkner , Manuel Morillo , Juyeon Yi , Peter Hanggi

We describe some solvable models which illustrate the Jarzynski theorem and related fluctuation theorems. We consider a charged particle in the presence of magnetic field in a two dimensional harmonic well. In the first case the centre of…

Statistical Mechanics · Physics 2015-06-25 A. M. Jayannavar , Mamata Sahoo

Detailed fluctuation theorem, a microscopic version of the steady state fluctuation theorem, has been proposed by Jarzynski and demonstrated in the case of Hamiltonian systems weakly coupled with reservoirs. We show that an identical…

Statistical Mechanics · Physics 2010-07-20 K. Gururaj , G. Raghavan , M. C. Valsakumar

Ability of dynamical systems to relax to equilibrium has been investigated since the invention of statistical mechanics, which establishes the connection between dynamics of many-body Hamiltonian systems and phenomenological thermodynamics.…

Statistical Mechanics · Physics 2019-07-01 K. S. Glavatskiy , V. L. Kulinskii